The carbon isotopic response of algae, (cyano)bacteria, archaea and higher plants to the late Cenomanian perturbation of the global carbon cycle: Insights from biomarkers in black shales from the Cape Verde Basin (DSDP Site 367)

The stable carbon isotopic compositions of free and sulfur (S)-bound biomarkers derived from algae, (cyano)bacteria, archaea and higher plants and total organic carbon (TOC) during the first phase of the late Cenomanian/Turonian oceanic anoxic event (OAE) were measured in black shales deposited in the southern proto-Atlantic Ocean in the Cape Verde basin (DSDP Site 367) to determine the response of these organisms to this major perturbation of the global carbon cycle resulting from widespread burial of marine organic matter. The average positive isotope excursions of TOC and biomarkers varied from 5.1‰ to 8.3‰. The δ¹³C values were cross correlated to infer potential common sources of biomarkers. This revealed common sources for C₃₁ and C₃₂ hopanes but no 1:1 relationship for pristane and phytane. The correlation of δ¹³C_TOC with the δ¹³C value of sulfur (S)-bound phytane is the strongest. This is because S-bound phytane is derived from phytol that originates from all marine primary producers (algae and cyanobacteria) and thus represents a weighted average of their carbon isotopic compositions. The δ¹³C values of S-bound phytane and C₃₅ hopane were also used to estimate pCO₂ levels. Before the OAE burial event, pCO₂ levels are estimated to be ca. 1300 ppmv using both biomarkers and the independent maximum Rubisco fractionation factors. At times of maximum organic carbon burial rates during the OAE, reconstructed pCO₂ levels are estimated to be ca. 700 ppmv. However, compared to other C/T OAE sections the positive isotope excursion of S-bound phytane is also affected by an increased production during the OAE. When we compensate for this, we arrive at pCO₂ levels around 1000 ppmv, a reduction of ca. 25%. This indicates that burial of organic matter can have a large effect on atmospheric CO₂ levels.     

Applications of particle-tracking techniques to bank infiltration: a case study from El Paso,Texas, USA

This paper presents results of a small scale study that utilized particle-tracking techniques to evaluate transport of river water through an alluvial aquifer in a bank infiltration testing site in El Paso, Texas, USA. The particle-tracking survey was used to better define filtration parameters. Several simulations were generated to allow visualization of the effects of well placement and pumping rate on flow paths, travel time, the size of the pumping influence zone, and proportion of river-derived water and groundwater mixing in the pumping well. Simulations indicate that migration of river water into the aquifer is generally slow. Most water does not arrive at the well by the end of an 18-day pumping period at 0.54 m³/min pumping rate for a well located 18 m from the river. Forty-four percent of the water pumped from the well was river water. The models provided important information needed to design appropriate sampling schedules for bank filtration practices and ensured meeting adequate soil-retention times. The pumping rate has more effect on river water travel time than the location of the pumping well from the river. The examples presented in this paper indicate that operating the pumping well at a doubled distance from the river increased the time required for the water to travel to the well, but did not greatly change the capture zone.     

Groundwater flow and contaminant transport modelling at an air weapons range

Numerical modelling was done at the Cold Lake Air Weapons Range, Canada, to test whether the dissolved RDX and nitrate detected in groundwater come from the same sources, and to predict whether contamination poses a threat to the surface water receptors near the site. Military live fire training activities may indeed pose a risk of contamination to groundwater resources, however field investigations on military bases are quite recent, and little information is available on the long-term behaviour of munition residues related contaminants. Very limited information was available about the contaminant source zones, which were assigned based on our knowledge of current training activities. The RDX plume was well represented with the model, but the heterogeneous distribution of nitrate concentrations was more difficult to reproduce. It was nonetheless determined that both contaminants originate from the same areas. According to the model, both contaminants should reach the nearby river, but concentrations in the river should remain very low if the source zone concentration does not change. Finally, the model allowed the recommendation of a new location for the main bombing target, which would offer added protection to the river and the lake into which it flows.     

Stable isotope study of the Archaean rocks of the Vredefort impact structure,central Kaapvaal Craton,South Africa

The Vredefort dome in the Kaapvaal Craton was formed as a result of the impact of a large meteorite at 2.02 Ga. The central core of Archaean granitic basement rocks is surrounded by a collar of uplifted and overturned strata of the Witwatersrand Supergroup, exposing a substantial depth section of the Archaean crust. Orthogneisses of the core show little variation in whole-rock δ ¹⁸O value, with the majority being between 8 and 10‰, with a mean of 9.2‰ (n = 35). Quartz and feldspar have per mil differences that are consistent with O-isotope equilibrium at high temperatures, suggesting minimal interaction with fluids during subsequent cooling. These data refute previous suggestions that the Outer Granite Gneiss (OGG) and Inlandsee Leucogranofels (ILG) of the core represent middle and lower crust, respectively. Granulite-facies greenstone remnants from the ILG have δ ¹⁸O values that are on average 1.5‰ higher than the ILG host rocks and are unlikely, therefore, to represent the residuum from the partial melting event that formed the host rock. Witwatersrand Supergroup sedimentary rocks of the collar, which were metamorphosed at greenschist-to amphibolite-facies conditions, generally have lower δ ¹⁸O values than the core rocks with a mean value for metapelites of 7.7‰ (n = 45). Overall, through an ∼20 km thick section of crust, there is a general increase in whole-rock δ ¹⁸O value with increasing depth. This is the reverse of what is normal in the crust, largely because the collar rocks have δ ¹⁸O values that are unusually low in comparison with metamorphosed sedimentary rocks worldwide. The collar rocks have δD values ranging from −35 to −115‰ (average −62‰, n = 29), which are consistent with interaction with water of meteoric origin, having a δD of about −25 to −45‰. We suggest that fluid movement through the collar rocks was enhanced by impact-induced secondary permeability in the dome structure. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

City senses: On the radical possibilities of pragmatism in geography

This paper explores the radical possibilities of pragmatism for geography using the illustration of arguments concerning a renewed (urban) public realm through the exchange of validity claims in communication. Pressing further the pragmatist possibilities of Habermas’s idea of communicative action it draws on John Dewey’s work, and a range of contemporary pragmatist philosophers, to consider human communicability in its widest sense. This is then explored using an example of the spatiality and performativity of body-minds in a range of communicative spaces of the city. Then the paper moves on to consider the radical implications of pragmatism for geography in general in terms of body-mind/environment relations; a transactional view of space; experience, rationality and radical democracy.     

Dissolved and labile concentrations of Cd, Cu, Pb, and Zn in the South Fork Coeur d’Alene River, Idaho: Comparisons among chemical equilibrium models and implications for biotic ligand models

In order to evaluate thermodynamic speciation calculations inherent in biotic ligand models, the speciation of dissolved Cd, Cu, Pb, and Zn in aquatic systems influenced by historical mining activities is examined using equilibrium computer models and the diffusive gradients in thin films (DGT) technique. Several metal/organic-matter complexation models, including WHAM VI, NICA-Donnan, and Stockholm Humic model (SHM), are used in combination with inorganic speciation models to calculate the thermodynamic speciation of dissolved metals and concentrations of metal associated with biotic ligands (e.g., fish gills). Maximum dynamic metal concentrations, determined from total dissolved metal concentrations and thermodynamic speciation calculations, are compared with labile metal concentrations measured by DGT to assess which metal/organic-matter complexation model best describes metal speciation and, thereby, biotic ligand speciation, in the studied systems. Results indicate that the choice of model that defines metal/organic-matter interactions does not affect calculated concentrations of Cd and Zn associated with biotic ligands for geochemical conditions in the study area, whereas concentrations of Cu and Pb associated with biotic ligands depend on whether the speciation calculations use WHAM VI, NICA-Donnan, or SHM. Agreement between labile metal concentrations and dynamic metal concentrations occurs when WHAM VI is used to calculate Cu speciation and SHM is used to calculate Pb speciation. Additional work in systems that contain wide ranges in concentrations of multiple metals should incorporate analytical speciation methods, such as DGT, to constrain the speciation component of biotic ligand models.     

Acoustic-gravity wave propagation in an atmosphere with two sound channels

Summary In order to interpret the observed features of pressure records produced by waves from large explosions in the earth's atmosphere, the writers have obtained numerical solutions of the homogeneous equations governing acoustic-gravity wave propagation in a stratified compressible fluid. Theoretical dispersion curves and variations of perturbation kinetic energy with altitude are presented for 11 normal modes. It is shown that the step-like character of the phase velocity curves in the velocity-period plane can be interpreted as being the result of interference between two families of normal modes-«quasi-horizontal modes» representing energy propagation in the lower atmosphere (below the ozonosphere) and «quasi-vertical modes» representing energy propagation in the upper atmosphere (above the ozonosphere). The theoretical prediction that several normal modes contribute to the observed barogram traces is verified by Fourier analysis of a number of wave records.Lamont Geological Observatory Contribution No. 611. — This research was supported by National Science Foundation Grant NSF-G-11997, Office of Naval Research Contract Nonr 266 (70), and National Science Foundation Grant NSF-GP-550. — Part of this research was done at the NASA Institute for Space Studies, New York, N. Y.     

Basalt from Louisiana continental shelf

A basalt outcrop was discovered on Alderdice Bank on the outer Louisiana continental shelf. The basalt shows an age of 76.8 ± 3.3 × 10⁶ years. Textural, mineralogical, and chemical characteristics indicate that it is an alkali basalt of shallow intrusive origin. It was probably brought to the seafloor by salt tectonics and exposed due to salt dissolution.An accurate account of the Mesozoic geologic history of the Gulf of Mexico must consider the apparent consanguinity of all magmatic rocks of the region, including the Alderdice Bank basalt, and the apparent basinward decrease in age of magmatic activities.