Comparisons of homogeneously reprocessed GPS and VLBI long time-series of troposphere zenith delays and gradients

Troposphere parameters estimated from space-geodetic techniques, like the Global Positioning System (GPS) or Very Long Baseline Interferometry (VLBI), can be used to monitor the atmospheric water vapor content. Although the troposphere can only be monitored at discrete locations, the distribution of the instruments, at least the GPS antennas, can be assumed to be quasi-global. Critical in the data analysis are systematic effects within each single technique that significantly degrade the accuracy and especially the long-term stability of the zenith delay determination. In this paper, consistent time-series of troposphere zenith delays and gradients from homogeneously reprocessed GPS and VLBI solutions are compared for a time period of 11 years. The homogeneity of these completely reprocessed time-series is essential to avoid misinterpretations due to individual model changes. Co-located sites are used to investigate systematic effects and the long-term behavior of the two space-geodetic techniques. Both techniques show common signals in the troposphere parameters at a very high level of precision. The biases between the troposphere zenith delays are at the level of a few millimeters. On the other hand, long-term trends significantly differ for the two techniques, preventing climatological interpretations at present. Tests assume these differences to be due to mathematical artifacts such as different sampling rates and unmodeled semi-annual signals with varying amplitudes.     

Be exposure dating of river terraces at the southern mountain front of the Dzungarian Alatau (SE Kazakhstan) reveals rate of thrust faulting over the past ~ 400 ka

The mountain belts of the Dzungarian Alatau (SE Kazakhstan) and the Tien Shan are part of the actively deforming India–Asia collision zone but how the strain is partitioned on individual faults remains poorly known. Here we use terrace mapping, topographic profiling, and ¹⁰Be exposure dating to constrain the slip rate of the 160-km-long Usek thrust fault, which defines the southern front of the Dzungarian Alatau. In the eastern part of the fault, where the Usek River has formed five terraces (T₁–T₅), the Usek thrust fault has vertically displaced terrace T₄ by 132 ± 10 m. At two sites on T₄, exposure dating of boulders, amalgamated quartz pebbles, and sand from a depth profile yielded ¹⁰Be ages of 366 ± 60 ka and 360 ^+ 77/_− 48 ka (both calculated for an erosion rate of 0.5 mm/ka). Combined with the vertical offset and a 45–70° dip of the Usek fault, these age constraints result in vertical and horizontal slip rates of ~ 0.4 and ~ 0.25 mm/a, respectively. These rates are below the current resolution of GPS measurements and highlight the importance of determining slip rates for individual faults by dating deformed landforms to resolve the pattern of strain distribution across intracontinental mountain belts.     

From seamount to oceanic island, Porto Santo, central East-Atlantic

The uplifted and deeply eroded volcanic succession of Porto Santo (central East-Atlantic) is the product of a wide spectrum of dynamic processes that are active in shoaling to emergent seamounts. Two superimposed lapilli cones marking the base of the exposed section are interpreted as having formed from numerous submarine to subaerial phreatomagmatic explosions, pyroclastic fragmentation being subordinate. The lower basaltic and the upper mugearitic to trachytic sections are dominated by redeposited tephra and are called 'lapilli cone aprons'. Vertical growth due to accumulation of tephra, voluminous intrusions, and minor pillowed lava flows produced ephemeral islands which were subsequently leveled by wave erosion, as shown by conglomerate beds. Periods of volcanic quiescence are represented by abundant biocalcarenite lenses at several stratigraphic levels. The loose tephra piles became stabilized by widespread syn-volcanic intrusions such as dikes and trachytic to rhyolitic domes welding the volcanic and volcaniclastic ensemble into a solid edifice. Shattering of a submarine extrusive trachytic dome by pyroclastic and phreatomagmatic explosions, accentuated by quench fragmentation, resulted in pumice- and crystal-rich deposits emplaced in a prominent submarine erosional channel. The dome must have produced an island as indicated by a collapse breccia comprising surf-rounded boulders of dome material. Subaerial explosive activity is represented by scoria cones and tuff cones. Basaltic lava flows built a resistant cap that protected the island from wave erosion. Some lava flows entered the sea and formed two distinct types of lava delta: 1. closely-packed pillow lava and massive tabular lava flows along the southwestern coast of Porto Santo, and 2. a steeply inclined pillow-hyaloclastite breccia prism composed of foreset-bedded hydroclastic breccia, variably-shaped pillows, and thin sheet flows capped by subhorizontal submarine to subaerial lava flows along the eastern coast of Porto Santo.The facies architectures indicate emplacement: 1. on a gently sloping platform in southwestern Porto Santo, and 2. on steep offshore slopes along high energy shorelines in eastern Porto Santo.Growth of the pillow-hyaloclastite breccia prism is dominated by the formation of foreset beds but various types of syn-volcanic intrusions contributed significantly. Submarine flank eruptions occurred in very shallow water on the flanks of the hyaloclastite prism in eastern Porto Santo. The island became consolidated by intrusion of numerous dikes and by emplacement of prominent intrusions that penetrate the entire volcanic succession. Volcanic sedimentation ended with the emplacement of a debris avalanche that postdates the last subaerial volcanic activity.     

Methane and carbon dioxide adsorption–diffusion experiments on coal: upscaling and modeling

Numerical modelling of the processes of CO₂ storage in coal and enhanced coalbed methane (ECBM) production requires information on the kinetics of adsorption and desorption processes. In order to address this issue, the sorption kinetics of CO₂ and CH₄ were studied on a high volatile bituminous Pennsylvanian (Upper Carboniferous) coal (VR_r=0.68%) from the Upper Silesian Basin of Poland in the dry and moisture-equilibrated states. The experiments were conducted on six different grain size fractions, ranging from <0.063 to 3 mm at temperatures of 45 and 32 °C, using a volumetric experimental setup. CO₂ sorption was consistently faster than CH₄ sorption under all experimental conditions. For moist coals, sorption rates of both gases were reduced by a factor of more than 2 with respect to dry coals and the sorption rate was found to be positively correlated with temperature. Generally, adsorption rates decreased with increasing grain size for all experimental conditions.Based on the experimental results, simple bidisperse modelling approaches are proposed for the sorption kinetics of CO₂ and CH₄ that may be readily implemented into reservoir simulators. These approaches consider the combination of two first-order reactions and provide, in contrast to the unipore model, a perfect fit of the experimental pressure decay curves. The results of this modeling approach show that the experimental data can be interpreted in terms of a fast and a slow sorption process. Half-life sorption times as well as the percentage of sorption capacity attributed to each of the two individual steps have been calculated.Further, it was shown that an upscaling of the experimental and modelling results for CO₂ and CH₄ can be achieved by performing experiments on different grain size fractions under the same experimental conditions.In addition to the sorption kinetics, sorption isotherms of the samples with different grain size fractions have been related to the variations in ash and maceral composition of the different grain size fractions.     

Characteristics of turnover of carbonyl sulfide in four different soils

Release and uptake of carbonyl sulfide (OCS) were measured at 25°C in samples of three forest soils (BL, BW, PBE) and one soil from a rape field (RA). The soil samples were flushed with a constant flow of either air (oxic conditions) or nitrogen (anoxic conditions) containing defined concentrations of OCS. A cryogenic trapping technique with liquid argon (-186 °C) was used to collect gas samples for analysis in a gas chromatograph equipped with a flame-photometric detector. The dependence of net OCS fluxes between soil and atmosphere could be described by a simple model of simultaneous OCS production and OCS uptake. By using this model, production rates (P), uptake rate constants (k) and compensation concentrations (m _c ) of OCS could be determined as function of the soil type and the incubation conditions. Under oxic conditions, OCS production (P) and uptake were observed in all soils tested. However, the compensation concentrations (<166 ng l^-1; 1 ng OCS l^-1=0.41 ppbv) that were calculated from the model were high relative to the ambient OCS concentration (ca. 0.5 ppbv). The production rates (0.16–1.9 ng h^-1 g^-1 dw) that were actually measured when flushing the soil samples with air containing zero OCS were smaller than those (17–114 ng h^-1 g^-1 dw) calculated from the model. This observation was explained by two different concepts: one assuming the existence of a threshold concentration (m _t ) below which OCS was no longer consumed in the soil; the other assuming the existence of two different OCS consumption processes, of which only the process active at elevated OCS concentrations was covered by the experiments. The latter concept allowed the estimation of OCS compensation concentrations that were partially low enough to allow the uptake of atmospheric OCS by soil. Both OCS production and uptake in PBE soil were dependent on soil temperature (optimum 20 °C) indicating a microbial process. However, both production and consumption of OCS were not consistently inhibited by sterilization of the soil, suggesting that they were not exclusively due to microbiological processes. Under anoxic conditions, OCS was also produced, but was not consumed except in one soil (RA). Production of OCS in the soils was stimulated after addition of thiocyanate, but not thiourea, thiosulfate, thioglycolate, tetrathionate, sulfate, elemental sulfur, cysteine and methionine.     

Analysis of unanchored liquid storage tanks under lateral loads

Many liquid storage tanks consist of a steel cylindrical shell, which is welded to a base plate, but not fixed to the foundation. When such an unanchored tank is subjected to lateral loads due to earthquake induced hydrodynamic pressures in the liquid, the tank wall tends to uplift locally, pulling the base plate up with it. The contact problem of the partially uplifted base plate and its interaction with the the cylindrical shell is solved in this paper using the finite difference energy method, and a Fourier decomposition of the displacements in the circumferential direction. Non-linearities due to contact, finite displacements and yield of the steel are included in the analysis. However, the equations for the shell are linearized. This uncouples the equations for the Fourier displacement coefficients in the cylindrical shell, and enables the degrees of freedom for the shell to be eliminated by static condensation at very little computational cost. Comparing the analytical results to (for the most part existing) experimental results, produces good agreement in some cases and not so good in others. A number of effects that could give rise to such differences are discussed. In most cases they represent experimental conditions that are not known or modelled in the analysis. The analysis results are also compared to those from a simplified analysis in which the hold-down action of the base plate is modelled by means of nonlinear Winkler springs.