Chemical composition,volatile components,and trace elements in melts of the Karymskii volcanic center,Kamchatka, and Golovnina volcano,Kunashir Island: Evidence from inclusions in minerals

Melt inclusions were examined in phenocrysts in basalt, andesite, dacite, and rhyodacite from the Karymskii volcanic center in Kamchatka and dacite form Golovnina volcano in Kunashir Island, Kuriles. The inclusions were examined by homogenization and by analyzing glasses in more than 80 inclusions on an electron microscope and ion microprobe. The SiO₂ concentrations in the melt inclusions in plagioclase phenocrysts from basalts from the Karymskii volcanic center vary from 47.4 to 57.1 wt %, these values for inclusions in plagioclase phenocrysts from andesites are 55.7–67.1 wt %, in plagioclase phenocrysts from the dacites and rhyodacites are 65.9–73.1 wt %, and those in quartz in the rhyodacites are 72.2–75.7 wt %. The SiO₂ concentrations in melt inclusions in quartz from dacites from Golovnina volcano range from 70.2 to 77.0 wt %. The basaltic melts are characterized by usual concentrations of major components (wt %): TiO₂ = 0.7–1.3, FeO = 6.8–11.4, MgO = 2.3–6.1, CaO = 6.7–10.8, and K₂O = 0.4–1.7; but these rocks are notably enriched in Na₂O (2.9–7.4 wt % at an average of 5.1 wt %, with the highest Na₂O concentration detected in the most basic melts: SiO₂ = 47.4–52.0 wt %. The concentrations of volatiles in the basic melts are 1.6 wt % for H₂O, 0.14 wt % for S, 0.09 wt % for Cl, and 50 ppm for F. The andesite melts are characterized by high concentrations (wt %) of FeO (6.5 on average), CaO (5.2), and Cl (0.26) at usual concentrations of Na₂O (4.5), K₂O (2.1), and S (0.07). High water concentrations were determined in the dacite and rhyodacite melts: from 0.9 to 7.3 wt % (average of 15 analyses equals 4.5 wt %). The Cl concentration in these melts is 0.15 wt %, and those of F and S are 0.06 and 0.01 wt %, respectively. Melt inclusions in quartz from the dacites of Golovnina volcano are also rich in water: they contain from 5.0 to 6.7 wt % (average 5.6 wt %). The comparison of melt compositions from the Karymskii volcanic center and previously studied melts from Bezymyannyi and Shiveluch volcanoes revealed their significant differences. The former are more basic, are enriched in Ti, Fe, Mg, Ca, Na, and P but significantly depleted in K. The melts of the Karymskii volcanic center are most probably less differentiated than the melts of Bezymyannyi and Shiveluch volcanoes. The concentrations of water and 20 trace elements were measured in the glasses of 22 melt inclusions in plagioclase and quartz from our samples. Unusually high values were obtained for Li concentrations (along with high Na concentrations) in the basaltic melts from the Karymskii volcanic center: from 118 to 1750 ppm, whereas the dacite and rhyolite melts contain 25 ppm Li on average. The rhyolite melts of Golovnina volcano are much poorer in Li: 1.4 ppm on average. The melts of the Karymskii volcanic center are characterized by relative minima at Nb and Ti and maxima at B and K, as is typical of arc magmas.     

National-scale estimation of potentially harmful element ambient background concentrations in topsoil using parent material classified soil:stream–sediment relationships

Regulatory authorities require estimates of ambient background concentrations (ABCs) of potentially harmful elements (PHEs) in topsoil; such data are currently not available in many countries. High resolution soil geochemical data exist for only part of England and Wales, whilst stream sediment data cover the entire landscape. A novel methodology is presented for estimating soil equivalent ABCs for PHEs from high-resolution (HR) stream sediment geochemical data grouped by common parent materials (PM), using arsenic (As) as an example. Geometric mean (GM) values for local PM groups are used to investigate different approaches for transforming sediment to soil equivalent concentrations. Holdout validation is used to assess: (i) the optimum number of samples for calculating local GM values, and (ii) the optimum scale at which to group data when using linear regression analysis to estimate GM soil ABCs from local sediment geochemical values. Holdout validation showed that the smallest differences were generally observed when five observations were used to calculate the GM and that these should be grouped over the smallest possible area in order to encompass soils over PMs with elevated GM As concentrations. Geometric mean ABCs are estimated and mapped for As in mineral soil across all of England and Wales within delineations of PM polygons. Errors for the estimation of soil equivalent GM As ABCs based on sediment data for an independent validation set were of a similar magnitude to those from holdout validation applied to the original data suggesting the approach is robust. The estimates of soil equivalent ABCs suggest that As exceeds the regulatory threshold used in risk assessments for residential land use (20 mg kg⁻¹) across 16% of the landscape of England and Wales. The applicability of the method for cognate landscapes, and potential refinements is discussed.     

Methodology of hydrogeological characterization of deep carbonate aquifers as potential reservoirs of groundwater. Case of study: the Jurassic aquifer of <Emphasis Type="Italic">El Maestrazgo</Emphasis> (Castellón,Spain)

A methodology for the characterization of deep carbonate aquifers has been developed and applied to El Maestrazgo Jurassic aquifer in Castellón, Spain. Characterization of these aquifer formations, located at more than 300 m deep, consisted of a previous phase of compilation, analysis and synthesis of the existing information about the area, followed by a coordinated combination of different speciality studies: geology, stratigraphy, structural analysis, hydrogeology, hydrochemistry, geophysics and remote sensing. Geological studies included geological mapping, definition of stratigraphical units and facies and structural analysis. The aim of the hydrogeology study was to define aquifer formations, recharge area, aquifer points inventory and groundwater flow directions for the establishment of piezometric and water quality observation nets. Special techniques were applied, like thermal infrared aerial images and the evaluation of submarine groundwater discharge by means of natural radium isotopes. Hydrochemical techniques, including majority elements characterization and stable isotopes (¹⁸O, ²H and ³H) determination, allowed classifying hydrochemical facies and establishing a renewal pattern for water within the system. Geophysics was useful in determining the aquifer geometry, the features of the basement and the petrophysical characteristics of the geological formations. Preliminary results show an important tectonic complexity and the possibilities for groundwater uses in the area of study.     

Detection of free vertical convection and double-diffusion in groundwater monitoring wells with geophysical borehole measurements

Two algorithms for in-situ detection and identification of vertical free convective and double-diffusive flows in groundwater monitoring wells or boreholes are proposed. With one algorithm the causes (driving forces) and with the other one the effects (convection or double-diffusion) of vertical transport processes can be detected based on geophysical borehole measurements in the water column. Five density-driven flow processes are identified: thermal, solutal, and thermosolutal convection leading to an equalization, as well as saltfingers and diffusive layering leading to an intensification of a vertical density gradient. The occurrence of density-driven transport processes could be proven in many groundwater monitoring wells and boreholes; especially shallow sections of boreholes or groundwater monitoring wells are affected dramatically by such vertical flows. Deep sections are also impaired as the critical threshold for the onset of a density-driven flow is considerably low. In monitoring wells or boreholes, several sections with different types of density-driven vertical flows may exist at the same time. Results from experimental investigations in a medium-scale testing facility with high aspect ratio (height/radius = 19) and from numerical modeling of a water column agree well with paramters of in-situ detected convection cells.     

Implementation of reconstructed geomorphologic units in landslide susceptibility mapping: the Melen Gorge (NW Turkey)

In the international literature, although considerable amount of publications on the landslide susceptibility mapping exist, geomorphology as a conditioning factor is still used in limited number of studies. Considering this factor, the purpose of this article paper is to implement the geomorphologic parameters derived by reconstructed topography in landslide susceptibility mapping. According to the method employed in this study, terrain is generalized by the contours passed through the convex slopes of the valleys that were formed by fluvial erosion. Therefore, slope conditions before landsliding can be obtained. The reconstructed morphometric and geomorphologic units are taken into account as a conditioning parameter when assessing landslide susceptibility. Two different data, one of which is obtained from the reconstructed DEM, have been employed to produce two landslide susceptibility maps. The binary logistic regression is used to develop landslide susceptibility maps for the Melen Gorge in the Northwestern part of Turkey. Due to the high correct classification percentages and spatial effectiveness of the maps, the landslide susceptibility map comprised the reconstructed morphometric parameters exhibits a better performance than the other. Five different datasets are selected randomly to apply proper sampling strategy for training. As a consequence of the analyses, the most proper outcomes are obtained from the dataset of the reconstructed topographical parameters and geomorphologic units, and lithological variables that are implemented together. Correct classification percentage and root mean square error (RMSE) values of the validation dataset are calculated as 86.28% and 0.35, respectively. Prediction capacity of the different datasets reveal that the landslide susceptibility map obtained from the reconstructed parameters has a higher prediction capacity than the other. Moreover, the landslide susceptibility map obtained from the reconstructed parameters produces logical results.     

The role of the volatile phase for REE and Y fractionation in low-silica carbonate magmas: implications from natural carbonatites, Namibia

Summary Two bimodal carbonatite complexes in Namibia of Cretaceous age are explored as to the presence and composition of a coexisting carbonatitic fluid. The Kalkfeld and Ondurakorume complexes contain both Ca- and Mg/Fe-carbonatites, composed of calcite alone or calcite with ferroan dolomite, fluorapatite and strontianite. The major element evolution in the bulk rocks from s?vites to beforsites is due to crystallization of calcite and fluorapatite. All carbonatites show a negative Y anomaly in normalised REE plots. Fractionation is accompanied by successively lower HREE contents between Tb and Yb, expressed by the ratios Nd/Ho and Ho/Lu. The evolution of this downward-facing hump goes along with decreasing Y contents in bulk rocks and minerals. All this requires an additional phase coexisting with the carbonate liquid during fractionation. Comparison between the bulk rocks and the expelled fluid shows that the latter had preferentially accumulated the HREE and Y. Further evidence for this process are hydrothermal, HREE, Y-rich fluorites in other carbonatite complexes which reflect the composition of the expelled fluid. The high strength of fluoride complexes suggests that fluoride complexing in the carbonatitic fluid is the process responsible for extracting HREE and Y from the carbonatite magma, leaving fractionated carbonatite rocks depleted in these elements. The geochemical evolution of carbonatite magmas along fractionation has therefore to be considered in a melt-mineral-fluid system. Correspondence: B. Bühn, Instituto de Geociências, Universidade de Brasilia, Campus Universitário Darcy Ribeiro, Brasilia 70910-900, Brazil     

The Messinian Sicilian stratigraphy revisited: new insights for the Messinian salinity crisis

Controversies around the Messinian salinity crisis (MSC) are because of the difficulties in establishing genetic and stratigraphic relationships between its deep and shallow‐water record. Actually, the Sicilian foreland basin shows both shallow and deep‐water Messinian records, thus offering the chance to reconstruct comprehensive MSC scenarios. The Lower Gypsum of Sicily comprises primary and resedimented evaporites separated in space and time by the intra‐Messinian unconformity. A composite unit including halite, resedimented gypsum and Calcare di Base accumulated between 5.6 and 5.55 Ma in the main depocentres; it records the acme of the Messinian Salinity Crisis during a tectonic phase coupled with sea‐level falls at glacials TG14‐TG12. These deposits fully post‐date primary gypsum, which precipitated in shallow‐water wedge‐top and foreland ramp basins between 5.96 and 5.6 Ma. This new stratigraphic framework results in a three‐stage MSC scenario characterized by different primary evaporite associations: selenite in the first and third stages, carbonate, halite and potash salt in the second one associated with hybrid resedimented evaporites.     

THE LAUSANNE CONGRESS

The International Society for Photogrammetry held the Xlth International Congress at Lausanne during July 1968. The authors review the activities of five of the seven I.S.P. Commissions.