Assessment to the potential mobility and toxicity of metals and metalloids in soils contaminated by old Sb–Au and As–Au mines (NW Portugal)

The main purpose of this study is to assess arsenic and antimony availability in soils, as well as Co, Cr, Cu, Fe, Mn, Ni, Pb and Zn availability in soils derived from the schist–metagraywacke complex close to old Sb–Au mines and in soils developed from Ordovician slates and close to an old As–Au mine in Portugal. The availability was determined using a European certified sequential extraction procedure (BCR). The results demonstrated that metalloids are not readily bioavailable, because they are mainly associated with the residual fraction. Arsenic and antimony proportions in exchangeable fractions are up to 3 and 1%, respectively. However, arsenic is up to 24% in oxy-hydroxide fractions, while antimony is up to 4% in them, demonstrating the highest bioavailability of arsenic compared to that of antimony, as metalloids are weakly bound to the soils in that fraction. Therefore, arsenic tends to be more toxic than antimony in all soils studied. However, the pseudo-total contents show that both metalloids are above the Italian and Dutch guidelines. Therefore, if physico-chemical changes occur arsenic and antimony will show higher potential environmental risk than evidenced by Co, Cr, Cu, Fe, Mn, Ni, Pb and Zn.     

Scour at the head of a vertical-wall breakwater

This paper presents the results of an experimental investigation on the near-bed flow patterns, the bed shear stress amplification and scour around the head of a vertical-wall breakwater, using regular waves. The Keulegan-Carpenter number (KC), based on the diameter of the breakwater head, is found to be the major parameter that governs the flow and the equilibrium scour depth. Basic flow structures are identified as function of KC. The scour depth is found to increase with increasing the Keulegan-Carpenter number. The necessary extent of the conventional stone protection is studied. An empirical formula is worked out for the width of the protection layer as function of KC. Also, the effects of head shape, the angle of attack and the presence of a co-directional current are investigated. The results indicate that the scour depth is increased considerably in the presence of a current. Likewise, the scour depth is increased when the head shape is changed from a round shape to a sharp-edged one. It is found that the angle of attack is also an influencing factor as regards the scour depth.     

Precursory seismicity of the 1994 eruption of Popocatépetl Volcano,Central Mexico

Popocatépetl Volcano is located in the central Mexican Volcanic Belt, within a densely populated region inhabited by over 20 million people. The eruptive history of this volcano indicates that it is capable of producing a wide range of eruptions, including Plinian events. After nearly 70 years of quiescence, Popocatépetl reawakened in December 21, 1994. The eruptive activity has continued up until the date of this submission and has been characterized by a succession of lava dome growth-and-destruction episodes, similar to events that have apparently been typical for Popocatépetl since the fourteenth century. In this regime, the episodes of effusive and moderately explosive activity alternate with long periods of almost total quiescence. In this paper we analyze five years of volcano-tectonic seismicity preceding the initial eruption of the current episode. The evolution of the V-T seismicity shows four distinct stages, which we interpret in terms of the internal processes which precede an eruption after a long period of quiescence. The thermal effects of a magma intrusion at depth, the fracturing related to the slow development of magma-related fluid pathways, the concentration of stress causing a protracted acceleration of this process, and a final relaxation or redistribution of the stress shortly before the initial eruption are reflected in the rates of V-T seismic energy release. A hindsight analysis of this activity shows that the acceleration of the seismicity in the third stage asymptotically forecast the time of the eruption. The total seismic energy release needed to produce an eruption after a long period of quiescence is related to the volume of rock that must be fractured so imposing a characteristic threshold limit for polygenetic volcanoes, limit that was reached by Popocatépetl before the eruption.     

Importance of mixotrophic nanoplankton in Aysén Fjord (Southern Chile) during austral winter

Mixotrophy, the combination of autotrophic and heterotrophic nutrition in the same organism, is widespread in planktonic algae. Several reports from temperate and high-latitude fjords in Scandinavia suggest the occurrence of a niche in late summer and autumn during post-bloom conditions in which mixotrophic algae can become important grazers in pelagic ecosystems, accessing the nutrients bound in their prey to overcome nutrient limitation. Here, we experimentally determined the trophic modes and bacterivory rates for the nanoplankton community (2–20 μm) in Aysén Fjord located in the Chilean Northern Patagonia during two contrasting seasons: winter and spring. While mixotrophic nanoplankton was virtually absent from the system in spring, in winter at occasions it even constituted the dominant trophic group of the nanoplankton with abundances of >900 cells mL^?1. This indicates a second niche for mixotrophs in winter, when mixotrophy allows overcoming light limitation.     

Onset of scour below pipelines and self-burial

This paper summarizes the results of an experimental study on the onset of scour below and self-burial of pipelines in currents/waves. Pressure was measured on the surface of a slightly buried pipe at two points, one at the upstream side and the other at the downstream side of the pipe, both in the sand bed. The latter enabled the pressure gradient (which drives a seepage flow underneath the pipe) to be calculated. The results indicated that the excessive seepage flow and the resulting piping are the major factor to cause the onset of scour below the pipeline. The onset of scour occurred always locally (but not along the length of the pipeline as a two-dimensional process). The critical condition corresponding to the onset of scour was determined both in the case of currents and in the case of waves. Once the scour breaks out, it will propagate along the length of the pipeline, scour holes being interrupted with stretches of soil (span shoulders) supporting the pipeline. As the span shoulder gets shorter and shorter, more and more weight of the pipeline is exerted on the soil. In this process, a critical point is reached where the bearing capacity of the soil is exceeded (general shear failure). At this point, the pipe begins to sink at the span shoulder (self-burial). It was found that the self-burial depth is governed mainly by the Keulegan–Carpenter number. The time scale of the self-burial process, on the other hand, is governed by the Keulegan–Carpenter number and the Shields parameter. Diagrams are given for the self-burial depth and the time scale of the self-burial process.     

La phase de la composante annuelle des niveaux des rivières de la plaine de l'Est Européen

Résumé L'étude publiée intéresse l'ensemble des échelles hydrométriques de la plaine de l'Est européen. Les moyennes mensuelles des niveaux ont été élaborées par la méthode d'analyse par combinaisons linéaires d'ordonnées, due à M. et MmeLabrouste, afin de définir la phase de la composante annuelle. La carte de la répartition de la phase et les profils de celle-ci le long des cours d'eau, montrent que cette répartition est commandée par le relief, ainsi que par la marche saisonnière des températures, ce qui permet d'expliquer les particularités constatées par les causes naturelles: altitudes, forme et extension du bassin, etc.

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Summary The research deals with the hydrographic observations of the East-Europe's plain. The monthly means of the water level have been elaborated after the method of Mr. and Mrs.Labrouste with the aim to determine the phase of the yearly component. The map of the phase distribution and the profiles along the streams shows that this distribution is governed by the physiography, as well as by the seasonal course of the temperatures, what can permit to explain the observed particularities.

     

Separation of PP- and PS-wave reflected seismic data using two-dimensional finite offset common-reflection-surface traveltime approximation

Recently, the interest in PS-converted waves has increased for several applications, such as sub-basalt layer imaging, impedance estimates and amplitude-versus-offset analysis. In this study, we consider the problem of separation of PP- and PS-waves from pre-stacked multicomponent seismic data in two-dimensional isotropic medium. We aim to demonstrate that the finite-offset common-reflection-surface traveltime approximation is a good alternative for separating PP- and PS-converted waves in common-offset and common shot configurations by considering a two-dimensional isotropic medium. The five parameters of the finite-offset common-reflection-surface are firstly estimated through the inversion methodology called very fast simulated annealing, which estimates all parameters simultaneously. Next, the emergence angle, one of the inverted parameters, is used to build an analytical separation function of PP and PS reflection separation based on the wave polarization equations. Once the PP- and PS-converted waves were separated, the sections are stacked to increase the signal-to-noise ratio using the special curves derived from finite-offset common-reflection-surface approximation. We applied this methodology to a synthetic dataset from simple-layered to complex-structured media. The numerical results showed that the inverted parameters of the finite offset common-reflection-surface and the separation function yield good results for separating PP- and PS-converted waves in noisy common-offset and common shot gathers.     

Images of Gradual Millimeter Emission and Multi-Wavelength Observations of the 17 august 1994 Solar Flare

We present a comprehensive analysis of the 17 August 1994 flare, the first flare imaged at millimeter (86 GHz) wavelengths. The temporal evolution of this flare displays a prominent impulsive peak shortly after 01:02 UT, observed in hard X-rays and at microwave frequencies, followed by a gradual decay phase. The gradual phase was also detected at 86 GHz. Soft X-ray images show a compact emitting region (20), which is resolved into two sources: a footpoint and a loop top source. Nonthermal emissions at microwave and hard X-ray wavelengths are analyzed and the accelerated electron spectrum is calculated. This energy spectrum derived from the microwave and hard X-ray observations suggests that these emissions were created by the same electron population. The millimeter emission during the gradual phase is thermal bremsstrahlung originating mostly from the top of the flaring loop. The soft X-rays and the millimeter flux density from the footpoint source are only consistent with the presence of a multi-temperature plasma at the footpoint.