Biodegradation of forest floor organic matter bound to minerals via different binding mechanisms

Mineral-associated organic matter (OM) represents a large reservoir of organic carbon (OC) in natural environments. The factors controlling the extent of the mineral-mediated OC stabilization, however, are poorly understood. The protection of OM against biodegradation upon sorption to mineral phases is assumed to result from the formation of strong bonds that limit desorption. To test this, we studied the biodegradation of OM bound to goethite (α-FeOOH), pyrophyllite, and vermiculite via specific mechanisms as estimated from OC uptake in different background electrolytes and operationally defined as ‘ligand exchange’, ‘Ca²⁺ bridging’, and ‘van der Waals forces’. Organic matter extracted from an Oa forest floor horizon under Norway spruce (Picea abies (L.) Karst) was reacted with minerals at dissolved OC concentrations of ∼5-130 mg/L at pH 4. Goethite retained up to 30.1 mg OC/g predominantly by ‘ligand exchange’; pyrophyllite sorbed maximally 12.5 mg OC/g, largely via ‘van der Waals forces’ and ‘Ca²⁺ bridging’, while sorption of OM to vermiculite was 7.3 mg OC/g, mainly due to the formation of ‘Ca²⁺ bridges’. Aromatic OM components were selectively sorbed by all minerals (goethite ? phyllosilicates). The sorption of OM was strongly hysteretic with the desorption into 0.01 M NaCl being larger for OM held by ‘Ca²⁺ bridges’ and ‘van der Waals forces’ than by ‘ligand exchange’. Incubation experiments under aerobic conditions (initial pH 4; 90 days) revealed that OM mainly bound to minerals by ‘ligand exchange’ was more resistant against mineralization than OM held by non-columbic interactions (‘van der Waals forces’). Calcium bridges enhanced the stability of sorbed OM, especially for vermiculite, but less than the binding via ‘ligand exchange’. Combined evidence suggests that the extent and rate of mineralization of mineral-associated OM are governed by desorption. The intrinsic stability of sorbed OM as related to the presence of resistant, lignin-derived aromatic components appears less decisive for the sorptive stabilization of OM than the involved binding mechanisms. In a given environment, the type of minerals present and the solution chemistry determine the operating binding mechanisms, thereby the extent of OM sorption and desorption, and thus ultimately the bioavailability of mineral-associated OM.     

Integrated geophysical and geological methods to investigate the inner and outer structures of the Quaternary Mýtina maar (W-Bohemia,Czech Republic)

The Mýtina maar is the first known Quaternary maar in the Bohemian Massif. Based on the results of Mrlina et al. (J Volcanol Geother Res 182:97–112, 2009), a multiparametric geophysical (electrical resistivity tomography, gravimetry, magnetometry, seismics) and geological/petrochemical research study had been carried out. The interpretation of the data has provided new information about the inner structure of the volcanic complex: (1) specification of the depth of post-volcanic sedimentary fill (up to ~100 m) and (2) magnetic and resistivity signs of one (or two) hidden volcanic structures interpreted as intrusions or remains of a scoria cone. The findings at the outer structure of the maar incorporate the (1) evidence of circular fracture zones outside the maar, (2) detection and distribution of volcanic ejecta and tephra-fall deposits at the surface, and (3) indications from electrical resistivity tomography and gravity data in the area between the Mýtina maar and ?elezná h?rka scoria cone, interpreted as a palaeovalley, filled by volcaniclastic rocks, and aligned along the strike line (NW–SE) of the Tachov fault zone. These findings are valuable contributions to extend the knowledge about structure of maar volcanoes in general. Because of ongoing active magmatic processes in the north-east part of the Cheb Basin (ca. 15–30 km north of the investigation area), the Mýtina maar-diatreme volcano and surroundings is a suitable key area for research directed to reconstruction of the palaeovolcanic evolution and assessment of possible future hazard potential in the Bohemian Massif.     

A quantitative vulnerability function for fluvial sediment transport

In quantitative risk assessment, risk is expressed as a function of hazard, elements at risk exposed, and vulnerability. Vulnerability is defined as the expected degree of loss for an element at risk as a consequence of a certain event, following a natural-scientific approach combined with economic methods of loss appraisal. The resulting value ranges from 0 (no damage) to 1 (complete destruction). With respect to torrent processes, i.e., fluvial sediment transport, this concept of vulnerability—though widely acknowledged—did not result in sound quantitative relationships between process intensities and associated degrees of loss so far, even if considerable loss occurred during recent years. To close this gap and establish this relationship, data from three well-documented torrent events in the Austrian Alps were used to derive a quantitative vulnerability function applicable to residential buildings located on torrent fans. The method applied followed a spatially explicit empirical approach within a GIS environment and was based on process intensities, the spatial characteristics of elements at risk, and average reconstruction values on a local scale. Additionally, loss data were collected from responsible administrative bodies and analysed on an object level. The results suggest a modified Weibull distribution to fit best to the observed damage pattern if intensity is quantified in absolute values, and a modified Frechet distribution if intensity is quantified relatively in relation to the individual building height. Additionally, uncertainties resulting from such an empirical approach were studied; in relation to the data quality a 90% confidence band was found to represent the data range appropriately. The vulnerability relationship obtained allows for an enhanced quantification of torrent risk, but also for an inclusion in comprehensive vulnerability models including physical, social, economic, and institutional vulnerability. As a result, vulnerability to mountain hazards might decrease in the future.     

The Philippine National Collection of Microorganisms (PNCM): Repository of microbial diversity of the country

The prime function of the Philippine National Collection of Microorganisms (PNCM), being the national repository of microbial strains, is to collect and preserve strains for their continued viability and availability for future use. To date, a total of 2144 strains of bacteria (1357), yeasts (250), filamentous, fungi (377), algae (14), and strains still to be identified (146) are maintained at the PNCM. These are preserved and maintained using various methods which include modified liquid drying (lyophilization), ultra-low temperature (−70°C) storage in 10% glycerol, storage in sterile soil, distilled water and overlaying with mineral oil. Periodic viability testing is done to assess the stability of these preserved cultures under storage. Aside from preservation and maintenance of cultures, the PNCM is also involved in several research activities. One of these is the isolation, characterization and identification of some Vibrio isolates from the Philippines. Details on this particular study is presented in this report.     

Variations in annual snowline and area of an ice-covered stratovolcano in the Cordillera Ampato,Peru, using remote sensing data (1986–2014)

This research focuses on the recent variations in the annual snowline and the total glaciated area of the Nevado Coropuna in the Cordillera Ampato, Peru. Maximum snowline altitude towards the end of dry season is taken as a representative of the equilibrium line altitude of the year, which is an indirect measurement of the annual mass balance. We used Landsat and IRS LISS3 images during the last 30 years due to its better temporal coverage of the study site. It is found that there was a decrease of 26.92% of the glaciated area during 1986–2014. We calculated the anomalies in precipitation and temperature in this region and also tried to correlate the changes in glacier parameters with the combined influence of El Niño – Southern Oscillation (ENSO) and pacific decadal oscillation (PDO). It is concluded that the snowline of Nevado Coropuna has been fluctuated during ENSO, and maximum fluctuations were observed when ENSO and PDO were in phase.     

Who uses the Clean Development Mechanism? An empirical analysis of projects in Chinese provinces

China is by far the largest host of projects implemented under the Kyoto Protocol's Clean Development Mechanism (CDM). However, earlier studies shed little light on the determinants of the distribution of CDM projects across Chinese provinces. Given China's large size and political-economic diversity, this dearth of research is troubling. We provide an empirical analysis of 2097 CDM projects in 30 Chinese provinces, 2004–2009. We find that high electricity consumption, low per capita income, and a lack of foreign direct investment are all associated with CDM project implementation. The findings are particularly strong for electricity and foreign direct investment. These findings are consistent with the economic theory of CDM project implementation. Project developers focus on minimizing the cost of carbon abatement. Moreover, they suggest that the CDM can, despite its limitations, contribute to reducing economic inequality and uneven development in China.     

Multi-spacecraft Observations of CIR-Associated Ion Increases During the Ulysses 2007 Ecliptic Crossing

The period between 21 June and 8 October, 2007 (Carrington rotations 2058 to 2061), comprising the Ulysses ecliptic plane crossing, was characterized by low solar activity. Excluding the small solar energetic particle events observed during July, the ion increases observed in the inner heliosphere between 100?keV/n and 10?MeV/n were associated with Corotating Interaction Regions (CIRs). In this work, we investigate CIR-related ion increases using multipoint observations from Ulysses, ACE, and the twin STEREO spacecraft. The ballistic backmapping technique has been used to correlate in situ observations of these spacecraft and remote-sensing observations of coronal holes. Although the radial, longitudinal and latitudinal separation of the spacecraft (except Ulysses) are relatively small, we find discrepancies when a detailed comparison of narrow structures like stream interfaces and CIR-associated shocks is performed. Therefore we concentrate on the two CIR events from day 5 to day 10 of August 2007 and from day 25 to day 31 of August 2007, which lend themselves to a more undisturbed comparison. Using the multi-spacecraft measurements we could determine a radial gradient of 230±30% AU^?1, which is consistent with previous results by van Hollebeke et al. (J. Geophys. Res. 83, 4723, 1978) of ～?350% AU^?1 using Helios and Pioneer data.

     

Salt movements in the Northeast German Basin and its relation to major post-Permian tectonic phases—results from 3D structural modelling, backstripping and reflection seismic data

The NW–SE-striking Northeast German Basin (NEGB) forms part of the Southern Permian Basin and contains up to 8 km of Permian to Cenozoic deposits. During its polyphase evolution, mobilization of the Zechstein salt layer resulted in a complex structural configuration with thin-skinned deformation in the basin and thick-skinned deformation at the basin margins. We investigated the role of salt as a decoupling horizon between its substratum and its cover during the Mesozoic deformation by integration of 3D structural modelling, backstripping and seismic interpretation. Our results suggest that periods of Mesozoic salt movement correlate temporally with changes of the regional stress field structures. Post-depositional salt mobilisation was weakest in the area of highest initial salt thickness and thickest overburden. This also indicates that regional tectonics is responsible for the initiation of salt movements rather than stratigraphic density inversion.Salt movement mainly took place in post-Muschelkalk times. The onset of salt diapirism with the formation of N–S-oriented rim synclines in Late Triassic was synchronous with the development of the NNE–SSW-striking Rheinsberg Trough due to regional E–W extension. In the Middle and Late Jurassic, uplift affected the northern part of the basin and may have induced south-directed gravity gliding in the salt layer. In the southern part, deposition continued in the Early Cretaceous. However, rotation of salt rim synclines axes to NW–SE as well as accelerated rim syncline subsidence near the NW–SE-striking Gardelegen Fault at the southern basin margin indicates a change from E–W extension to a tectonic regime favoring the activation of NW–SE-oriented structural elements. During the Late Cretaceous–Earliest Cenozoic, diapirism was associated with regional N–S compression and progressed further north and west. The Mesozoic interval was folded with the formation of WNW-trending salt-cored anticlines parallel to inversion structures and to differentially uplifted blocks. Late Cretaceous–Early Cenozoic compression caused partial inversion of older rim synclines and reverse reactivation of some Late Triassic to Jurassic normal faults in the salt cover. Subsequent uplift and erosion affected the pre-Cenozoic layers in the entire basin. In the Cenozoic, a last phase of salt tectonic deformation was associated with regional subsidence of the basin. Diapirism of the maturest pre-Cenozoic salt structures continued with some Cenozoic rim synclines overstepping older structures. The difference between the structural wavelength of the tighter folded Mesozoic interval and the wider Cenozoic structures indicates different tectonic regimes in Late Cretaceous and Cenozoic.We suggest that horizontal strain propagation in the brittle salt cover was accommodated by viscous flow in the decoupling salt layer and thus salt motion passively balanced Late Triassic extension as well as parts of Late Cretaceous–Early Tertiary compression.