QuakeIST<Superscript>®</Superscript> earthquake scenario simulator using interdependencies

Earthquakes are a permanent threat to urban environments worldwide. The communication of the related risk demands accurate damage model simulations and an interactive visualization of results. The aim of this paper is to provide a realistic problem-solving environment for earthquake discussions among decision makers, stakeholders, and the general public. QuakeIST^® is an integrated earthquake simulator developed by Instituto Superior Técnico (Lisbon University), oriented towards the performance of risk calculations concerning damage propagations that use the Disruption Index concept. This software imports data stored in a GIS environment, handles different ground motion scenarios, and deals with a complex situation of different soils and vulnerabilities of various layers of civil structures (buildings, lifelines, and other urban structures). It models interdependencies between several infrastructures and between infrastructures and the urban tissue. The computer programme is very versatile, written in separate modules, allowing an experimented user to incorporate new formulations. Results can be treated with any statistical application and most common GIS commercial environments can produced their geographic visualization. Current progress and new upcoming are briefly described at the end of the paper.     

Evolution of anthropogenic and biomass burning emissions of air pollutants at global and regional scales during the 1980�C2010 period

Several different inventories of global and regional anthropogenic and biomass burning emissions are assessed for the 1980?C2010 period. The species considered in this study are carbon monoxide, nitrogen oxides, sulfur dioxide and black carbon. The inventories considered include the ACCMIP historical emissions developed in support of the simulations for the IPCC AR5 assessment. Emissions for 2005 and 2010 from the Representative Concentration Pathways (RCPs) are also included. Large discrepancies between the global and regional emissions are identified, which shows that there is still no consensus on the best estimates for surface emissions of atmospheric compounds. At the global scale, anthropogenic emissions of CO, NO_x and SO₂ show the best agreement for most years, although agreement does not necessarily mean that uncertainty is low. The agreement is low for BC emissions, particularly in the period prior to 2000. The best consensus is for NO_x emissions for all periods and all regions, except for China, where emissions in 1980 and 1990 need to be better defined. Emissions of CO need better quantification in the USA and India for all periods; in Central Europe, the evolution of emissions during the past two decades needs to be better determined. The agreement between the different SO₂ emissions datasets is rather good for the USA, but better quantification is needed elsewhere, particularly for Central Europe, India and China. The comparisons performed in this study show that the use of RCP8.5 for the extension of the ACCMIP inventory beyond 2000 is reasonable, until more global or regional estimates become available. Concerning biomass burning emissions, most inventories agree within 50?C80%, depending on the year and season. The large differences between biomass burning inventories are due to differences in the estimates of burned areas from the different available products, as well as in the amount of biomass burned.     

Geochemistry of granites and metasediments of the urban area of Vila Real (northern Portugal) and correlative radon risk

Radon concentration was evaluated in dwellings of the urban area of Vila Real (Northern Portugal). The area is mainly composed of Hercynian granites and Cambrian metasediments, and CR-39 passive detectors (n = 112) were used for the purpose. The results obtained in winter conditions suggest that the most productive geological unit is the Hercynian granite G1 (geometric mean of 364 Bq/m³), while Cambrian metasediments of the Douro Group show the lowest average indoor radon concentration (236 Bq/m³). The geological, geochemical and radiological data obtained suggest that the most effective control on the radon concentrations of the area is related with the uranium content of the rocks; indeed, the highest contents were observed in granite G1 (21 ppm) and the lowest in the metasediments (3 ppm). This is also confirmed by the results obtained for groundwater, where granites present the highest concentrations of dissolved radon (up to 938 Bq/l), uranium (5–18 ppb) and gross α activities (0.47–0.92 Bq/l). No important radiometric anomalies were found in relation with geological structures such as faults, veins and contacts, but a moderate increase of the uranium content can occur locally in such structures. Petrographic observations and SEM studies show that uranium is mainly contained within the rock in heavy accessory minerals (apatite, zircon, monazite, xenotime), which reduces radon emanation. Notwithstanding, due to the high U contents granites show a significant potential to induce indoor radon concentrations in dwellings in excess of the recommended value of 400 Bq/m³. Overall, we can conclude that the region of Vila Real presents a moderate to high radon risk in dwellings and groundwater.     

Removal of Copper,Nickel and Zinc Ions from Aqueous Solution by Chitosan‐8‐Hydroxyquinoline Beads

In this work, 8‐hydroxyquinoline is used as the active sites in cross‐linked chitosan beads with epichlorohydrin (CT‐8HQ). The CT‐8HQ material was shaped in bead form and used for heavy metal removal from aqueous solution. The study was carried out at pH 5.0 with both batch and column methods and the maximum adsorption capacity of metal ions by the CT‐8HQ was attained in 4 h in the batch experiment. The adsorption capacity order was: Cu²⁺ > Ni²⁺ > Zn²⁺ for both mono‐ and multi‐component systems with batch conditions. From breakthrough curves with column conditions, the adsorption capacity followed the order Cu²⁺ > Zn²⁺ > Ni²⁺ for both mono‐ and multi‐component systems. The CT‐8HQ beads maintained good metal adsorption capacity for all five cycles with absorbent restoration achieved with the use of 1.0 mol L^–1 HCl solution, with 90% regeneration.     

Fe,Mn, P and S Speciation in Sediments from the Capivara Hydroelectric Dam Lake (Brazil) as an Indicator of Anthropogenic Influences

The conservation of large water resources is essential for the preservation of human life. The quantification and, more importantly, the speciation of chemical substances that indicate the presence of anthropogenic contamination in water resources are of great importance. This paper presents the results of analysis for the determination of organic, inorganic and total phosphorus, pseudo‐sulfur, and iron and manganese, in five fractions, in water sediments collected from the Capivara Hydroelectric Power Plant, Brazil. A study on the seasonal variation of these parameters was conducted, with data having been collected in the winter and in the summer, at two sites along the dam, 5 km apart, close to the city of Primeiro de Maio. Phosphorous was found in sediments and adjacent soil in the organic form (OP), and was used as an indicator of anthropogenic influence on the reservoir banks. Speciation of potentially toxic Mn showed that it is present in the exchangeable fraction of the 0–5 cm depth layer (sediment/water interface), making its transfer to the water column possible. Results from this study showed that domestic and industrial effluent treatment measures are needed for the preservation of the quality of aquatic environments.     

Granite fracture index to check suitability of granite outcrops for quarrying

A correct knowledge of fracture patterns previous to quarrying is important for economical exploitation. This work comprises the general characterization of the discontinuities of 10 granite rock masses in NE Portugal. During the study some discontinuity characteristics such as orientation, persistence, aperture, trace length and spacing were evaluated. The differences in the characteristics of the selected granites were described, and the most important exploration factors were identified. In the granites studied, most of the joints are oriented from N10°E to N50°E, which is compatible with the regional fracture pattern. Concerning joint termination, the XX type is common, while the RR type is rare; the persistence index ranges from 3.5% to 25.4%. Closed joints are predominant in the granites studied (> 72.4%), and openings of the others are about 1–2 mm as a result of superficial displacement of the granite blocks. The percentage of filled joints, usually by quartz and pegmatite, is different from one granite to another, but most are < 20%. The average joint length ranges from 11.1 m in post-tectonics granites to 4.6 m in syntectonic granites. Joint spacing varies from 0.98 to 2.8 m with higher values in post-tectonic granites. Joint-space distributions of the granites studied are close to log-normal and exponential distributions. Volumetric joint count (Jv) ranges from 0.8 to 2.1 joints/m³ and is used for categorizing the places of each granite. The relationships between Jv and other joint characteristics, such as length, spacing and number of joint sets, were investigated. A Granite Fracturing Index (GFI) is introduced, computed on the basis of volumetric joint count, number of joint sets and true joint spacing. The GFI classification of studied places allows us evaluate the suitability for profitable exploitation.     

High-Frequency Response of the Atmospheric Electric Potential Gradient Under Strong and Dry Boundary-Layer Convection

The spectral response of atmospheric electric potential gradient gives important information about phenomena affecting this gradient at characteristic time scales ranging from years (e.g., solar modulation) to fractions of a second (e.g., turbulence). While long-term time scales have been exhaustively explored, short-term scales have received less attention. At such frequencies, space-charge transport inside the planetary boundary layer becomes a sizeable contribution to the potential gradient variability. For the first time, co-located (Évora, Portugal) measurements of boundary-layer backscatter profiles and the 100-Hz potential gradient are reported. Five campaign days are analyzed, providing evidence for a relation between high-frequency response of the potential gradient and strong dry convection.     

Biogeographical drivers of ragweed pollen concentrations in Europe

Theoretical and Applied Climatology - The drivers of spatial variation in ragweed pollen concentrations, contributing to severe allergic rhinitis and asthma, are poorly quantified. We analysed the...     

Post-LGM sedimentation on the outer shelf-upper slope of the northernmost part of the São Paulo Bight, southeastern Brazil

Sedimentary and isotope data as well as ¹⁴C AMS dating on 15 box cores were used to identify the main post-Last Glacial Maximum (LGM) processes in the outer shelf and upper slope of the northernmost part of the São Paulo Bight, southeastern Brazil. Results show slight but significant variations in calcium carbonate, total sulphur and nitrogen contents as well as carbon and oxygen isotope ratios. Sedimentation rates, varying from 5 to 184 mm kyr⁻¹ are controlled by the shelf and upper slope morphology, the Brazil Current meander dynamics, and the Coastal Water offshore motion.