Distribution and sorption of potentially toxic metals in four forest soils from Hungary

Metals of natural and anthropogenic origin behave differently in soils mostly due to their different mobility. In this study, sequential extractions and batch sorption experiments were performed to relate the fractionation of native Ni, Cu, Zn and Pb to the sorption properties of added metals in four soils with contrasting physiochemical characteristics. A significant effect due to sample composition on both the mobility and sorption characteristics of these metals was found. The efficiency of soil components in metal immobilization was in the order of carbonate > organic matter > swelling clay minerals. The partitioning of native metals together with the information gained through the sorption isotherms allows a deeper insight on the fate and behavior of metals in soils with various compositions.     

Effects of social and climatic factors on building activity in the Czech lands between 1450 and 1950: a dendrochronological analysis

The development of settlement and building activity is the result of socioeconomic, political and demographic changes in the past. However, accurate information on temporal variation in building activity is rather limited. Dendrochronological databases containing dated historical wooden constructions provide an important resource. We used 6514 tree-felling dates to reconstruct building activity in the Czech lands for the period 1450–1950. Comparing felling dates with historical events demonstrated that building activity was negatively associated with intense wars, particularly during the Thirty Years' War (1618–1648). After the Peace of Westphalia (1648), socioeconomic renewal and demographic growth were reflected in an upsurge of building activity, especially ecclesiastical buildings. While the construction of ecclesiastical and noble buildings culminated around the 1720s, rural buildings peaked in the 1780s and the 1820s. Although no direct effect of climate was demonstrated, adverse climatic conditions leading to harvest failures and subsequent famines (e.g. the ‘Hunger Years’ 1770–1772) significantly contributed to declines in building activity. In contrast, a higher number of felling dates were detected when strong and/or frequent windstorms occurred. This study provides a comprehensive understanding of building activity in Central Europe and advocates the use of dendrochronological databases for the investigation of human activities in history.     

Analysis of soil boundary conditions of flash floods in a small basin in SW Hungary

Flash floods are one of the most significant natural hazards of today. Due to the complexity of flash flood triggering factors, to prevent or mitigate flood triggered losses, numeric model based flood forecasting models are capable tools to predict stream water levels. The main goal of the current research was to reproduce two flow peaks with the HEC-HMS rainfall-runoff model and test the model sensitivity for various input parameters. To obtain sufficient input data, we monitored soil depth, maximum infiltration rate, soil moisture content, rainfall, time of concentration and flow. To obtain input data, parameters were calculated, measured in the Sás Valley experimental watershed (SW Hungary) or optimized with the built in function of the HEC-HMS. Soil moisture was monitored in the 1.7 km2 pilot catchment over the period between September 2008 and September 2009. HEC-HMS had a good performance reproducing the two events, however simulated flow time series are highly influenced by the antecedent soil moisture, infiltration rate and canopy storage. Outflow modeled data were verified for two flood events (June 4, 2008 and July 9, 2009). The HEC-HMS was over-sensitive for input soil moisture and with increasing input rainfall and increasing outflow, larger simulation errors were observed.     

On the application of combined geoelectric weighted inversion in environmental exploration

Geophysical surveying methods are of great importance in environmental exploration. Inversion-based data processing methods are applied for the determination of geometrical and physical parameters of the target model. The use of this geoelectric inversion method is advantageous in environmental research where highly reliable information with large spatial resolution is required. The 2D combined geoelectric inversion (CGI) method performs more accurate parameter estimation than conventional 1D single inversion methods by efficiently decreasing the number of unknowns of the inverse problem (single means that data sets of individual vertical electric sounding stations are inverted separately). The quality improvement in parameter space is demonstrated by comparing the traditional 1D inversion procedure with a 2D series expansion-based inversion technique. The CGI method was further developed by weighting individual direct current geoelectric data sets automatically in order to improve inversion results. The new algorithm was named combined geoelectric weighted inversion, which extracts the solution by a special weighted least squares technique. It is shown that the new inversion methodology is applicable to resolve near-surface structures such as rapidly varying layer boundaries, laterally inhomogeneous formations and pinch-outs.     

Dynamics of grains falling on a sloping granular medium: application to the evolution of a talus

Numerous field surveys have provided quantitative information on the characteristics of talus deposits. Much less has been done to quantify the basic dynamics processes of blocks involved in talus evolution. In this work, we perform a set of experiments at the reduced scale of some metres using an inclined board covered with a loose granular medium. The complexity of the processes forming a talus is simplified by studying the interaction of only two kinds of grain sizes at a time. Grains of one class size are dropped from a fixed height onto the board covered by a layer of grains of a different class size, and their final distribution is recorded. We find that when small grains fall on large grains, the granular abundance decreases rapidly as a function of the distance from the fall point, which is explained by the effect of multiple bouncing on the irregular surface. In contrast, large grains falling on a bed of smaller grains lose much more energy at impact. They may stop at once, or roll down slope, often reaching the whole board length; as a consequence, their abundance peaks in the fall zone and at the change of slope. Experiments also show that grains travel longer with increasing fall height and sloping angle. The results clarify in a physical manner one mechanism that might explain why large blocks are typically found in the distal part of a talus slope, while smaller blocks remain near the fall zone. Based on these and previous experiments, a schematic view of talus evolution is discussed. Copyright © 2014 John Wiley & Sons, Ltd.     

A comparison of biological trends from four marine ecosystems: Synchronies, differences, and commonalities

Major features of four marine ecosystems were analyzed based on a broad range of fisheries-associated datasets and a suite of oceanographic surveys. The ecosystems analyzed included the Gulf of Maine/Georges Bank in the Northwest Atlantic Ocean, the Norwegian/Barents Seas in the Northeast Atlantic Ocean, and the eastern Bering Sea and the Gulf of Alaska in the Northeast Pacific Ocean. We examined survey trends in major fish abundances, total system fish biomass, and zooplankton biomasses. We standardized each time series and examined trends and anomalies over time, using both time series and cross-correlational statistical methods. We compared dynamics of functionally analogous species from each of these four ecosystems. Major commonalities among ecosystems included a relatively stable amount of total fish biomass and the importance of large calanoid copepods, small pelagic fishes and gadids. Some of the changes in these components were synchronous across ecosystems. Major differences between ecosystems included gradients in the magnitude of total fish biomass, commercial fish biomass, and the timing of major detected events. This work demonstrates the value of comparative analysis across a wide range of marine ecosystems, suggestive of very few but none-the-less detectable common features across all northern hemisphere ocean systems.     

Alpine metamorphic evolution and cooling history of the Veporic basement in northern Hungary: new petrological and geochronological constraints

Petrological and geochronological investigations were carried out on metamorphic rocks of the Veporic unit (Inner Western Carpathians) in northern Hungary. K/Ar and Ar/Ar data on micas and amphibole show only Alpine ages (mostly in the range of 87-95 Ma) in this basement unit. Thermobarometric calculations yield lower amphibolite facies peak conditions (ca. 550냴 °C and 9ǃ kbar) for the Eoalpine metamorphic event. Complex evolution of gneissic rocks is reflected by the presence of discontinuously zoned garnets, the cores of which may represent relics of a pre-Alpine (presumably Variscan) thermal event. Zircon fission track (FT) data in the narrow range of 75-77.5 Ma indicate that this portion of the Veporic unit was emplaced to shallow crustal levels already during the Senonian time. The relative minor difference between zircon FT and K/Ar or Ar/Ar ages suggests very rapid cooling during the Late Cretaceous, most probably related to the extensional unroofing of the Veporic core complex. The obtained cooling ages do not support previous models of Tertiary uplift and exhumation of the Veporic unit along the Hurbanovo-Diósjeni Line.     

Investigation of the climate-driven periodicity of shallow groundwater level fluctuations in a Central-Eastern European agricultural region

The distribution and amount of groundwater, a crucial source of Earth’s drinking and irrigation water, is changing due to climate-change effects. Therefore, it is important to understand groundwater behavior in extreme scenarios, e.g. drought. Shallow groundwater (SGW) level fluctuation under natural conditions displays periodic behavior, i.e. seasonal variation. Thus, the study aims to investigate (1) the periodic behavior of the SGW level time series of an agriculturally important and drought-sensitive region in Central-Eastern Europe – the Carpathian Basin, in the north-eastern part of the Great Hungarian Plain, and (2) its relationship to the European atmospheric pressure action centers. Data from 216 SGW wells were studied using wavelet spectrum analysis and wavelet coherence analyses for 1961–2010. Locally, a clear relationship exists between the absence of annual periodic behavior in the SGW level and the periodicity of droughts, as indicated by the self-calibrating Palmer Drought Severity Index and the Aridity Index. During the non-periodic intervals, significant drops in groundwater levels (average 0.5 m) were recorded in 89% of the wells. This result links the meteorological variables to the periodic behavior of SGW, and consequently, drought. On a regional scale, Mediterranean cyclones from the Gulf of Genoa (northwest Italy) were found to be a driving factor in the 8-yr periodic behavior of the SGW wells. The research documents an important link between SGW levels and local/regional climate variables or indices, thereby facilitating the necessary adaptation strategies on national and/or regional scales, as these must take into account the predictions of drought-related climatic conditions.     

Model-free estimation from spatial samples: A reappraisal of classical sampling theory

A commonly held view among geostatisticians is that classical sampling theory is inapplicable to spatial sampling because spatial data are dependent, whereas classical sampling theory requires them to be independent. By comparing the assumptions and use of classical sampling theory with those of geostatistical theory, we conclude that this view is both false and unfortunate. In particular, estimates of spatial means based on classical sampling designs require fewer assumptions for their validity, and are therefore more robust, than those based on a geostatistical model.     

On diurnal variations of the solar rotation rate as derived from sunspot tracings

The heliographic positions of more than 100 sunspots were accurately measured several times a day from 1974 until 1979 by means of the computer-controlled tracing method described by Schröter and Wöhl (1975). A striking degree of constancy of the solar rotation rate (about 0.15% or 3 m s^–1) is found, when east-west proper motion components of each individual stable sunspot is considered. However, large differences of the rotation rate are observed (up to 7% or 130 m s^–1) when comparing different sunspots. We found no significant correlation of these fluctuations with characteristics of the sunspots (age, evolution, etc.).Mitteilungen aus dem Kiepenheuer-Institut Nr. 191.