Overview of the potential of microalgae for CO2 sequestration

An economic and environmentally friendly approach of overcoming the problem of fossil CO₂ emissions would be to reuse it through fixation into biomass. Carbon dioxide (CO₂), which is the basis for the formation of complex sugars by green plants and microalgae through photosynthesis, has been shown to significantly increase the growth rates of certain microalgal species. Microalgae possess a greater capacity to fix CO₂ compared to C₄ plants. Selection of appropriate microalgal strains is based on the CO₂ fixation and tolerance capability together with lipid potential, both of which are a function of biomass productivity. Microalgae can be propagated in open raceway ponds or closed photobioreactors. Biological CO₂ fixation also depends on the tolerance of selected strains to high temperatures and the amount of CO₂ present in flue gas, together with SO_x and NO_x. Potential uses of microalgal biomass after sequestration could include biodiesel production, fodder for livestock, production of colorants and vitamins. This review summarizes commonly employed microalgal species as well as the physiological pathway involved in the biochemistry of CO₂ fixation. It also presents an outlook on microalgal propagation systems for CO₂ sequestration as well as a summary on the life cycle analysis of the process.     

Removal of lead (II) from synthetic and batteries wastewater using agricultural residues in batch/column mode

The present article explores the ability of five different combinations of two adsorbents (Arachis hypogea shell powder and Eucalyptus cameldulensis saw dust) to remove Pb(II) from synthetic and lead acid batteries wastewater through batch and column mode. The effects of solution pH, adsorbent dose, initial Pb(II) concentration and contact time were investigated with synthetic solutions in batch mode. The Fourier transform infrared spectroscopy study revealed that carboxyl and hydroxyl functional groups were mostly responsible for the removal of Pb(II) ions from test solutions. The kinetic data were found to follow pseudo-second-order model with correlation coefficient of 0.99. Among Freundlich and Langmuir adsorption models, the Langmuir model provided the best fit to the equilibrium data with maximum adsorption capacity of 270.2 mg g^?1. Column studies were carried out using lead battery wastewater at different flow rates and bed depths. Two kinetic models, viz. Thomas and Bed depth service time model, were applied to predict the breakthrough curves and breakthrough service time. The Pb(II) uptake capacity (q _e = 540.41 mg g^?1) was obtained using bed depth of 35 cm and a flow rate of 1.0 mL min^?1 at 6.0 pH. The results from this study showed that adsorption capacity of agricultural residues in different combinations is much better than reported by other authors, authenticating that the prepared biosorbents have potential in remediation of Pb-contaminated waters.     

Geochemical characterization and heavy metal contamination of groundwater in Satluj River Basin

Groundwater, a renewable and finite natural resource, vital for man’s life, social and economic development and a valuable component of the ecosystem, is vulnerable to natural and human impacts. The aim of present study is to evaluate hydrogeochemical parameters and heavy metals in groundwater and to study their spatial distribution in the Rupnagar District of Punjab. The spatial distribution of physico-chemical parameters were studied using Arc GIS 9.2. It was observed that the concentration of parameters, such as NO₃, Cd, Cr, Mn and Pb was above permissible limit (World Health Organization, WHO) in southern part of the study area. The heavy metal pollution index (HPI) was calculated for all sampling locations and it was found much above the critical limit of pollution. Geochemical reaction models of selected water groups were constructed using Phreeqc. Geochemical modeling suggests that sodium has source other than halite-albite and calcium has alternate source other than gypsum-carbonate or silicates. It also suggests that evaporites, ion exchange, dissolution along with anthropogenic activities are controlling the hydro-geochemistry of groundwater in the region. Various indices, such as heavy metal pollution index, permeability index, sodium adsorption ratio, were studied to verify suitability of groundwater for drinking and irrigation.     

Appraisal of land use/land cover of mangrove forest ecosystem using support vector machine

Human activities in many parts of the world have greatly changed the natural land cover. This study has been conducted on Pichavaram forest, south east coast of India, famous for its unique mangrove bio-diversity. The main objectives of this study were focused on monitoring land cover changes particularly for the mangrove forest in the Pichavaram area using multi-temporal Landsat images captured in the 1991, 2000, and 2009. The land use/land cover (LULC) estimation was done by a unique hybrid classification approach consisting of unsupervised and support vector machine (SVM)-based supervised classification. Once the vegetation and non-vegetation classes were separated, training site-based classification technology i.e., SVM-based supervised classification technique was used. The agricultural area, forest/plantation, degraded mangrove and mangrove forest layers were separated from the vegetation layer. Mud flat, sand/beach, swamp, sea water/sea, aquaculture pond, and fallow land were separated from non-vegetation layer. Water logged areas were delineated from the area initially considered under swamp and sea water-drowned areas. In this study, the object-based post-classification comparison method was employed for detecting changes. In order to evaluate the performance, an accuracy assessment was carried out using the randomly stratified sampling method, assuring distribution in a rational pattern so that a specific number of observations were assigned to each category on the classified image. The Kappa accuracy of SVM classified image was highest (94.53 %) for the 2000 image and about 94.14 and 89.45 % for the 2009 and 1991 images, respectively. The results indicated that the increased anthropogenic activities in Pichavaram have caused an irreversible loss of forest vegetation. These findings can be used both as a strategic planning tool to address the broad-scale mangrove ecosystem conservation projects and also as a tactical guide to help managers in designing effective restoration measures.     

Hydrogeological processes controlling the release of arsenic in parts of 24 Parganas district,West Bengal

A study was conducted to understand the hydrogeological processes dominating in the North 24 Parganas and South 24 Parganas based on representative 39 groundwater samples collected from selected area. The abundance of major ions was in the order of Ca²⁺ > Na⁺ > Mg²⁺ > K⁺ > Fe²⁺ for cations and HCO₃ ^? > PO₄ ^3? > Cl^? > SO₄ ^2? > NO₃ ^? for anions. Piper trilinear diagram was plotted to understand the hydrochemical facies. Most of the samples are of Ca-HCO₃ type. Based on conventional graphical plots for (Ca + Mg) vs. (SO₄ + HCO₃) and (Na + K) vs. Cl, it is interpreted that silicate weathering and ion exchange are the dominant processes within the study area. Previous studies have reported quartz, feldspar, illite, and chlorite clay minerals as the major mineral components obtained by the XRD analysis of sediments. Mineralogical investigations by SEM and EDX of aquifer materials have shown the occurrence of arsenic as coating on mineral grains in the silty clay as well as in the sandy layers. Excessive withdrawal of groundwater for irrigation and drinking purposes is responsible for fluctuation of the water table in the West Bengal. Aeration beneath the ground surface caused by fluctuation of the water table may lead to the formation of carbonic acid. Carbonic acid is responsible for the weathering of silicate minerals, and due to the formation of clay as a product of weathering, ion exchange also dominates in the area. These hydrogeological processes may be responsible for the release of arsenic into the groundwater of the study area, which is a part of North 24 Parganas and South 24 Parganas.     

Hydrogeochemical investigation and groundwater quality assessment of Pratapgarh district,Uttar Pradesh

Hydogrochemical investigation of groundwater resources of Paragraph district has been carried out to assess the solute acquisition processes and water quality for domestic and irrigation uses. Fifty-five groundwater samples were collected and analyzed for pH, electrical conductivity, total dissolved solids, hardness, major anions (F^?, Cl^?, NO₃, HCO₃ ^?, SO₄ ^2?) and cations (Ca²⁺, Mg²⁺, Na⁺, K⁺). Study results reveal that groundwater of the area is alkaline in nature and HCO₃ ^?, Cl^?, Mg²⁺, Na⁺ and Ca²⁺ are the major contributing ions to the dissolved solids. The hydrogeochemical data suggest that weathering of rock forming minerals along with secondary contributions from agricultural and anthropogenic sources are mainly controlling the groundwater composition of Pratapgarh district. Alkaline earth metals (Ca²⁺+Mg²⁺) exceed alkalis (Na⁺+K⁺) and weak acid (HCO₃ ^?) dominate over strong acids (Cl^?+SO₄ ^2?) in majority of the groundwater samples. Ca-Mg-HCO₃ and Ca-Mg-Cl-HCO₃ are the dominant hydrogeochemical facies in the groundwater of the area. The computed saturation indices demonstrate oversaturated condition with respect to dolomite and calcite and undersaturated with gypsum and fluorite. A comparison of groundwater quality parameters in relation to specified limits for drinking water shows that concentrations of TDS, F^?, NO₃ ^? and total hardness exceed the desirable limits in many water samples. Quality assessment for irrigation uses reveal that the groundwater is good for irrigation. However, values of salinity, sodium adsorption ratio (SAR), residual sodium carbonate (RSC), %Na and Kelley index are exceeding the prescribed limit at some sites, demanding adequate drainage and water management plan for the area.     

Nine years of GPS measurements of crustal deformation at Imphal,Indo-Burmese wedge

We report results of 9 years of GPS measurements of crustal deformation at Imphal, Manipur, a site located in the Indo-Burmese wedge of northwest Sunda arc. The analysis of these measurements suggests that the site moves at a rate of about 36.3±0.5 mm/year towards N55° in the ITRF2008. With respect to the Indian plate it moves at a rate of 16.7 mm/year towards N222°, i.e., predominantly towards southwest. The site is located about 15 km east of the Churachandpur Mao fault (CMF), which is reported to accommodate part of the India-Sunda motion. The site motion is not significantly affected by the earthquakes that occurred in the nearby region. However, the 2004 Sumatra-Andaman earthquake caused a coseismic displacement of ～ 3–5 mm predominantly towards southwest. The site motion is almost linear, with some seasonal variation, and does not show any evidence of accelerated slip or slow earthquake on the CMF or along the plate boundary.     

Provenance of the late Paleocene sandstones of the Jaisalmer Basin,Western India

Provenance of the late Paleocene sandstone of the Jaisalmer basin has been determined by petrographic and heavy minerals analysis supported by paleocurrent study. Petrography of the quartzose-arenite sandstone reveals an abundance of sub-angular to sub-rounded monocrystalline non-undulatory quartz and some amount of feldspar and rock fragments. The rock fragments are dominated by argillites (slate, phyllite) and limestone. The heavy minerals suite of these sandstones comprises of angular to sub-angular grains of magnetite, zircon, tourmaline, kyanite and staurolite. The paleocurrent analysis indicates bipolar paleocurrent pattern with the dominance of NW flow suggesting that the provenance was in the SE direction of the depositional basin. Q-F-L and Qm-F-Lt diagrams suggest for a provenance at the margin of the craton interior and transitional continental. It is envisaged that the basic igneous rocks of the Deccan basalt, low- to medium-grade metamorphic rocks of the Aravalli belt and Jurassic limestones present in the vicinity are the source rocks for the late Paleocene sandstones of the Jaisalmer basin.     

New finding of sillmanite in sapphirine-bearing granulites from Pedapalli,NE part of the Eastern Dharwar Craton,India

We report the occurrence of sillimanite in sapphirine-bearing granulites near Pedapalli town in the north eastern part of the Eastern Dharwar Craton (EDC). The sapphirine-bearing granulites of the Pedapalli area display evidence of metamorphic reactions involved in the formation of diverse mineral assemblages documented in different types of reaction textures. The common stable assemblage contains sapphirine-spinel-orthopyroxene-cordieriteplagioclage-corundum-sillimanite. The P-T evolution of these sapphirine granulites has been constrained by using the TWEEQU program. Temperature of formation of sapphirine-spinel assemblages is high, around 800 °C, and pressure ca. 8 kbar. The assemblage reported in this study has important bearing on the high-temperature metamorphism and exhumation history of the EDC.