High-pressure Raman spectroscopic study of Mn2GeO4, Ca2GeO4, Ca2SiO4, and CaMgGeO4 olivines

We present a Raman spectroscopic study of the structural modifications of several olivines at high pressures and ambient temperature. At high pressures, the following modifications in the Raman spectra are observed: 1)?in Mn₂GeO₄, between 6.7 and 8.6?GPa the appearance of weak bands at 560 and 860?cm^?1; between 10.6 and 23?GPa, the progressive replacement of the olivine spectrum by the spectrum of a crystalline high pressure phase; upon decompression, the inverse sequence of transformations is observed with some hysteresis in the transformation pressures; this sequence may be interpreted as the progressive transformation of the olivine to a spinelloid where Ge tetrahedra are polymerized, and then to a partially inverse spinel; 2)?in Ca₂SiO₄, the olivine transforms to larnite between 1.9 and 2.1?GPa; larnite is observed up to the maximum pressure of 24?GPa and it can partially back-transform to olivine during decompression; 3)?in Ca₂GeO₄, the olivine transforms to a new structure between 6.8 and 8?GPa; the vibrational frequencies of the new phase suggest that the phase transition involves an increase of the Ca coordination number and that Ge tetrahedra are isolated; this high pressure phase is observed up to the maximum pressure of 11?GPa; during decompression, it transforms to a disordered phase below 5?GPa; 4)?in CaMgGeO₄, no significant modification of the olivine spectrum is observed up to 15?GPa; between 16 and 26?GPa, broadening of some peaks and the appearance of a weak broad feature at 700–900?cm^?1 suggests a progressive amorphization of the structure; near 27?GPa, amorphization is complete and an amorphous phase is quenched down to ambient pressure; this unique behaviour is interpreted as the result of the incompatibilities in the high pressure behaviour of the Ca and Mg sublattices in the olivine structure.     

Total Mercury Distribution and Volatilization in Microcosms with and Without the Aquatic Macrophyte Eichhornia Crassipes

Mercury (Hg) is one of the most toxic pollutants and spreads in the environment according to its affinity to several compartments. Aquatic macrophytes, such as Eichhornia crassipes, are known as sites for accumulation of Hg and methylmercury formation. The objective of this research was to observe Hg distribution among air, water and whole plants of the macrophyte E. crassipes for 17?days. The distribution of a single ²⁰³Hg spike was evaluated by gamma spectrometry. Two experiments, with and without macrophytes, were made, and the compartments analyzed for the presence of Hg were air, 0.2-μm filtered water, suspended and settled particles, roots, leafs, petioles and adsorption on the desiccators walls. ²⁰³Hg was detected in all analyzed compartments, and the highest total Hg concentrations were found in the roots and particles of the incubations with and without macrophytes that retained in average 68 and 34?% of added Hg, respectively. On the other hand, the lowest concentrations were found in air for both incubations, with higher volatilization (up to 2.5?% of added Hg) in the absence of macrophytes. The lower Hg values in leafs and petioles suggest this plant has mechanisms of Hg retention in the roots. Results suggest this macrophyte promotes changes in the Hg cycle since it attracts most Hg present in water and particulate to its roots and settled particles underneath and also reduces Hg volatilization.     

Earthquake activity in the Southern Vanuatu arc recorded by the Texas digital OBS

We have reconfigured the Texas digital ocean bottom seismograph (OBS) to operate in a triggered mode and record regional earthquake signals. This paper reports the results of a deployment program designed to test these digital OBS, by moni toring earthquake activity in and near the trench in southern Vanuatu (formerly, the New Hebrides). We successfully recorded hundreds of earthquakes, including 133 located regional earth quakes recorded by three or more stations. We also report J-B residuals for 21 earthquakes reported and located by the ISC. Fourier analysis of seismograms from regional earthquakes suggest that the frequencies of spectral peaks at any station were nearly the same for large, small, nearby, and distant events. However, we obtained very disparate frequencies when we analyzed seismograms for the same earthquake recorded at different stations. The most plausible interpretation is that spectral peaks do not depend on the characteristics of the earthquake source, but instead on site characteristics, or, more specifically, on the coupling of the instrument to the seafloor. To record reliable spectral data, we need to overcome this problem.     

Experimental and numerical study of the effect of variable bathymetry on the slow-drift wave response of floating bodies

An experimental campaign is reported on the slow-drift motion of a rectangular barge moored at different positions along an inclined beach, at waterdepths ranging from 54 cm to 21 cm, and submitted to irregular beam seas. The beach is achieved by inclining the 24 m long false bottom of the tank at a slope of 5%, from a depth of 1.05 m. The slow-drift component of the measured sway motion is first compared with state-of-the-art calculations based on Newman’s approximation. At 54 cm depth a good agreement is obtained between calculations and measurements. At 21 cm depth the Newman calculations exceed the measured values. When the flat bottom setdown contribution is added up, the calculated values become 2 to 3 times larger than the measured ones. A second-order model is proposed to predict the shoaling of a bichromatic sea-state propagating in varying water-depth. This model is validated through comparisons with an extension of Schäffer’s model for a straight beach [Schäffer HA. Infragravity waves induced by short-wave groups. J Fluid Mech 1993;247:551-88] and with a fully nonlinear Boussinesq model. It appears that the long wave amplitude is much less than predicted by the flat bottom model, and that its phase difference with the short wave envelope also deviates from the flat bottom model prediction. As a result of this phase shift the actual second-order wave loads can be lower than predicted by Newman’s approximation alone. Application of the shoaling model to the barge tests yields a notably better agreement between numerical and experimental values of its slow-drift sway motion.     

On the remote monitoring of Karenia brevis blooms of the west Florida shelf

In situ surveys (1997–2002) of Karenia brevis distribution on the west Florida shelf were used to explain spectral remote sensing reflectance, chlorophyll-a concentration, and backscattering coefficient estimates derived using SeaWiFS satellite data. Two existing approaches were tested in an attempt to differentiate K. brevis blooms from other blooms or plumes. A chlorophyll-anomaly method used operationally by the National Oceanic and Atmospheric Administration (NOAA) sometimes correctly identified K. brevis blooms but also generated false positives and false negatives. The method identified approximately 1000 km² of high chlorophyll-anomalies (>1 mg m⁻³) off southwest Florida between the 10 and 50-m isobaths nearly every day from summer to late fall. Whether these patches were K. brevis blooms or not is unknown. A second method used a backscattering:chlorophyll-a ratio to identify K. brevis patches. This method separated K. brevis from other blooms using in situ optical data, but it yielded less satisfactory results with SeaWiFS data. Spectral reflectance (R_rs) estimates for K. brevis blooms, diatom blooms, and coastal river plumes are statistically similar for many cases. Large pixel size, shallow water, and imperfect algorithms distort satellite retrievals of bio-optical parameters in patchy blooms. At present, a combination of chlorophyll-a, chlorophyll-anomaly, backscattering:chlorophyll-a ratio, RGB composites, MODIS fluorescence data, as well as time-series analysis and ancillary data such as winds, currents, and sea surface temperature can improve K. brevis bloom assessments. Progress in atmospheric correction and bio-optical inversion algorithms is required to help improve capabilities to monitor K. brevis blooms from space. Further, satellite sensors with improved radiometric capabilities and temporal/spatial resolutions are also required.     

Ice cover variability in the Caspian and Aral seas from active and passive microwave satellite data

The paper discusses time and space variations of ice extent in the Caspian and Aral seas during the last decade (1992-2002). It uses synergy of data from active (radar altimeter) and passive (radiometer) microwave nadir-looking instruments onboard the TOPEX/Poseidon satellite. The proposed approach is substantiated and validated using both in situ and satellite imagery data for the Caspian Sea. The results indicate significant spatial and temporal variability of ice conditions, with a significant decrease of both the duration of ice season and ice extent during the last four winters (1998-2002). The TOPEX/Poseidon-derived time series of sea ice extent are very valuable in view of the fragmentary and mostly unpublished data on ice conditions on the Caspian and Aral seas since the mid-1980s.     

Time splitting and linear stability of the slow part of the barotropic component

In this paper, the authors analyse the stability of particular numerical schemes used in oceanic general circulation models to deal with the barotropic momentum advection term. It is shown that, when this term is integrated using time splitting, its stability properties can be drastically reduced in configurations where there exists shallow areas, where velocities become comparable to the propagation speed of external gravity waves. A simple alternative scheme with improved stability is proposed and discussed.     

The deuterium and oxygen-18 isotopic composition of the groundwater in Khan Younis City,southern Gaza Strip (Palestine)

The environmental isotopes such as deuterium and oxygen-18 and the deuterium excess values have been used to assess groundwater recharge sources and their dynamics in Khan Younis City in the Gaza Strip in Palestine. Three isotopic lines for the relationship between δ²H and δ¹⁸O were used in the assessment. These lines are the global meteoric water line, the local meteoric water line and the groundwater evaporation line. The δ²H, δ¹⁸O and D-excess values indicate that deuterium and oxygen-18 isotopes originated in the groundwater from groundwater mixing with rainfall and other water sources; the groundwater in the area recharged from rainfall from a distant source that came from the Mediterranean Sea and from other sources such as wastewater, irrigation return flow and saline water.