Geodynamic evolution of the northern Molucca Sea area (Eastern Indonesia) constrained by 3-D gravity field inversion

In order to better understand the tectonic framework of the Northern Molucca Sea area, we inverted satellite and sea-surface gravity data into an iterative scheme including a priori seismological and geological data. The resulting 3-D density model images the various tectonic units from the surface down to 40 km. We proceed to various tests to assess the stability and robustness of our inversion. In particular, we performed an offset and average smoothing method to properly refine our results. The resulting model shows a striking vertical regularity of the structures through the different layers, whereas the density contrasts appear strongly uneven in the horizontal direction.The density model emphasizes the complexity of the upper lithospheric structure in the northern Molucca Sea, which is clearly dominated by the interaction between ophiolitic ridges, sedimentary wedges and rigid blocks of the Philippine Sea Plate. It also provides new, hard information that can be used in discussion of the evolution of the region.Large density variations are concentrated in the central part of northern Molucca Sea and dominate the upper lithospheric. North–south trending density structures along the Central Ridge and west dipping thrust faults on the western side of the region are clearly imaged. In the eastern part of the region, we distinguish several blocks, especially the Snellius Plateau which seems to be split into two parts. We interpret this as an oceanic plateau associated with thicker crust that previously belonged to the Philippine Sea Plate. This crust is now trapped between the Molucca Sea complex collision zone and the Philippine Trench, due to the development of a new subduction zone in its eastern side.     

High pressure polymorphism of dicalcium silicate Ca2SiO4. A transmission electron microscopy study

Ca₂SiO₄ dicalcium silicate has been transformed at high pressure in a diamond-anvil cell (DAC) coupled with a YAG laser heater, in order to study the high-pressure modifications of this compound. Starting material was the olivine form of Ca₂SiO₄ (γ-polymorph). Several samples have been synthesized at loading pressures of 4.5, 10 and 15 GPa respectively, at room temperature. Other samples have been obtained at pressures ranging between 4.5 and 45 GPa and temperatures estimated to be about 2500 °C. The study of the quenched high pressure and/or high temperature phases has been performed using analytical transmission electron microscopy (ATEM) and X-ray diffraction (XRD). All the polymorphs of Ca₂SiO₄ usually produced with high temperatures, including α-Ca₂SiO₄, have been observed in the samples recovered from the high-pressure experiments. The α′-Ca₂SiO₄ and α-Ca₂SiO₄ polymorphs have been obtained at ambient conditions for the first time without stabilizing impurities. A new modification of α′-Ca₂SiO₄ has also been synthesized. Finally, the breakdown at high-pressure and temperature of Ca₂SiO₄ into CaSiO₃ and CaO is reported.     

Complex conductivity response to microbial growth and biofilm formation on phenanthrene spiked medium

Several laboratory studies have recently demonstrated the utility of geophysical methods for the investigation of microbial-induced changes over contaminated sites. However, it remains difficult to distinguish the effects due to the new physical properties imparted by microbial processes, to bacterial growth, or to the development of bacterial biofilm. We chose to study the influence of biofilm formation on geophysical response using complex conductivity measurements (0.1-1000 Hz) in phenanthrene-contaminated media. Biotic assays were conducted with two phenanthrene (PHE) degrading bacterial strains: Burkholderia sp (NAH1), which produced biofilm and Stenophomonas maltophilia (MATE10), which did not, and an abiotic control. Results showed that bacterial densities for NAH1 and MATE10 strains continuously increased at the same rate during the experiment. However, the complex conductivity signature showed noticeable differences between the two bacteria, with a phase shift of 50 mrad at 4 Hz for NAH1, which produced biofilm. Biofilm volume was quantified by Scanning Confocal Laser Microscopy (SCLM). Significant correlations were established between phase shift decrease and biofilm volume for NAH1 assays. Results suggest that complex conductivity measurements, specifically phase shift, can be a useful indicator of biofilm formation inside the overall signal of microbial activity on contaminated sites.     

Total Mercury Distribution and Volatilization in Microcosms with and Without the Aquatic Macrophyte Eichhornia Crassipes

Mercury (Hg) is one of the most toxic pollutants and spreads in the environment according to its affinity to several compartments. Aquatic macrophytes, such as Eichhornia crassipes, are known as sites for accumulation of Hg and methylmercury formation. The objective of this research was to observe Hg distribution among air, water and whole plants of the macrophyte E. crassipes for 17?days. The distribution of a single ²⁰³Hg spike was evaluated by gamma spectrometry. Two experiments, with and without macrophytes, were made, and the compartments analyzed for the presence of Hg were air, 0.2-μm filtered water, suspended and settled particles, roots, leafs, petioles and adsorption on the desiccators walls. ²⁰³Hg was detected in all analyzed compartments, and the highest total Hg concentrations were found in the roots and particles of the incubations with and without macrophytes that retained in average 68 and 34?% of added Hg, respectively. On the other hand, the lowest concentrations were found in air for both incubations, with higher volatilization (up to 2.5?% of added Hg) in the absence of macrophytes. The lower Hg values in leafs and petioles suggest this plant has mechanisms of Hg retention in the roots. Results suggest this macrophyte promotes changes in the Hg cycle since it attracts most Hg present in water and particulate to its roots and settled particles underneath and also reduces Hg volatilization.     

Groundwater beneath the urban area of Khan Younis City,southern Gaza Strip (Palestine): hydrochemistry and water quality

Arabian Journal of Geosciences - This paper presents the results of a groundwater hydrochemical assessment in the urban area of Khan Younis City in the southern Gaza Strip by measuring its...     

High-pressure Raman spectroscopic study of Mn2GeO4, Ca2GeO4, Ca2SiO4, and CaMgGeO4 olivines

We present a Raman spectroscopic study of the structural modifications of several olivines at high pressures and ambient temperature. At high pressures, the following modifications in the Raman spectra are observed: 1)?in Mn₂GeO₄, between 6.7 and 8.6?GPa the appearance of weak bands at 560 and 860?cm^?1; between 10.6 and 23?GPa, the progressive replacement of the olivine spectrum by the spectrum of a crystalline high pressure phase; upon decompression, the inverse sequence of transformations is observed with some hysteresis in the transformation pressures; this sequence may be interpreted as the progressive transformation of the olivine to a spinelloid where Ge tetrahedra are polymerized, and then to a partially inverse spinel; 2)?in Ca₂SiO₄, the olivine transforms to larnite between 1.9 and 2.1?GPa; larnite is observed up to the maximum pressure of 24?GPa and it can partially back-transform to olivine during decompression; 3)?in Ca₂GeO₄, the olivine transforms to a new structure between 6.8 and 8?GPa; the vibrational frequencies of the new phase suggest that the phase transition involves an increase of the Ca coordination number and that Ge tetrahedra are isolated; this high pressure phase is observed up to the maximum pressure of 11?GPa; during decompression, it transforms to a disordered phase below 5?GPa; 4)?in CaMgGeO₄, no significant modification of the olivine spectrum is observed up to 15?GPa; between 16 and 26?GPa, broadening of some peaks and the appearance of a weak broad feature at 700–900?cm^?1 suggests a progressive amorphization of the structure; near 27?GPa, amorphization is complete and an amorphous phase is quenched down to ambient pressure; this unique behaviour is interpreted as the result of the incompatibilities in the high pressure behaviour of the Ca and Mg sublattices in the olivine structure.     

Geodynamic aspects of the basic intrusions of central and Western Nepal

A petrological study of the basic rocks of magmatic activity in the Pokhara and Beri Khola regions of Central and Western Nepal suggests that the volcanic activities were not related to collision or continental subduction.     

Scale decomposition of atmospheric water budget over West Africa during the monsoon 2006 from NCEP/GFS analyses

NCEP/GFS analysis is used to investigate the scale dependence and the interplay between the terms of the atmospheric water budget over West Africa using a dedicated decomposition methodology. The focus is on a 2-month period within the active monsoon period of 2006. Results show that the dominant scales of seasonal mean precipitation and moisture flux divergence over West Africa during the monsoon period are large scales (greater than 1,400 km) except over topography, where mean values of small scales (smaller than 900 km) are strong. Correlations between moisture flux divergences in monsoon and African Easterly Jet layers and precipitation indicate that precipitation is strongly correlated to moisture flux divergence via both large-scale and small-scale processes, but the correlation signal is quite different depending on the region and vertical layer considered. The analysis of the scales associated with the rainfall and the local evaporation over 3 different regions shows that positive correlation exists over the ocean between precipitation and evaporation especially at large scale. Over the continent south of the Sahel, the correlation is negative and driven by large scale. Over the northern part of Sahel, positive correlation is found, only at small scales during the active monsoon period. Lag correlation reveals that the maximum evaporation over the Sahel occurs 1–3 days after the maximum precipitation with maximum contribution from small-scale processes during the first day. This study shows that NCEP/GFS reproduces well the known atmospheric water budget features. It also reveals a new scale dependence of the relative role of each term of the atmospheric water budget. This indicates that such scale decomposition approach is helpful to clarify the functioning of the water cycle embedded in the monsoon system.