GGR Biennial Review: Advances in Laser Ablation and Solution ICP-MS from 2008 to 2009 with Particular Emphasis on Sensitivity Enhancements,Mitigation of Fractionation Effects and Exploration of New Applications

Recent developments from 2008 to 2009 in ICP-MS engineering, methods and applications are reviewed here. Of particular emphasis are advances in: (a) maximising sensitivity and reducing elemental/isotopic fractionation during laser ablation processing; (b) developing new analytical techniques to measure major, minor and trace element abundances without depending on matrix-matched calibrating materials, pre-determined internal standard concentrations and/or multiple analytical methods; (c) applying in situ and solution-based ICP-MS techniques to the analysis of forensic materials for criminal and/or nuclear investigations; and (d) improving precision and limits of detection of laser ablation multi-collector ICP-MS measurements of (ultra) trace elemental and isotopic abundances.     

A red algal bloom in the aftermath of the Marinoan Snowball Earth

Organic matter from the cap dolostones overlying the Marinoan‐age glacigenic diamictites of the Araras Group, Amazon craton, has been studied to reconstruct the post‐glacial ecosystem. Molecular fossils indicate that the post‐Marinoan ecosystem was marked by an apparent decline in marine algal diversity. The proliferation of red algae may be explained by environmental changes, such as a massive nutrient input accompanying continental weathering after the ice thaw and a dimer light penetrating sea water due to the drowning of the platform. In addition, the presence of green sulphur bacteria indicates that sea water was stratified with an anoxic (possibly euxinic, i.e. sulphidic) layer at the water–sediment interface. Sulphur cycling probably occurred at the redox boundary as suggested by the recognition of active sulphate reduction. This observation supports a microbially induced model for the formation of the cap dolostones.     

Optimization for performance-based design under seismic demands,including social costs

Performance-based design in earthquake engineering is a structural optimization problem that has, as the objective, the determination of design parameters for the minimization of total costs, while at the same time satisfying minimum reliability levels for the specifi ed performance criteria. Total costs include those for construction and structural damage repairs, those associated with non-structural components and the social costs of economic losses, injuries and fatalities. This paper presents a general framework to approach this problem, using a numerical optimization strategy and incorporating the use of neural networks for the evaluation of dynamic responses and the reliability levels achieved for a given set of design parameters. The strategy is applied to an example of a three-story offi ce building. The results show the importance of considering the social costs, and the optimum failure probabilities when minimum reliability constraints are not taken into account.     

The importance of and need for rapid hydrologic assessments in Latin America

Long‐term observations are critical in hydrology to understand the dynamics of biological and physicochemical processes involved in and affected by the flux of water. Long‐term observations have been employed to provide basic understanding of the water cycle (e.g., infiltration, evaporation, run‐off generation, and groundwater–surface water interactions), but they are lacking in hydrologically relevant regions such as the Andes Mountains, including alpine watersheds. Although the call for long‐term data acquisition in Latin America has been made, the establishment of long‐term data collection centres remains logistically challenging. This ever‐growing scientific gap hinders our understanding of differences and similarities in hydrological processes of tropical and temperate regions. Furthermore, technological advances such as in situ optical sensors for water quantity and quality remain cost‐prohibitive for both short and long deployment at most existing research sites in Latin America, restricting researchers pursuing research funding or developing meaningful, intersite comparisons and syntheses. Here, we emphasize the importance of and need for rapid assessments (i.e., field campaigns conducted over a few days) for improved hypothesis development and mechanistic understanding of hydrological dynamics in Latin America. We report on rapid assessments conducted in the high‐elevation mountains (>3,000 m) of Colombia. Our results highlight rapidly changing dynamics in nutrient retention potential and dissolved CO₂ (pCO₂), as well as highly variable spatial distribution of water quality parameters (N, C, P, Cl) in areas with varying land use. We present an initial examination of the effects of land‐use change on stream nutrient dynamics in one of the most biodiverse and threatened ecosystems on Earth. We conclude that rapid assessments not only are necessary but also represent a cost‐effective way to develop clear, testable hypotheses to advance a hydrologic research agenda in Latin America and work towards long‐term hydrological knowledge and information for use by other scientists.     

Three-dimensional discrete element method for granular materials

This paper describes a three-dimensional discrete element method of analysis for granular materials. Individual particles are modelled as rigid, six-sided solids with six degrees of freedom. Various types of contacts are possible among the three-dimensional discrete elements. Models for these contact types are described. Computational aspects of the method, such as techniques for contact detection and data structure, are addressed. Selective results of three examples that demonstrate the application of the method to granular flow problems are presented and discussed.     

Global assessments of the NCEP Ensemble Forecast System using altimeter data

Ocean Dynamics - Forecasts of 10-m wind (U10) and significant wave height (Hs) from the National Centers for Environmental Prediction (NCEP) Ensemble Forecast System are evaluated using altimeter...     

Climate change in the Paraná state,Brazil: responses to increasing atmospheric CO 2 in reference evapotranspiration

The hydrological variable evapotranspiration (ET) is challenging to estimate because it cannot be measured directly in natural environments (except in small plots). The uncertainties associated with the models used for its prediction have increased under climate change conditions. We studied the influence of stomatal resistance on ET estimates using the Penman-Monteith method as projected by three general circulation models in two emission scenarios (RCP4.5 and RCP8.5) for future climates throughout the twenty-first century (2010–2039, 2040–2069, and 2070–2099). We also investigated the probable ET rate changes in relation to the current (30 years average, 1980–2009) climate conditions for the Paraná state in the southern region of Brazil. The results were regionalized to help policymakers assess climate change impacts and design adaptation measures. ET increases of up to 15% were found in future climate conditions, which may lead to a significant increase in the water demand for agricultural crops. However, we believe that plant morphophysiological changes may occur under atmospheric CO2 enrichment conditions and that a possible reduction in stomatal conductance will result in lower ET increases than those obtained with the traditional Penman-Monteith method. When considering future climate scenarios, we propose the equation be adjusted to consider stomatal resistance as a function of CO2 concentrations.