Initial moduli of particulated mass with frictional contacts

The stiffness characteristics of a packing of granules are influenced by the particle interactions at contacts, the void ratio, the co-ordination number and the packing structure. A stress-strain relationship for the packings of spheres is presented. The relationship explicitly includes the contact force-displacement law and the parameters characterizing the packing structure. The initial moduli computed using this relationship are compared with experimental measurements and empirical equations for sands. The theoretical results are also compared with experimental results on packings of glass balls. Closed-form solutions are derived for statistically isotropic packings under initial isotropic stress conditions. Numerical solutions for the stiffness properties are obtained for anisotropic initial stress conditions and anisotropic packing structures.     

Influence of Bacterial Exopolymers, Conspecific Adult Extract and Salinity on the Cyprid Metamorphosis of Balanus amphitrite Cirripedia: Thoracica

Abstract. The influence of bacterial exopolymers and conspecific adult extract of Balanus amphitrite on metamorphosis of cyprid larvae at different salinities has been evaluated through laboratory assay. The bacterial exopolymers epm extracted from Pseudomonas, Acinetobacter and Enterobacteriaceae strains, isolated from the shell surface of Balanus amphitrite , were examined for their influence on metamorphosis, both individually and in combination with conspecific adult extract at 15, 25, 35 and 45% salinities. The epm extracted from the pool of these three strains mixed culture was also tested similarly.
The influence of epm varied with the strain of bacteria and salinity. The surface condition and time interval significantly influenced the metamorphosis rate. The interaction between these two variables, however, did not change in any combination, irrespective of the bacterial strain used. The Pseudomonas epm promoted metamorphosis at 15%, but was inhibitory at 45%. The Acinetobacter epm induced metamorphosis to a level of 71 ± 15% at 15%. No such metamorphosis promotion was observed with the epm of this strain at higher salinities and the influence was less than the conspecific adult extract. The epm of Enterobacteriaceae and mixed culture epm did not promote metamorphosis. There was no appreciable change in the metamorphic rate in the control conditions at 25%, 35% and 45% salinities and the rate was much lower than that obtained with conspecific adult extract. At 15%, however, the influence of adult extract was closer to that of the control condition. This shows that even in the absence of any attractant, the settlement intensity is positively influenced at mid-salinity of the barnacles' natural distributional range.     

Latest Pleistocene glacial chronology of the Uinta Mountains: support for moisture-driven asynchrony of the last deglaciation

Recent estimates of the timing of the last glaciation in the southern and western Uinta Mountains of northeastern Utah suggest that the start of ice retreat and the climate-driven regression of pluvial Lake Bonneville both occurred at approximately 16 cal. ka. To further explore the possible climatic relationship of Uinta Mountain glaciers and the lake, and to add to the glacial chronology of the Rocky Mountains, we assembled a range-wide chronology of latest Pleistocene terminal moraines based on seventy-four cosmogenic ¹⁰Be surface-exposure ages from seven glacial valleys. New cosmogenic-exposure ages from moraines in three northern and eastern valleys of the Uinta Mountains indicate that glaciers in these parts of the range began retreating at 22–20 ka, whereas previously reported cosmogenic-exposure ages from four southern and western valleys indicate that ice retreat began there between 18 and 16.5 ka. This spatial asynchrony in the start of the last deglaciation was accompanied by a 400-m east-to-west decline in glacier equilibrium-line altitudes across the Uinta Mountains. When considered together, these two lines of evidence support the hypothesis that Lake Bonneville influenced the mass balance of glaciers in southern and western valleys of the range, but had a lesser impact on glaciers located farther east. Regional-scale variability in the timing of latest Pleistocene deglaciation in the Rocky Mountains may also reflect changing precipitation patterns, thereby highlighting the importance of precipitation controls on the mass balance of Pleistocene mountain glaciers.     

Continuous measurement of nitrate concentration in a highly event‐responsive agricultural catchment in south‐west of France: is the gain of information useful?

A nitrate sensor has been set up to measure every 10 min the nitrate signal in a stream draining a small agricultural catchment dominated by fertilized crops during a 2‐year study period (2006–2008) in the south‐west of France. An in situ sampling protocol using automatic sampler to monitor flood events have been used to assume a point‐to‐point calibration of the sensor values. The nitrate concentration exhibits nonsystematic concentration and dilution effects during flood events. We demonstrate that the calibrated nitrate sensor signal gathered from the outlet is considered to be a continuous signal using the Nyquist–Shannon sampling theorem. The objectives of this study are to quantify the errors generated by a typical infrequent sampling protocol and to design appropriate sampling strategy according to the sampling objectives. Nitrate concentration signal and flow data are numerically sampled to simulate common sampling frequencies. The total fluxes calculated from the simulated samples are compared with the reference value computed on the continuous signal. Uncertainties are increasing as sampling intervals increase; the method that is not using continuous discharge to compute nitrate fluxes bring larger uncertainty. The dispersion and bias computed for each sampling interval are used to evaluate the uncertainty during each hydrological period. High underestimation is made during flood periods when high‐concentration period is overlooked. On the contrary, high sampling frequencies (from 3 h to 1 day) lead to a systematic overestimation (bias around 3%): highest concentrations are overweighted by the interpolation of the concentration in such case. The in situ sampling protocol generates less than 1% of load estimation error and sample highest concentration peaks. We consider useful such newly emerging field technologies to assess short‐term variations of water quality parameters, to minimize the number of samples to be analysed and to assess the quality state of the stream at any time. Copyright © 2012 John Wiley & Sons, Ltd.     

An approach to estimate Lower Jurassic seawater oxygen‐isotope composition using δ18O and Mg/Ca ratios of belemnite calcites (Early Pliensbachian,northern Spain)

Palaeotemperature estimates from the oxygen‐isotope compositions of belemnites have been hampered by not knowing ancient seawater isotope compositions well enough. We have tackled this problem using Mg/Ca as a proxy for temperature and here, we present a ~2 Ma record of paired Mg/Ca and δ¹⁸O measurements of Jurassic (Early Pliensbachian) belemnites from the Asturian basin as a palaeo‐proxy of seawater oxygen‐isotope composition. From the combined use of the two approaches, we suggest a δ¹⁸O_w composition of about ?0.1‰ for the Jamesoni–Ibex zones. This value may have been increased by about 0.6‰ during the Davoei Zone due to the effect of waters with a different δ¹⁸O_w composition. These findings illustrate the inaccuracy of using a globally homogeneous ice‐free value of δ¹⁸O_w = ?1‰ for δ¹⁸O_carb‐based palaeotemperature reconstructions. Our data suggest that previous palaeotemperatures calculated in the region from δ¹⁸O values of belemnites may have been underestimated as the seawater oxygen isotopic composition could have been higher.     

Beryllium‐10 surface exposure dating of glacial successions in the Central Alaska Range

Glacial landforms and outwash terraces in the Nenana River valley, Reindeer Hills and Monahan Flat in the central Alaska Range were dated with 60 ¹⁰Be exposure ages to determine the timing of Late Pleistocene glaciation. In the Nenana River valley, glaciation occurred at 104–180 ka (Lignite Creek glaciation), ca. 55 ka (Healy glaciation), and ca. 16 ka (Carlo Creek phase); glaciers retreated in the Reindeer Hills and Monahan Flat by ca. 14 ka and ca. 13 ka, respectively. The Carlo Creek moraine is similar in age to at least six other moraines in the Alaska Range, Ahklun Mountains and Brooks Range. The new data suggest that post‐depositional geological processes limit the usefulness of ¹⁰Be methods to the latter part (≤60 ka) of the late Quaternary in central Alaska. Ages on Healy and younger landforms cluster well, with the exception of Riley Creek moraines and Monahan Flat‐west sites, where boulders were likely affected by post‐depositional processes. Copyright © 2010 John Wiley & Sons, Ltd.