CO2-driven cation leaching after tropical forest clearing

The objective of this study was to investigate the role of dissolved CO₂ (H₂CO₃*) as a mechanism of cation removal from surface soils under secondary land uses in the tropics. Soil leachate columns were prepared with 0–10 cm soils from mature and secondary forest, and managed pastures, and extracted with H₂CO₃* from deionized water equilibrated with 0%, 0.5%, 1%, and 10% CO₂ (g). Extraction of soil cations slowed over time following an exponential form for the cumulative data. The rate of cation concentration decline varied as a function of CO₂ concentration with the 10% solution resulting in a greater percent decline with extraction volume. Potassium removal from the exchange sites of all soils and for all solutions was nearly complete ranging from 85% to 97% while removals of Mg (31% to 71%) and Ca (12% to 42%) were lower. The asymptotic patterns of cation loss observed in this study suggest that H₂CO₃* acid-driven losses of cations may become self-limiting over time. Other stronger acids from atmospheric deposition or organic sources may serve to perpetuate cation removal, and re-forestation on these cleared lands would certainly re-distribute cations from soils to vegetation.     

Gravimetric determination of an intrusive complex under the Island of Faial (Azores): some methodological improvements

We present some improvements of a gravity inversion method to determine the geometry of the anomalous bodies for priori density contrasts. The 3-D method is based on an exploratory process applied, not for the global model, but for the steps of a growth approach. The (positive and/or negative) anomalous structure is described by successive aggregation of cells, while its corresponding gravity field remains nearly proportional to the observed one. Moreover, a simple (e.g. linear) regional trend can be simultaneously adjusted. The corresponding program is applied to new gravity data on the volcanic island of Faial (Azores archipelago). The inversion approach shows a subsurface anomalous structure for the island, the main feature being an elongated high-density body. The body is interpreted as a compact sheeted dyke swarm, emplaced along Faial-Pico Fracture Zone, a leaky transform structure that forms the current boundary between Eurasian and African plates in the Azores area. The new results in this paper are (1) a Bouguer gravity anomaly map, (2) several improvements in the inversion process (robust process, optimal balance fitness/model magnitude), (3) a new gravimetric method for estimating the mean terrain density, (4) a 3-D model for subsurface mass anomalies in Faial and (5) some interpretative conclusions about a main intrusive complex detected under the island as a wall-like structure extending from a depth of 0.5 to 6 km b.s.l., with a N100°E trend and corresponding to an early fissural volcanic episode controlled by the regional tectonics.     

Changes in diatom, pollen, and chironomid assemblages in response to a recent volcanic event in Lake Galletué (Chilean Andes)

Several lakes in Chile are near important volcanic areas where eruption impacts can limit the quality of lacustrine sediments for reconstructing past environmental changes. In this study, we report changes in diatoms, pollen, and chironomids assemblages after a tephra deposition in Lake Galletué (Chilean Andes). A sediment core obtained from Lake Galletué (40 m water depth) was sliced in 1 cm intervals and subsamples were taken to analyze each proxy. ²¹⁰Pb and ¹³⁷Cs activities were measured to obtain the geochronology and mineralogical analyses were performed to determine the mineral composition of the tephra. Diatom species composition and productivity were modified when the lake received the tephra; Aulacoseira granulata decreased and was later replaced by Cyclotella af. glomerata. After the tephra input, Aulacoseira granulata abundance increased to pre-disturbance levels and Cyclotella af. glomerata decreased. These changes seem to suggest a momentary increase in lake nutrient levels after the tephra deposition. Chironomid assemblages also decreased in head capsules just after the tephra deposition, but the most important change was the replacement of Ablabesmyia by Parakiefferiella, probably due to the sedimentological changes produced by the input of coarse tephra grains. Furthermore, unlike other studies, chironomid assemblages in Lake Galletué did not show a decrease drastically in diversity within the tephra layer. The pollen analysis indicated that, prior to the volcanic event, the vegetal community was dominated by Nothofagus sp., Araucaria araucana, and Blechnum sp.-type. After the tephra deposition, the same taxa are dominant, indicating that the volcanic event seems not produce changes in the vegetation. Nevertheless, within the tephra layer it is possible to see an increase in Poaceae, which represent – due to the percolation process – the effect of eruption on the vegetation. According to our results, diatoms were the most sensitive proxy for describing the changes produced by tephra deposition into the aquatic ecosystem and, despite the noticeable changes in its sedimentological properties; the lake seems to have a high resilience capacity, allowing it to return to pre-tephra input conditions.     

Evaluation of susceptibility for terrain collapse and subsidence in karst areas,municipality of Iraquara,Chapada Diamantina (BA), Brazil

The morphological evolution of the karstic systems is associated with a set of physical and chemical processes, triggered by the dissolution of the rocks, related to percolation of groundwater and surface water, which consequently open underground voids and carve out peculiar forms of relief. Due to environmental and geotechnical aspects, this system is naturally more fragile and vulnerable than other natural systems and, therefore, has increasingly received the attention of the scientific community over the past decades. The objective of the study was to delimit zones with varying degrees of susceptibility for collapses and subsidence of sinkholes in the municipality of Iraquara, Chapada Diamantina (BA), Brazil, and to understand their geological and morphological determinant factors. Geological data, karst phenomenon map, and visual analysis in the field were used to categorize zones with different types of susceptibilities to the nucleation of new sinkholes based on a Hazard Index. This index was defined from the sum of geological hazard factors, lineament density, and sinkhole density. The areas that presented the highest susceptibility for terrain collapse and subsidence corresponded to regions where carbonate rocks outcrop, with high density of photolineaments and 2.62 sinkholes/km². Processes associated with terrain collapse and subsidence in karst areas consisted of a combination of various factors, hindering precise predictions. However, zones of different types of susceptibilities to terrain collapse and subsidence can be delimited when the relationships between these processes and their factors are understood. The Hazard Index proposed does not provide quantitative values for the probability of hazard susceptibility, but rather indicates areas that are more susceptible to terrain subsidence and collapse.     

Estimating groundwater recharge using GIS-based distributed water balance model in an environmental protection area in the city of Sete Lagoas (MG), Brazil

Improvement in modern water resource management has become increasingly reliant on better characterizing of the spatial variability of groundwater recharge mechanisms. Due to the flexibility and reliability of GIS-based index models, they have become an alternative for mapping and interpreting recharge systems. For this reason, an index model by integrating water balance parameters (surface runoff, actual evapotranspiration, and percolation) calculated by Thornthwaite and Mather’s method, with maps of soil texture, land cover, and terrain slope, was developed for a sustainable use of the groundwater resources. The Serra de Santa Helena Environmental Protection Area, next to the urbanized area of Sete Lagoas (MG), Brazil, was selected as the study area. Rapid economic growth has led to the subsequent expansion of the nearby urban area. Large variability in soil type, land use, and slope in this region resulted in spatially complex relationships between recharge areas. Due to these conditions, the study area was divided into four zones, according to the amount of recharge: high (>?100 mm/year), moderate (50–100 mm/year), low (25–50 mm/year), and incipient (>?25 mm/year). The technique proved to be a viable method to estimate the spatial variability of recharge, especially in areas with little to no in situ data. The success of the tool indicates it can be used for a variety of groundwater resource management applications.     

Vulnerability to contamination by phosphorus in a zero-order basin with a high density of pigs and a history of slurry addition: extrapolation of an index

The application of phosphorus (P)-index methodology to assess the risk of water pollution from agriculture in river basins usually takes time and expends a great amount of resources. This study adapted the P-index methodology using digital mapping of key basin risk criteria for P loss in reference areas to evaluate the wider vulnerability to P loss in a zero-order basin with an intense concentration of pigs and with a history of pig slurry additions to the soil. The P content of eleven reference areas, where ten areas have received various applications of pig slurry and one area has no history of addition, was extrapolated to a zero-order basin using principal component analysis and analysis of hierarchical groupings. Estimated loss of soil and the distance between the P source and the watercourse were mapped using satellite images and in situ evaluations. The methodology of extrapolating was well correlated with a survey of P concentrations in land runoff and provides the potential to improve land management of those areas that are most vulnerable. Principal component analysis and hierarchical clustering analysis proved to be useful tools for the separation of areas with different slurry application times. Our results suggest that the P loss risk could be reduced through the adoption of soil conservation techniques such as reduced-tillage incorporating slurry and crop residue management to provide adequate soil protection, reduce the impact of raindrops and reduce erosion risk and transport of chemical pollutants to water bodies.     

Spatial coincidence and similar geochemistry of Late Triassic and Eocene–Oligocene magmatism in the Andes of northern Chile: evidence from the MMH porphyry type Cu–Mo deposit,Chuquicamata District

International Journal of Earth Sciences - The MMH porphyry type copper–molybdenum deposit in northern Chile is the newest mine in the Chuquicamata District, one of largest copper...     

The Diamantina Monazite: A New Low‐Th Reference Material for Microanalysis

Most monazite reference materials (RMs) for in situ U‐Pb geochronology are rich in Th; however, many hydrothermal ore deposits contain monazite that is low in trace element contents, including Th, U and Pb. Because of potential problems with matrix effects and the lack of appropriate matrix‐matched RMs, such variations can bias dating of hydrothermal deposits. In this paper, we describe a polycrystalline low‐U and low‐Th Diamantina monazite from the Espinhaço Range, SE Brazil. It has a U‐Pb ID‐TIMS weighted mean ²⁰⁷Pb^*/²³⁵U ratio of 0.62913 ± 0.00079, ²⁰⁶Pb^*/²³⁸U of 0.079861 ± 0.000088 and ²⁰⁷Pb^*/²⁰⁶Pb^* of 0.057130 ± 0.000031, yielding a weighted mean ²⁰⁶Pb^*/²³⁸U date of 495.26 ± 0.54 Ma (95% c.l.). In situ dates acquired with different methods (LA‐(Q, SF, MC)‐ICP‐MS and SIMS) are within uncertainty of the ID‐TIMS data. U‐Pb LA‐(Q, MC)‐ICP‐MS runs, using Diamantina as a primary RM, reproduced the ages of other established RMs within < 1% deviation. The LA‐MC‐ICP‐MS analyses yielded homogeneous Sm‐Nd isotopic compositions (¹⁴³Nd/¹⁴⁴Nd = 0.511427 ± 23, 2s; ¹⁴⁷Sm/¹⁴⁴Nd = 0.1177 ± 13, 2s) and εNd_(495 Ma) of ?18.7 ± 0.5 (2s). SIMS oxygen isotope determinations showed measurement reproducibility better than ± 0.3‰ (2s), confirming Diamantina's relative homogeneity at test portion masses below 1 ng.     

Temporal Variability of Dark Carbon Fixation and Bacterial Production and Their Relation with Environmental Factors in a Tropical Estuarine System

Dark carbon fixation (DCF) is considered an important energy source in aquatic environments, although it has been neglected for a long time. DCF is known to be relevant in ecosystems associated with redoxclines, shallow-water sulfide-rich habitats, deep-sea vents, cold seeps, and even in coastal waters associated with upwelling events. The aim of this study was to evaluate the relative importance of DCF in relation to heterotrophic bacterial production (BP), as well as how these rates affect each other, and how they are influenced by the environmental factors. This study was conducted monthly during 2 years in a tropical eutrophic bay (Guanabara Bay), where two stations were sampled and compared. DCF and BP were measured by ¹⁴C-bicarbonate and ³H-leucine incorporation, respectively, and incubations in the dark. Our results showed that DCF is not a quantitatively relevant process in this estuarine system, when compared to heterotrophic BP, and possibly occurred via anaplerotic reactions. Relatively higher DCF rates were associated with less oxygenated waters at the more polluted station and during the wet summer-spring, when the water column is more stratified. BP rates presented clear spatial patterns, according to pollution and depth gradients, with higher rates in more polluted areas, and also at surface waters. The hydrodynamics combined with other environmental conditions (precipitation, temperature, dissolved organic carbon, and nutrients) may control the distribution of DCF and BP over space and time. The allochthonous inputs of organic matter are more important than DCF-derived organic carbon to bacterioplankton in this polluted and eutrophic bay, where the heterotrophic metabolism prevails.     

Landslide disaster risk awareness in Mexico: community access to mapping at local scale

Recent investigations have sought to understand the spatial-temporal distribution of landslides in Teziutlán, Puebla, a municipality historically affected by landslides. The latest initiative, under the umbrella of the ICL-IPL Project “Landslide disaster risk communication in mountain areas,” was the publication of a book of Atlas type comprising a collection of 142 maps and their corresponding explanatory texts that included a context analysis of landslide disaster risk drivers at various scales, from regional to local. This paper aims to recognise and address the necessity to further enhance the guiding principle of the Sendai Framework for Disaster Risk Reduction to focus on the understanding of disaster risk drivers at local level, for the determination of measures to reduce disaster risk. We present an initial contribution to promote landslide disaster risk awareness in the urban area of Teziutlán by providing to the community direct access to maps of landslide disaster risk at local scale; this is a first step towards the establishment of a robust strategy to communicate landslide risk in the long term. Effective implementation calls for decreasing vulnerability and exposure. Beyond contexts of vulnerability reflected by social, economic, cultural, political, and institutional conditions, it may be difficult to picture the spatial interactions of exposure of communities, assets, and the environment because the means of analysing spatial relationships between society and nature are not commonly available in mountain areas. Therefore, for people to better understand risk, maps of landslide susceptibility and risk exposure present a good way for the inhabitants to familiarise themselves with the spatial context of the dynamics in which they are immersed.