Collagen fingerprinting for the species identification of archaeological amphibian remains

Amphibians are well known as being one of the main groups of animals today most threatened by environmental changes but they are also some of the least well understood of all terrestrial vertebrates. This gap in knowledge is much greater as we look further back into the relatively recent past, despite representing an invaluable resources in archaeological and palaeontological assemblages that are more indicative of palaeoclimate conditions than most other vertebrate taxa. This in part stems from their remains being typically much less studied, partly due to the less common forms of expertise required for identifications based on skeletal morphology – the most frequently observed tissue that remains in ancient assemblages. Here we apply a method of biomolecular species identification by collagen peptide mass fingerprinting to the British Late Pleistocene assemblage of Pin Hole Cave (Creswell Crags, UK) as well as a range of relevant extant taxa for comparison. Our results demonstrate the ability to separate at the species level with all modern taxa investigated, allowing for the identification of these archaeological remains to the amphibian taxa known to exist in Late Pleistocene Britain. Analyses of the Pin Hole assemblage found a dominance of the two species previously known from the site (common frogs and toads: Rana temporaria and Bufo bufo, respectively) and also a small number of the rarer natterjack toad (Epidalea calamita) not previously identified in the Creswell Crags region but known from other sites in the UK; additionally, one specimen appeared to yield the fingerprint of the moor frog (R. arvalis), now extinct in the UK. As such, collagen fingerprinting is here shown to widen the known palaeobiodiversity of taxa, and highlights the further potential to enhance our understanding of climate change in the past.     

Towards Improved Remedial Outcomes in Categorical Aquifers with an Iterative Ensemble Smoother

Categorical parameter distributions consisting of geologic facies with distinct properties, for example, high-permeability channels embedded in a low-permeability matrix, are common at contaminated sites. At these sites, low-permeability facies store solute mass, acting as secondary sources to higher-permeability facies, sustaining concentrations for decades while increasing risk and cleanup costs. Parameter estimation is difficult in such systems because the discontinuities in the parameter space hinder the inverse problem. This paper presents a novel approach based on Traveling Pilot Points (TRIPS) and an iterative ensemble smoother (IES) to solve the categorical inverse problem. Groundwater flow and solute transport in a hypothetical aquifer with a categorical parameter distribution are simulated using MODFLOW 6. Heads and concentrations are recorded at multiple monitoring locations. IES is used to generate posterior ensembles assuming a TRIPS prior and an approximate multi-Gaussian prior. The ensembles are used to predict solute concentrations and mass into the future. The evaluation also includes an assessment of how the number of measurements and the choice of the geological prior determine the characteristics of the posterior ensemble and the resulting predictions. The results indicate that IES was able to efficiently sample the posterior distribution and showed that even with an approximate geological prior, a high degree of parameterization and history matching could lead to parameter ensembles that can be useful for making certain types of predictions (heads, concentrations). However, the approximate geological prior was insufficient for predicting mass. The analysis demonstrates how decision-makers can quantify uncertainty and make informed decisions with an ensemble-based approach.     

Comparison of environmental tracers including organic micropollutants as groundwater exfiltration indicators into a small river of a karstic catchment

Understanding groundwater–surface water (GW–SW) interactions is vital for water management in karstic catchments due to its impact on water quality. The objective of this study was to evaluate and compare the applicability of seven environmental tracers to quantify and localize groundwater exfiltration into a small, human-impacted karstic river system. Tracers were selected based on their emission source to the surface water either as (a) dissolved, predominantly geogenic compounds (radon-222, sulphate and electrical conductivity) or (b) anthropogenic compounds (predominantly) originating from wastewater treatment plant (WWTP) effluents (carbamazepine, tramadol, sodium, chloride). Two contrasting sampling approaches were compared (a) assuming steady-state flow conditions and (b) considering the travel time of the water parcels (Lagrangian sampling) through the catchment to account for diurnal changes in inflow from the WWTP. Spatial variability of the concentrations of all tracers indicated sections of preferential groundwater inflow. Lagrangian sampling techniques seem highly relevant for capturing dynamic concentration patterns of WWTP-derived compounds. Quantification of GW inflow with the finite element model FINIFLUX, based on observed in-stream Rn activities led to plausible fluxes along the investigated river reaches (0.265 m³ s⁻¹), while observations of other natural or anthropogenic environmental tracers produced less plausible water fluxes. Important point sources of groundwater exfiltration can be ascribed to locations where the river crosses geological fault lines. This indicates that commonly applied concepts describing groundwater–surface water interactions assuming diffuse flow in porous media are difficult to transfer to karstic river systems whereas concepts from fractured aquifers may be more applicable. In general, this study helps selecting the best suited hydrological tracer for GW exfiltration and leads to a better understanding of processes controlling groundwater inflow into karstic river systems.     

Innovative Techniques for Measuring the Oil Content of Oil-Contaminated Porous Media

The oil content of oil-contaminated porous media is an important parameter for the assessment and remediation of oil pollution in soil and groundwater. However, an accurate measurement method is not available. In this study, we propose a new equation to calculate the oil content of water-bearing media based on traditional extraction–ultraviolet spectroscopy. Further, an improved experimental method was developed. The results indicate that the pure solid weight and oil content of oil-contaminated media can be accurately determined by introducing the oil drying loss coefficient (γ). The average relative errors of the improved method range from −0.14% to −0.96%. They are much smaller than errors of −4.49% to −10.97% of the original methods, indicating that the accuracy of measured oil content is enhanced. In addition, the accuracy of the new method does not depend on oil volatility and oil content.     

Rates of rockwall slope erosion in the upper Bhagirathi catchment,Garhwal Himalaya

Rockwall slope erosion is defined for the upper Bhagirathi catchment using cosmogenic Beryllium-10 (¹⁰Be) concentrations in sediment from medial moraines on Gangotri glacier. Beryllium-10 concentrations range from 1.1 ± 0.2 to 2.7 ± 0.3 × 10⁴ at/g SiO₂, yielding rockwall slope erosion rates from 2.4 ± 0.4 to 6.9 ± 1.9 mm/a. Slope erosion rates are likely to have varied over space and time and responded to shifts in climate, geomorphic and/or tectonic regime throughout the late Quaternary. Geomorphic and sedimentological analyses confirm that the moraines are predominately composed of rockfall and avalanche debris mobilized from steep relief rockwall slopes via periglacial weathering processes. The glacial rockwall slope erosion affects sediment flux and storage of snow and ice at the catchment head on diurnal to millennial timescales, and more broadly influences catchment configuration and relief, glacier dynamics and microclimates. The slope erosion rates exceed the averaged catchment-wide and exhumation rates of Bhagirathi and the Garhwal region on geomorphic timescales (10³−10⁵ years), supporting the view that erosion at the headwaters can outpace the wider catchment. The ¹⁰Be concentrations of medial moraine sediment for the upper Bhagirathi catchment and the catchments of Chhota Shigri in Lahul, northern India and Baltoro glacier in Central Karakoram, Pakistan show a tentative relationship between ¹⁰Be concentration and precipitation. As such there is more rapid glacial rockwall slope erosion in the monsoon-influenced Lesser and Greater Himalaya compared to the semi-arid interior of the orogen. Rockwall slope erosion in the three study areas, and more broadly across the northwest Himalaya is likely governed by individual catchment dynamics that vary across space and time. © 2019 The Authors. Earth Surface Processes and Landforms Published by John Wiley & Sons, Ltd.     

Direct finite element method for nonlinear earthquake analysis of concrete dams: Simplification,modeling, and practical application

A direct finite element (FE) method for nonlinear response history analysis of semi-unbounded dam-water-foundation systems has recently been presented. The analysis procedure employs standard viscous-damper absorbing boundaries to model the semi-unbounded foundation and fluid domains and specifies the seismic input as effective earthquake forces—determined from a control motion defined at the foundation surface—at these boundaries. Presented in this paper are several simplifications to this direct FE method that greatly facilitates its implementation in commercial FE software. Also addressed is the modeling of the principal nonlinear mechanisms for concrete dams, calibration of damping in the numerical model to ensure consistency with values measured at actual dams, and practical procedures for implementation of the direct FE method with a commercial FE program.     

26Al and 10Be dating of late pleistocene and holocene fill terraces: a record of fluvial deposition and incision,Colorado front range

Cosmogenic ²⁶Al, ¹⁰Be, and ¹⁴C dating of fluvial fill terraces in steep canyons of the Colorado Front Range provides a temporal framework for analysing episodic aggradation and incision. Results from Boulder Canyon show that terrace heights above the modern channel (grade) can be divided into: (1) Bull Lake (≳100 ka; 20–15 m above grade); (2) Pinedale (32–10 ka; 15–4 m above grade); and (3) Holocene age (<4 m above grade). No pre‐Bull Lake deposits are preserved along Boulder Canyon, and only three small remnants >15 m above grade record Bull Lake deposition. Well‐preserved terraces of Pinedale age suggest that the range of terrace height above grade reflects short‐term fluctuations in the river profile during periods of rapidly changing stream load and power. Net river incision apparently occurred during transitions to interglacial periods. Soil development and stratigraphic position, along with limited cosmogenic and ¹⁴C dating, suggest that ∼130 ka terraces in Boulder Canyon correlate with the Louviers Alluvium, and that 32 to 10 ka fills in the canyon correlate with the Broadway Alluvium on the adjacent High Plains. Late Pleistocene incision rates (∼0·15 m ka⁻¹) along Boulder Canyon exceed pre‐late Pleistocene incision rates, and are higher than middle to late Pleistocene incision rates (∼0·04 m ka⁻¹) on the High Plains. This study provides an example of how modern geochronologic techniques allow us to understand better rivers that drain glaciated catchments. Copyright © 2002 John Wiley & Sons, Ltd.     

Swelling behaviour of expansive soil treated with fly ash–GGBS based binder

In this article, the potential of a binder developed by admixing fly ash and ground granulated blast furnace slag (GGBS) to stabilise expansive soils is evaluated. Laboratory tests included determination of free swell index, swell potential and swelling pressure tests of the soil/binder mixtures at different mixing ratio. The test results showed decrease in the swelling behaviour of the soil with increase in binder content. The percent swell–time relationship was observed to fit the hyperbolic curves enabling us to predict the ultimate percent swell from few initial test results. Addition of 1% of lime to the binder showed further improvement in reducing swelling. A good linear relationship is established between percent oedometer swell and modified free swell index (MFSI) for soil/binder mixtures without lime but the same has not been observed in the presence of lime. The compressibility characteristics of the soil/binder mixtures reduced nominally with increase in binder content but in the presence of lime, the compressibility reduced significantly. Binder used in this study has been found to be effective and economic to stabilise expansive soils with lesser amount of chemical additives such as lime.     

A framework for the evaluation of ground motion selection and modification procedures

This study develops a framework to evaluate ground motion selection and modification (GMSM) procedures. The context is probabilistic seismic demand analysis, where response history analyses of a given structure, using ground motions determined by a GMSM procedure, are performed in order to estimate the seismic demand hazard curve (SDHC) for the structure at a given site. Currently, a GMSM procedure is evaluated in this context by comparing several resulting estimates of the SDHC, each derived from a different definition of the conditioning intensity measure (IM). Using a simple case study, we demonstrate that conclusions from such an approach are not always definitive; therefore, an alternative approach is desirable. In the alternative proposed herein, all estimates of the SDHC from GMSM procedures are compared against a benchmark SDHC, under a common set of ground motion information. This benchmark SDHC is determined by incorporating a prediction model for the seismic demand into the probabilistic seismic hazard analysis calculations. To develop an understanding of why one GMSM procedure may provide more accurate estimates of the SDHC than another procedure, we identify the role of ‘IM sufficiency’ in the relationship between (i) bias in the SDHC estimate and (ii) ‘hazard consistency’ of the corresponding ground motions obtained from a GMSM procedure. Finally, we provide examples of how misleading conclusions may potentially be obtained from erroneous implementations of the proposed framework. Copyright © 2014 John Wiley & Sons, Ltd.