Distribution of polycyclic musks in water and particulate matter of the Lippe River (Germany)

The occurrence and distribution of polycyclic musks in the Lippe River system (a tributary of the Rhine River, Germany) was investigated in order to observe the dynamic transport and partitioning of these compounds between aqueous and particulate phases after their discharge into the river by sewage effluents. 1,3,4,6,7,8-Hexahydro-4,6,6,7,8,8-hexamethylcyclopenta[g]-2-benzopyrane (HHCB), 7-acetyl-1,1,3,4,4,6-hexamethyl-1,2,3,4-tetrahydronaphthalene (AHTN), 6-acetyl-1,1,2,3,3,5-hexamethylindane (AHMI) and 4-acetyl-1,1-dimethyl-6-tert.-butylindane (ADBI) concentrations were determined in 19 water and surface sediment samples which were taken from a longitudinal section of the river. HHCB and AHTN were present in each of the water samples at concentrations ranging from <10 to 180 ng l⁻¹ and <10 to 70 ng l⁻¹, respectively. The load of dissolved HHCB and AHTN was calculated on the basis of compound concentrations in water and the corresponding river runoff data and ranged from 3 to 293 g day⁻¹ and from 1 to 108 g day⁻¹, respectively. Increasing loads of HHCB and AHTN along the river reflect a high input of sewage effluents to the densely populated areas along the central part of the river. Decreasing loads at the lower reaches indicate that in the corresponding river sections the rate of removal of musks was higher than the rate of input. Degradation and/or adsorption to particulate matter are processes that might explain this phenomenon. Consequently, high concentrations of HHCB and AHTN were detected in surface sediments from the Lippe River (from 5 to 191 μg kg⁻¹ and from 2 to 1399 μg kg⁻¹, respectively). HHCB/AHTN ratios in sediment samples were lower (average 1.2) than in water samples (average 2.9), suggesting the preferential adsorption of AHTN to particulate matter.     

Sodic Pyroxene and Sodic Amphibole as Potential Reference Materials for In Situ Lithium Isotope Determinations by SIMS

Two large pegmatitic crystals of sodic pyroxene (aegirine) and sodic amphibole (arfvedsonite) from the agpaitic igneous Ilímaussaq Complex, south Greenland were found to be suitable as reference materials for in situ Li isotope determinations. Lithium concentrations determined by SIMS and micro‐drilled material analysed by MC‐ICP‐MS generally agreed within analytical uncertainty. The arfvedsonite crystal was homogeneous with [Li] = 639 ± 51 μg g^?1 (2s, n = 69, MC‐ICP‐MS and SIMS results). The aegirine crystal shows strongly developed sector zoning, which is a common feature of aegirines. Using qualitative element mapping techniques (EPMA), the homogeneous core of the crystal was easily distinguished from the outermost sectors of the crystals. The core had a mean [Li] of 47.6 ± 3.6 μg g^?1 (2s, n = 33) as determined by SIMS. The seven micro‐drilled regions measured by solution MC‐ICP‐MS returned slightly lower concentrations (41–46 μg g^?1), but still overlap with the SIMS data within uncertainty. Based on MC‐ICP‐MS and SIMS analyses, the variation in δ⁷Li was about 1‰ in each of the two crystals, which is smaller than that in widely used glass reference materials, making these two samples suitable to serve as reference materials. There was, however, a significant offset between the results of MC‐ICP‐MS and SIMS. The latter deviated from the MC‐ICP‐MS results by ?6.0 ± 1.9‰ (2s) for the amphibole and by ?3.9 ± 1.9‰ (2s) for the aegirine. This indicates the presence of a significant matrix effect in SIMS determinations of Li isotopes for amphibole and pyroxene relative to the basalt glasses used for calibration. Based on the MC‐ICP‐MS results, mean δ⁷Li values of +0.7 ± 1.2‰ (2s, n = 10) for the arfvedsonite crystal and of ?3.7 ± 1.2‰ (2s, n = 7) for the core of the aegirine crystal were calculated. Adopting these values, SIMS users can correct for the specific IMF (instrumental mass fractionation) of the ion probe used. We propose that these two crystals serve as reference materials for in situ Li isotope determinations by SIMS and pieces of these two crystals are available from the first author upon request.     

Integrated 3D forward stratigraphic and petroleum system modeling of the Levant Basin,Eastern Mediterranean

The Eastern Mediterranean Levant Basin is a proven hydrocarbon province with recent major gas discoveries. To date, no exploration wells targeted its northern part, in particular the Lebanese offshore. The present study assesses the tectono‐stratigraphic evolution and related petroleum systems of the northern Levant Basin via an integrated approach that combines stratigraphic forward modeling and petroleum systems/basin modeling based on the previous published work. Stratigraphic modeling results provide a best‐fit realisation of the basin‐scale sedimentary filling, from the post‐rift Upper Jurassic until the Pliocene. Simulation results suggest dominant eastern marginal and Arabian Plate sources for Cenozoic siliciclastic sediments and a significant contribution from the southern Nilotic source mostly from Lower Oligocene to Lower Miocene. Basin modeling results suggest the presence of a working thermogenic petroleum system with mature source rocks localised in the deeper offshore. The generated hydrocarbons migrated through the deep basin within Jurassic and Cretaceous permeable layers towards the Latakia Ridge in the north and the Levant margin and offshore topographic highs. Furthermore, the basin model indicates a possibly significant influence of salt deposition during Messinian salinity crisis on formation fluids. Ultimately, the proposed integrated workflow provides a powerful tool for the assessment of petroleum systems in underexplored areas.     

The Phase A study of the ESA M4 mission candidate ARIEL

ARIEL, the Atmospheric Remote sensing Infrared Exoplanet Large survey, is one of the three M-class mission candidates competing for the M4 launch slot within the Cosmic Vision science programme of the European Space Agency (ESA). As such, ARIEL has been the subject of a Phase A study that involved European industry, research institutes and universities from ESA member states. This study is now completed and the M4 down-selection is expected to be concluded in November 2017. ARIEL is a concept for a dedicated mission to measure the chemical composition and structure of hundreds of exoplanet atmospheres using the technique of transit spectroscopy. ARIEL targets extend from gas giants (Jupiter or Neptune-like) to super-Earths in the very hot to warm zones of F to M-type host stars, opening up the way to large-scale, comparative planetology that would place our own Solar System in the context of other planetary systems in the Milky Way. A technical and programmatic review of the ARIEL mission was performed between February and May 2017, with the objective of assessing the readiness of the mission to progress to the Phase B1 study. No critical issues were identified and the mission was deemed technically feasible within the M4 programmatic boundary conditions. In this paper we give an overview of the final mission concept for ARIEL as of the end of the Phase A study, from scientific, technical and operational perspectives.     

IMAGE: a multivariate multi-site stochastic weather generator for European weather and climate

Capturing the spatial and temporal correlation of multiple variables in a weather generator is challenging. A new massively multi-site, multivariate daily stochastic weather generator called IMAGE is presented here. It models temperature and precipitation variables as latent Gaussian variables with temporal behaviour governed by an auto-regressive model whose residuals and parameters are correlated through resampling of principle component time series of empirical orthogonal function modes. A case study using European climate data demonstrates the model’s ability to reproduce extreme events of temperature and precipitation. The ability to capture the spatial and temporal extent of extremes using a modified Climate Extremes Index is demonstrated. Importantly, the model generates events covering not observed temporal and spatial scales giving new insights for risk management purposes.     

Shear-wave velocity estimation using a combination of ambient noise from small aperture array and small-scale active seismic measurements: a case study in the area of the natural gas fields of Northern Germany

In recent years, numerous induced seismic events have occurred in the proximity of the natural gas field in Northern Germany. To monitor the seismicity and to asses the seismic hazard potential, a local monitoring network was installed in the area. Focusing on the seismicity hazard assessment, a major challenge is the characterisation of potential site effects due to local soil characteristics. This is quantitatively performed by estimating the shear-wave velocity (V _s) variation with subsurface layer thickness. Such local effects can only be covered with a coarse spatial resolution due to the limited number of monitoring stations. Profiles were determined at three test sites (Langwedel, Walle and Bomlitz) by using a combined approach of small aperture 2D array ambient noise and small-scale active 1D measurements. The high-resolution frequency-wavenumber (HRFK), spatial autocorrelation (SPAC) and multichannel analysis of surface waves (MASW) methods were applied to the recorded ambient noise and active seismic data using various array sizes supplemented by the active measurements. This jointly allowed obtaining phase velocity dispersion curves covering a wide frequency range from 2 up to 32 Hz. The inversion of the obtained dispersion curves results in average S-wave velocity profiles down to depths of 70 m, identifying thin near-surface layers of a few meters as well as thicker layers of tens of meters in greater depth. A comparison with available borehole data shows a good correlation with the layering. Additionally, to asses the impact of a seismic event at the test sites, PGV estimations for various seismic events were performed. The final results of the test surveys demonstrate that the combined approach represents a suitable tool for near-surface characterisation, which can be used to improve the seismic hazard assessment in the area of the natural gas fields in Northern Germany.     

Communicating landscape hydrology — the water cycle in a box

Physical models are a well‐established tool in education to strengthen hydrological understanding. They facilitate the straightforward visualization of hydrological processes and allow the communication of hydrological concepts, research and questions of general interest to the public. In order to visualize the water cycle in a landscape of postglacial sediments, in particular the subsurface part, a physical model was constructed. In two videos, (1) a detailed construction manual and (2) visualization examples of hydrological concepts and processes are presented. With our contribution, we like to encourage professionals in the field of hydrology to share methods and tools of knowledge transfer and communication of hydrological concepts. Copyright © 2016 John Wiley & Sons, Ltd.     

Choice chamber experiments to test the attraction of postflexion Rhabdosargus holubi larvae to water of estuarine and riverine origin

Although the recruitment of larvae and juveniles of marine fishes into estuaries has been well documented, little is known about the factors governing the immigration of estuary-associated marine fishes into estuaries. Fishes have a well-developed sense of smell and it has been suggested by several workers that olfactory cues of freshwater or estuarine origin serve as stimuli, attracting larvae and juveniles of estuary-associated species into estuaries. Attraction of postflexion Rhabdosargus holubi larvae to estuary and river water from the Kowie estuarine system, South Africa, was measured using a rectangular choice chamber. In experiments, conducted during peak recruitment periods, larvae selected estuary and river water with a significantly higher frequency than sea water. This study, the first to assess the possible role of olfaction in the recruitment process of an estuary-associated marine fish species, demonstrates that larvae are able to recognise water from different origins, probably based on odour.