Accurate ocean tide modeling in southeast Alaska and large tidal dissipation around Glacier Bay

An accurate prediction of ocean tides in southeast Alaska is developed using a regional, barotropic ocean model with a finite difference scheme. The model skill is verified by the observational tidal harmonics in southeast Alaska including Glacier Bay. The result is particularly improved in Glacier Bay compared to the previous model described by Foreman et al. (2000). The model bathymetry dominates the model skill. We re-estimate tidal energy dissipation in the Alaska Panhandle and suggest a value for tidal energy dissipation of 3.4 GW associated with the M₂ constituent which is 1.5 times the estimation of Foreman et al. (2000). A large portion of the M₂ energy budget entering through Chatham Strait is dissipated in the vicinity of Glacier Bay. Moreover, it is shown that the developed model has the potential to correct the ocean tide loading effect in geodetic data more efficiently than the model of Foreman et al. (2000), especially around Glacier Bay.     

Polycyclic aromatic hydrocarbons in gulf of maine sediments: Distributions and mode of transport

Sediments from 19 stations in the Gulf of Maine were analyzed for 16 priority polycyclic aromatic hydrocarbon (PAH) compounds in 1983. Thirteen of the compounds were distributed widely with total concentrations ranging from 10–512 ppb (dry wt). These values are an order of magnitude lower than those observed in the coastal zone but higher than those on Georges Bank. PAH concentration was directly related to grain size, total organic carbon (TOC) and distance from source. PAHs appear to be accumulating in Wilkinson and Jordan Basins but not in Georges Basin. Observed PAH distributions support the conclusion that the principal transport mechanism is through the atmosphere with localized augmentation by sediment resuspension and transport from coastal embayments.     

Tracing dissolved organic matter in aquatic environments using a new approach to fluorescence spectroscopy

Dissolved organic matter (DOM) is a complex and poorly understood mixture of organic polymers that plays an influential role in aquatic ecosystems. In this study we have successfully characterised the fluorescent fraction of DOM in the catchment of a Danish estuary using fluorescence excitation–emission spectroscopy and parallel factor analysis (PARAFAC). PARAFAC aids the characterisation of fluorescent DOM by decomposing the fluorescence matrices into different independent fluorescent components. The results reveal that at least five different fluorescent DOM fractions present (in significant amounts) in the catchment and that the relative composition is dependent on the source (e.g. agricultural runoff, forest soil, aquatic production). Four different allochthonous fluorescent groups and one autochthonous fluorescent group were identified. The ability to trace the different fractions of the DOM pool using this relatively cheap and fast technique represents a significant advance within the fields of aquatic ecology and chemistry, and will prove to be useful for catchment management.     

A New Video and Digital Camera System for Studies of the Dynamics of Microtopographic Features on Tidal Flats

A newly developed video and camera system for tidal flat microtopographic studies is presented. It consists of a SONY handy cam placed in an underwater housing mounted on a frame about 70 cm above the sediment surface. A rectangular surface area of 30 ×40 cm is imaged by the camera. The camera records video sequences and/or digital images at predetermined time lapses. The total number of images is about 540, and a similar number of 10-second long video sequences can be recorded. The camera is programmed with a PC before deployment, and the total deployment time depends on the time lapse between recordings. The camera is connected to an external power supply (12 volt), and a halogen projector pointing towards the sediment surface ensures that the system is operable on a 24-hours scale. The system has been tested in the Danish Wadden Sea. It has proved to be a very useful tool in studies of topographic effects of erosion and deposition sequences, and for studies of benthic organisms-sediment interactions. The test site was further equipped with sensors for water and seabed measurements, which proved to be indispensable regarding the interpretation of recorded image time-series.     

Biochemical and histological responses in mussel (Mytilus edulis) exposed to North Sea oil and to a mixture of North Sea oil and alkylphenols

Several environmental chemicals are suspected to be responsible for adverse health effects on the reproductive system in various organisms. During this work, environmentally relevant concentrations of North Sea oil were used alone or in combination with alkylphenols and additional PAH to study the effect on vitellogenin-like protein expression and gonadal development in mussels. North Sea oil (0.5 ppm) induced the expression of phospho-proteins in both sexes indicating that some compounds are oestrogen-mimics. This induction was not seen in samples dosed with the mixture but signs of toxic effects were observed in the gonads. Indeed, numerous degenerating ovarian follicles in females and foci, similar to vertebrate melanomacrophage centres, were observed in testes.     

Climate change risks for severe storms in developing countries in the context of poverty and inequality in Cambodia

Least developed countries are generally regarded as particularly sensitive to climate change due to among other vulnerable locations and low adaptation capabilities. In the present study, we address climate change hazards in least developed countries by presenting a methodological framework, which is suitable for the estimation damage costs as a function of risk aversion, equality, income distribution and climate scenario using state-of-the-art climate model projections. As a case study, the methodology is applied to study severe storms in Cambodia based on two future climate scenarios and data on historical damages from storm events, which are used as a proxy in performing a sensitivity analysis on all input parameters. For the assumptions and parameter ranges used here, the study shows a high sensitivity to the income distribution (reflected by discount rates) and risk aversion and smaller effects from equality measures and extreme wind climate scenario. We emphasize that the assumptions on risk aversion reflecting consumption smoothing possibilities of low-income households clearly depicts that climate risks can be particularly high as a consequence of poverty and therefore recommend that context-specific vulnerabilities and equity concerns in climate risk studies should be included when making assessments for least developed countries.     

Geochemistry at the sulfate reduction-methanogenesis transition zone in an anoxic aquifer—A partial equilibrium interpretation using 2D reactive transport modeling

The study addresses a 10 m deep phreatic postglacial sandy aquifer of vertically varying lithology and horizontally varying infiltration water chemistry, displaying calcite dissolution, ion-exchange, and anaerobic redox processes. The simple variations in lithology and infiltration combine into a complex groundwater chemistry, showing ongoing Fe-oxide reduction, sulfate reduction and methanogenesis. Rates of sulfate reduction, methanogenesis and methane oxidation were measured directly using radiotracers. Maximum rates were 1.5 mM/yr for sulfate reduction, 0.3 mM/yr for methanogenesis, and only 4.5 μM/yr for methane oxidation. The overlap of sulfate reduction and methanogenesis was very small. The important intermediates formed during the degradation of the organic matter in the sediment, formate and acetate, had concentrations around 2 μM in the sulfate reducing zone, increasing to 10 and 25 μM in the methanogenic part. The concentration of H₂ was around 0.25 nM in the Fe-reducing zone, 0.4 nM in the sulfate reducing zone, and increased to 6 nM in the methanogenic zone. Using in situ concentrations of products and reactants the available energies for a range of different reactions could be calculated. The results of the calculations are in accordance with the observed distribution of the ongoing redox processes, implying that the system is well described using a partial equilibrium approach. A 2D numerical PHAST model of the system based on the partial equilibrium approach, extended by implementing specific energy yields for the microbial redox processes, could explain most of the observed groundwater geochemistry as an expression of a closely coupled system of mineral equilibria and redox processes occurring at partial equilibrium.     

Investigating the last deglaciation of the Scandinavian Ice Sheet in southwest Sweden with 10Be exposure dating

In this study we have obtained 17 cosmogenic exposure ages from three well‐developed moraine systems – Halland Coastal Moraines (HCM), Göteborg Moraine (GM) and Levene Moraine (LM) – which were formed during the last deglaciation in southwest Sweden by the Scandinavian Ice Sheet (SIS). The inferred ages of the inner HCM, GM and LM are 16.7 ± 1.6, 16.1 ± 1.4 and 13.6 ± 1.4 ka, respectively, which is slightly older than previous estimates of the deglaciation based on the minimum limiting radiocarbon ages and pollen stratigraphy. During this short interval from 16.7 ± 1.6 to 13.6 ± 1.4 ka a large part (100–125 km) of the marine‐based sector of the SIS in southwest Sweden was deglaciated, giving an average ice margin retreat between 20 to 50 m a^?1. The inception of the deglaciation pre‐dated the Bølling/Allerød warming, the rapid sea level rise at 14.6 cal. ka BP and the first inflow of warm Atlantic waters into Skagerrak. We suggest that ice retreat in southwest Sweden is mainly a dynamical response governed by the disintegration of the Norwegian Channel Ice Stream and not primarily driven by climatic changes. Copyright © 2011 John Wiley & Sons, Ltd.     

Sorption of phosphate onto calcite; results from batch experiments and surface complexation modeling

The adsorption of phosphate onto calcite was studied in a series of batch experiments. To avoid the precipitation of phosphate-containing minerals the experiments were conducted using a short reaction time (3 h) and low concentrations of phosphate (?50 μM). Sorption of phosphate on calcite was studied in 11 different calcite-equilibrated solutions that varied in pH, P_CO2, ionic strength and activity of Ca²⁺, and . Our results show strong sorption of phosphate onto calcite. The kinetics of phosphate sorption onto calcite are fast; adsorption is complete within 2-3 h while desorption is complete in less than 0.5 h. The reversibility of the sorption process indicates that phosphate is not incorporated into the calcite crystal lattice under our experimental conditions. Precipitation of phosphate-containing phases does not seem to take place in systems with ?50 μM total phosphate, in spite of a high degree of super-saturation with respect to hydroxyapatite (SI_HAP ? 7.83). The amount of phosphate adsorbed varied with the solution composition, in particular, adsorption increases as the activity decreases (at constant pH) and as pH increases (at constant activity). The primary effect of ionic strength on phosphate sorption onto calcite is its influence on the activity of the different aqueous phosphate species. The experimental results were modeled satisfactorily using the constant capacitance model with >CaPO₄Ca⁰ and either >CaHPO₄Ca⁺ or > as the adsorbed surface species. Generally the model captures the variation in phosphate adsorption onto calcite as a function of solution composition, though it was necessary to include two types of sorption sites (strong and weak) in the model to reproduce the convex shape of the sorption isotherms.     

Atmosphere–Surface Fluxes of CO<Subscript>2</Subscript> using Spectral Techniques

Different flux estimation techniques are compared here in order to evaluate air–sea exchange measurement methods used on moving platforms. Techniques using power spectra and cospectra to estimate fluxes are presented and applied to measurements of wind speed and sensible heat, latent heat and CO₂ fluxes. Momentum and scalar fluxes are calculated from the dissipation technique utilizing the inertial subrange of the power spectra and from estimation of the cospectral amplitude, and both flux estimates are compared to covariance derived fluxes. It is shown how even data having a poor signal-to-noise ratio can be used for flux estimations.