Thallium in meteorites

Abstract— Thallium has been quantified in 50 iron meteorites and 6 chondrites using a combination of solvent extraction and graphite furnace atomic absorption spectrometry. The accuracy of the data was checked by analysis of two iron meteorites by laser-excited ICP mass spectrometry. The Tl abundance values for irons appear to be the first recorded and show that the Tl content allows for taxonomic separation of several groups on Tl vs. Ni abundance plots. The Tl content of irons is inversely correlated with abundances of platinum group metals such as Ir, Pt, and Rh and, in this respect, behaves like Pd and As that favour sulphur-rich phases in meteorites. Analysis of carbonaceous chondrites showed a 30-fold enrichment of Tl compared with ordinary chondrites.     

RING CURRENT DYNAMICS DURING THE 13–18 JULY 2000 STORM PERIOD

We study the development of the terrestrial ring current during the time interval of 13–18 July, 2000, which consisted of two small to moderate geomagnetic storms followed by a great storm with indices Dst=−300 nT and Kp=9. This period of intense geomagnetic activity was caused by three interplanetary coronal mass ejecta (ICME) each driving interplanetary shocks, the last shock being very strong and reaching Earth at ∼ 14 UT on 15 July. We note that (a) the sheath region behind the third shock was characterized by B _z fluctuations of ∼35 nT peak-to-peak amplitude, and (b) the ICME contained a negative to positive B _z variation extending for about 1 day, with a ∼ 6-hour long negative phase and a minimum B _z of about −55 nT. Both of these interplanetary sources caused considerable geomagnetic activity (Kp=8 to 9) despite their disparity as interplanetary triggers. We used our global ring current-atmosphere interaction model with initial and boundary conditions inferred from measurements from the hot plasma instruments on the Polar spacecraft and the geosynchronous Los Alamos satellites, and simulated the time evolution of H⁺, O⁺, and He⁺ ring current ion distributions. We found that the O⁺ content of the ring current increased after each shock and reached maximum values of ∼ 60% near minimum Dst of the great storm. We calculated the growth rate of electromagnetic ion cyclotron waves considering for the first time wave excitation at frequencies below O⁺ gyrofrequency. We found that the wave gain of O⁺ band waves is greater and is located at larger L shells than that of the He⁺ band waves during this storm interval. Isotropic pitch angle distributions indicating strong plasma wave scattering were observed by the imaging proton sensor (IPS) on Polar at the locations of maximum predicted wave gain, in good agreement with model simulations.     

EUV observations of the chromospheric network

Extreme ultraviolet observations of a quiet region of the Sun on August 18, 1969, with the Harvard spectroheliometer on OSO 6 indicate that the chromospheric network can be observed in lines of the chromosphere and transition region (T = 8.4 × 10⁵ K) with almost identical structure. At coronal heights, the network changes but some residual structure can still be discerned in Mgx and perhaps Sixii (T = 2.3 × 10⁶ K), although there is little or no evidence remaining in Fexvi (T = = 3.5 × 10⁶ K).     

Pathways and timescales associated with nitrogen transport from septic systems in coastal aquifers intersected by canals

Septic systems located near coastal waterways can contribute to nutrients that lead to eutrophication, harmful algal blooms, and high levels of fecal coliforms such as E. coli. This study defines pathways and timescales of nitrogen transport released from septic systems using a groundwater-flow and nitrogen transport model of a coastal subdivision connected to 2,000 septic systems and dissected by a dense network of canals. Lift station effluent data are used as a proxy to quantify average household septic nitrogen and fluid contributions of 11 kg/year and 160 m³/year, respectively. These fluxes are upscaled and applied to five sewer conversion zones, each having a known number of septic systems. Model results provide a basis for assessing nitrogen transport timescales associated with (1) coastal groundwaters for regions with high septic density near the coastline and (2) groundwater–canal interaction. Timescales associated with nitrogen removal by natural groundwater flow in a sandy surficial aquifer, following septic to sewer conversion, are predicted by the model to be on the order of 2–3 years for 50% reduction and 8–10 years for 90% reduction. Both numerical and collected field data indicate that canals significantly influence groundwater flow and have the potential to convey nitrogen to coastal waters at rates several orders of magnitude higher than introduced by submarine discharge along the coast. Pre and post sewer conversion data on nitrate and total nitrogen in shallow groundwater from a nearby field site, obtained post-model development, support the nitrogen concentrations and timescales predicted by the numerical model.

     

Precipitation Observations with NSSL’s X-band Polarimetric Radar during the SNOW-V10 Campaign

In support of SNOW-V10, the National Oceanic Administration/National Severe Storms Laboratory (NOAA/NSSL) mobile dual-polarized X-band (NO-XP) radar was deployed to Birch Bay State Park in Birch Bay, Washington from 3 January 2010 to 17 March 2010. In addition to being made available in real time for Science and NOWcasting of the Olympic Weather for Vancouver 2010 (SNOW-V10) operations, NO-XP data are used here to demonstrate the capabilities of easily deployable, polarimetric X-band radar systems, especially for regions where mountainous terrain results in partial beam blockage. A rainfall estimator based on specific attenuation is shown to mitigate the effects of partial beam blockage and provide potential improvement in rainfall estimation. The ability of polarimetric X-band radar to accurately detect melting layer (ML) height is also shown. A 16 h comparison of radar reflectivity (Z), differential reflectivity (Z _DR), and correlation coefficient (ρ_hv) measurements from NO-XP with vertically pointing Micro Rain Radar observations indicates that the two instruments provide ML height evolution that exhibit consistent temporal trends. Since even slight changes in the ML height in regions of mountainous terrain might result in a change in precipitation type measured at the surface, this shows that horizontally extensive information on ML height fluctuations, such as provided by the NO-XP, is useful in determining short term changes in expected precipitation type. Finally, range-height indicator (RHI) scans of NO-XP Z, Z _DR, and ρ_hv fields from SNOW-V10 are used to demonstrate the ability of polarimetric radar to diagnose microphysical processes (both above and below the ML) that otherwise remain unseen by conventional radar. Near-surface enhancements in Z _DR are attributed to either differential sedimentation or the preferential evaporation of smaller drops. Immediately above the ML, regions of high Z, low Z _DR, and high ρ_hv are believed to be associated with convective turrets containing heavily aggregated or rimed snow that supply water/ice mass that later result in enhanced regions of precipitation near the surface. Higher up, horizontally extensive regions of enhanced Z _DR are attributed to rapid dendritic growth and the onset of snow aggregation, a feature that has been widely observed with both S band and C band radars.