Contemporary 14C radiocarbon levels of oxygenated polybrominated diphenyl ethers (O-PBDEs) isolated in sponge-cyanobacteria associations

Considerable debate surrounds the sources of oxygenated polybrominated diphenyl ethers (O-PBDEs) in wildlife as to whether they are naturally produced or result from anthropogenic industrial activities. Natural radiocarbon (¹⁴C) abundance has proven to be a powerful tool to address this problem as recently biosynthesized compounds contain contemporary (i.e. modern) amounts of atmospheric radiocarbon; whereas industrial chemicals, mostly produced from fossil fuels, contain no detectable ¹⁴C. However, few compounds isolated from organisms have been analyzed for their radiocarbon content. To provide a baseline, we analyzed the ¹⁴C content of four O-PBDEs. These compounds, 6-OH-BDE47, 2′-OH-BDE68, 2′,6-diOH-BDE159, and a recently identified compound, 2′-MeO-6-OH-BDE120, were isolated from the tropical marine sponges Dysidea granulosa and Lendenfeldia dendyi. The modern radiocarbon content of their chemical structures (i.e. diphenyl ethers, C₁₂H₂₂O) indicates that they are naturally produced. This adds to a growing baseline on, at least, the sources of these unusual compounds.     

The role of aridification in constraining the elevation range of Holocene solifluction processes and associated landforms in the periglacial belt of the Sierra Nevada (southern Spain)

Climate variability during the Mid‐Late Holocene has influenced the activity of geomorphic processes in the current periglacial belt of the Sierra Nevada. We studied two types of sedimentary records that reveal a synchronous timing for slope instability in this high semi‐arid massif: solifluction landforms and mountain lake sediments. Lithological and sedimentological properties of both records have recorded numerous cycles of different magnitude of slope processes in the massif. Solifluction deposits record seven phases of solifluction activity and soil development during the last 7 ka bp and lake sediments show evidence of eight periods with increased geomorphic activity in the catchments over the last 6 ka bp . Although present‐day climate conditions do not promote active solifluction processes in the Sierra Nevada, colder and wetter periods during the Holocene triggered solifluction and transported coarse‐grained sediments into the lakes. By contrast, warm phases favoured soil formation and spread an incipient vegetation cover over the headwaters of the highest valleys, diminishing the grain size of the particles reaching the lakes. Lake sediments record an aridification trend in the massif intensifying since 4·2 ka bp that has conditioned solifluction activity to shift gradually to higher elevations. During major cooler phases such as the Little Ice Age active solifluction was recorded back down to 2500 m altitude. Copyright © 2010 John Wiley & Sons, Ltd.     

Three‐dimensional modal pushover analysis of buildings subjected to two components of ground motion,including its evaluation for tall buildings

The modal pushover analysis (MPA) procedure, presently restricted to one horizontal component of ground motion, is extended to three‐dimensional analysis of buildings—symmetric or unsymmetric in plan—subjected to two horizontal components of ground motion, simultaneously. Also presented is a variant of this method, called the practical modal pushover analysis (PMPA) procedure, which estimates seismic demands directly from the earthquake response (or design) spectrum. Its accuracy in estimating seismic demands for very tall buildings is evaluated, demonstrating that for nonlinear systems this procedure is almost as accurate as the response spectrum analysis procedure is for linear systems. Thus, for practical applications, the PMPA procedure offers an attractive alternative whereby seismic demands can be estimated directly from the (elastic) design spectrum, thus avoiding the complications of selecting and scaling ground motions for nonlinear response history analysis. Copyright © 2010 John Wiley & Sons, Ltd.     

Oxygen isotopic constraints on the origin of Mg-rich olivines from chondritic meteorites

Chondrules are the major high temperature components of chondritic meteorites which accreted a few millions years after the oldest solids of the solar system, the calcium–aluminum-rich inclusions, were condensed from the nebula gas. Chondrules formed during brief heating events by incomplete melting of solid dust precursors in the protoplanetary disk. Petrographic, compositional and isotopic arguments allowed the identification of metal-bearing Mg-rich olivine aggregates among the precursors of magnesian type I chondrules. Two very different settings can be considered for the formation of these Mg-rich olivines: either a nebular setting corresponding mostly to condensation–evaporation processes in the nebular gas or a planetary setting corresponding mostly to differentiation processes in a planetesimal. An ion microprobe survey of Mg-rich olivines of a set of type I chondrules and isolated olivines from unequilibrated ordinary chondrites and carbonaceous chondrites revealed the existence of several modes in the distribution of the ?¹⁷O values and the presence of a large range of mass fractionation (several ‰) within each mode. The chemistry and the oxygen isotopic compositions indicate that Mg-rich olivines are unlikely to be of nebular origin (i.e., solar nebula condensates) but are more likely debris of broken differentiated planetesimals (each of them being characterized by a given ?¹⁷O). Mg-rich olivines could have crystallized from magma ocean-like environments on partially molten planetesimals undergoing metal–silicate differentiation processes. Considering the very old age of chondrules, Mg-rich olivine grains or aggregates might be considered as millimeter-sized fragments from disrupted first-generation differentiated planetesimals. Finally, the finding of only a small number of discrete ?¹⁷O modes for Mg-rich olivines grains or aggregates in a given chondrite suggests that these shattered fragments have not been efficiently mixed in the disk and/or that chondrite formation occurred in the first vicinity of the breakup of these planetary bodies.     

Origin of magmatic sulfides in a Proterozoic island arc—an example from the Portneuf–Mauricie Domain,Grenville Province,Canada

The Portneuf–Mauricie Domain (PMD), located in the south-central part of the Grenville province, contains Mesoproterozoic Ni–Cu ± platinum-group element (PGE) prospects hosted in a variety of plutonic intrusions (layered, with simple structures, or zoned) and emplaced in a mature island arc setting. A two-stage model is envisaged to explain the formation of magmatic sulfides. An early loss of a small amount of sulfides in the conduits of primitive, hydrous mantle-derived melts under high fO₂, resulted in depletion of the magmas in chalcophile and precious metals (Cu/Pd ratios vary from initial mantle values up to 1.6 × 10⁶). Then, nearer the mineralized zones, the magmas interacted with sulfide-bearing country rocks, resulting in felsification of the magmas, assimilation of crustal sulfur (δ ³⁴S values up to +5.5‰), and the formation of an immiscible sulfide liquid. Liquid-sulfide formation was followed by variable interactions between the silicate and sulfide magmas, which were responsible for the enrichment of sulfides in Ni, Cu, and, locally, PGE. Indeed, low R factors are found for prospects hosted in intrusions with a simple internal structure and in layered intrusions whereas high R factors are found for prospects hosted in zoned intrusions. Finally, sulfide melt may have been partly incorporated into later pulses of magma and injected into shallow magma chambers to form the PMD prospects. The PMD prospects share common characteristics with other well-known deposits (Aguablanca, Vammala, Stormyrplunen, and deposits in Alaskan/Ural-type intrusions), attesting to the Ni, Cu, and PGE potential of deposits associated with subduction-zone settings.     

Ontogenetic Habitat Shifts of the Atlantic Tomcod (<Emphasis Type="Italic">Microgadus tomcod</Emphasis>) Across an Estuarine Transition Zone

Tomcod (Microgadus tomcod) in the St. Lawrence estuarine transition zone (ETZ) undergo an ontogenetic habitat shift. Older age classes, characterised by a male-dominated sex ratio, disperse downstream over the summer months to occupy the colder more saline waters of the estuary. Significant differences in length and mass along the salinity gradient were observed in September with upstream fish of any given age class generally exhibiting greater growth. These differences were not seen in early summer. Benthic amphipod δ ³⁴S signatures were strongly correlated with salinity and served to demonstrate that tomcod δ ³⁴S signatures were not in isotopic equilibrium in the more saline waters of the ETZ. Seasonal distributional patterns, growth dynamics and isotopic disequilibrium all indicate that the observed habitat shift may occur on an annual basis, following winter aggregation in warmer, less saline waters. Tomcod located in the downstream parts of the ETZ, predominantly males, were significantly more sexually developed than upstream tomcod for a given age. On the other hand, greater growth early in life is insured by occupying warmer, upstream waters during the summer months.     

Groundwater exploitation and recharge rate estimation of a quaternary sand aquifer in Dar-es-Salaam area,Tanzania

Dar-es-Salaam City gets water supply from surface water and groundwater. The groundwater is used to supplement surface water supply and has increasingly become a major source of water supply in the city. The study area comprises three major parts: the central coastal plain with quaternary fluvial–deltaic sediments, the deltaic Mio-Pliocene clay-bound sands and gravels in the northwest and southeast and the Lower Miocene fluviatile sandstones of Pugu Hills in the west of the study area. The main objective of this study was to quantify the integrated water balance. The major source of renewable groundwater in the aquifer is rainfall. Hence, the average recharge of 256.2 mm/year (for the year 2006) to the aquifer was estimated using the balance method of Thornthwaite and Mather, which is equal to 99.4 hm³/year for the whole alluvial aquifer. This value was balanced with total groundwater abstraction of 8.59 hm³/year, baseflow to rivers of 75.7 hm³/year and discharge into the sea (15.11 hm³/year).     

Overview of the subsurface structural pattern of the Paris Basin (France): Insights from the reprocessing and interpretation of regional seismic lines

The study presents the methodology used by the French Geological Survey (BRGM) for the building, reprocessing and interpretation of selected regional seismic lines in the Paris intracratonic basin (France): the 14 constructed E-W and N-S regional transects represent a total of 2,516 km length, and are based on the merge of 240 seismic single profiles recorded by petroleum operators between 1971 and 1995. The regional lines have been selected to cross the main oil fields of the Paris Basin, as well as high potential areas for oil exploration. A first difficulty was to recover the raw data necessary to build-up the regional transects. The signal reprocessing, harmonization and merge of the single seismic lines, constituent of the regional transects, are then described; these operations represent the cornerstone of the study. We put the emphasis on the primary static corrections, as the targeted structures are commonly spatially associated with large seismic velocity variations in the upper Cretaceous chalk and Tertiary sedimentary cover.The interpreted regional transects definitely give complementary information to the existing studies, which generally lack seismic (and therefore structural) data: we give an overview of the main structural and geometrical features of the Paris Basin: inversion structures, major unconformities, as well as Permo-Carboniferous basins. We also describe the structural pattern, and show the close relationships between the faults geometry, the faults density, and the geological evolution of the Paris Basin: we distinguish (1) few large-scale polyphase faults, with a Variscan origin, representing the first order structural frame of the Paris Basin; (2) monophase normal faults, with strike-slip features, representing the subsurface prolongation of Cenozoic grabens cropping out in the neighbourhood; (3) deep normal faults, sealed by the base Calcareous Dogger sequence, related to the Permo-Liassic extensional tectonic regime. This large-scale view of the Paris Basin has highlighted several potential exploration targets.     

Measuring the accessibility of different household income groups to basic community services in upland Misamis Oriental,Northern Mindanao,Philippines

Improving household accessibility to basic community services can help reduce poverty in upland areas. In this study, spatial analysis with GIS was used to measure the accessibility of different household income groups to community services in the landlocked upland municipality Claveria in Northern Mindanao, the Philippines. Important community services were identified through villagers' participation in a matrix‐scoring activity. Travel information was derived from key informant interviews while the geographical coordinates of sample households and important services were collected using GPS receivers. The Flowmap GIS software (version 7.2) was used to compute accessibility to services along the road network by habal‐habal (two‐wheel motorcycle). Outcomes from the participatory data gathering activities revealed that agricultural, educational and health facilities, as well as government services are important to the community to achieve sustainable livelihoods. Because local people perceive accessibility in terms of monetary costs, rather than distance, road distance measurements were converted into fare costs. Results of the accessibility analysis show that higher‐income household groups generally incur lower mean one‐way travel costs to reach important community services than poorer households. However, almost all households spend more than the daily per capita poverty threshold for the province to reach basic community services. A scenario to improve accessibility to services in the study area was investigated to emphasize the potential of GIS‐based accessibility analysis in rural service planning.     

Age and geochemistry of the Newania dolomite carbonatites, India: implications for the source of primary carbonatite magma

The Newania carbonatite complex of India is one of the few dolomite-dominated carbonatites of the world. Intruding into Archean basement gneisses, the rocks of the complex have undergone limited diversification and are not associated with any alkaline silicate rock. Although the magmatic nature of the complex was generally accepted, its age of emplacement had remained equivocal because of the disturbed nature of radioisotope systems. Many questions about the nature of its mantle source and mode of origin had remained unanswered because of lack of geochemical and isotopic data. Here, we present results of our effort to date the complex using ¹⁴⁷Sm–¹⁴³Nd, ²⁰⁷Pb–²⁰⁶Pb and ⁴⁰Ar–³⁹Ar dating techniques. We also present mineral chemistry, major and trace element geochemistry and Sr–Nd isotopic ratio data for these carbonatites. Our age data reveal that the complex was emplaced at ~1,473 Ma and parts of it were affected by a thermal event at ~904 Ma. The older ²⁰⁷Pb–²⁰⁶Pb ages reported here (~2.4 Ga) and by one earlier study (~2.3 Ga; Schleicher et al. Chem Geol 140:261–273, 1997) are deemed to be a result of heterogeneous incorporation of crustal Pb during the post-emplacement thermal event. The thermal event had little effect on many magmatic signatures of these rocks, such as its dolomite–magnesite–ankerite–Cr-rich magnetite–magnesio-arfvedsonite–pyrochlore assemblage, mantle like δ¹³C and δ¹⁸O and typical carbonatitic trace element patterns. Newania carbonatites show fractional crystallization trend from high-Mg to high-Fe through high-Ca compositions. The least fractionated dolomite carbonatites of the complex possess very high Mg# (≥80) and have similar major element oxide contents as that of primary carbonatite melts experimentally produced from peridotitic sources. In addition, lower rare earth element (and higher Sr) contents than a typical calcio-carbonatite and mantle like Nb/Ta ratios indicate that the primary magma for the complex was a magnesio-carbonatite melt and that it was derived from a carbonate bearing mantle. The Sr–Nd isotopic data suggest that the primary magma originated from a metasomatized lithospheric mantle. Trace element modelling confirms such an inference and suggests that the source was a phlogopite bearing mantle, located within the garnet stability zone.