New type of possible high-pressure polymorphism in NiAs minerals in planetary cores

The nickel arsenide (B8₁) and related crystal structures are among the most important crystallographic arrangements assumed by Fe and Ni compounds with light elements such as Si, O, S, and P, expected to be present in planetary cores. Despite the simple structure, some of these materials like troilite (FeS) exhibit complex phase diagrams and rich polymorphism, involving significant changes in interatomic bonding and physical properties. NiP (oP16) represents one of the two principal structure distortions found in the nickel arsenide family and is characterized by P–P bonding interactions that lead to the formation of P₂ dimers. In the current study, the single-crystal synchrotron X-ray diffraction technique, aided by first principles density functional theory (DFT) calculations, has been applied to examine the compression behavior of NiP up to 30 GPa. Two new reversible displacive phase transitions leading to orthorhombic high-pressure phases with Pearson symbols oP40 and oC24 were found to occur at approximately 8.5 and 25.0 GPa, respectively. The oP40 phase has the primitive Pnma space group with unit cell a = 4.7729(5) Å, b = 16.6619(12) Å, and c = 5.8071(8) Å at 16.3(1) GPa and is a superstructure of the ambient oP16 phase with multiplicity of 2.5. The oC24 phase has the acentric Cmc2₁ space group with unit cell a = 9.695(6) Å, b = 5.7101(9) Å, and c = 4.7438(6) Å at 28.5(1) GPa and is a superstructure of the oP16 phase with multiplicity of 1.5. DFT calculations fully support the observed sequence of phase transitions. The two new phases constitute logical next stages of P sublattice polymerization, in which the dilution of the P₃ units, introduced in the first high-pressure phase, decreases, leading to compositions of Ni₂₀(P₃)₄(P₂)₄ and Ni₁₂(P₃)₄, and provide important clues to understanding of phase relations and transformation pathways in the NiAs family.     

Tectonic and magmatic evolution of the eastern Karakoram,India

Abstract

The Shyok suture zone separates the Ladakh terrane to the SW from the Karakoram terrane to the NE. Six tectonic units have been distinguished. From south to north these are; 1. Saltoro formation; 2. Shyok volcanites; 3. Saltoro molasse; 4. Ophiolitic melange; 5. Tirit granitoids; 6. Karakoram terrane including the Karakoram batholith. Albian—Aptian Orbitolina-bearing lime-stones and turbidites of the Saltoro formation tectonically overlie high-Mg-tholeiites similar to the tectonically overlying Shyok volcanites. The high-Mg tholeiitic basalts and calcalkaline andesites of the Shyok volcanites show an active margin signature. The Saltoro molasse is an apron-like, moderately folded association of redgreen shales and sandstones that are interbedded with ~ 50 m porphyritic andesite. Desiccation cracks and rain-drop imprints indicate deposition in a subaerial fluvial environment. Rudist fragments from a polygenic conglomerate of the Saltoro molasse document a post-Middle Cretaceous age. The calcalkaline andesites of the Shyok volcanites are intruded by the Tirit granitoids, which are located immediately south of the Ophiolitic melange and belong to a weakly deformed trondhjemite-tonalite-granodiorite-granite suite. These granitoids are subalkaline, I-type and were emplaced in a volcanic arc setting. The subalkaline to calcalkaline granitoids of the Karakoram batholith are I-and S-type granitoid. The I-type granitoids represent a typical calcalkaline magmatism of a subduction zone environment whereas the S-type granitoids are crustderived, anatectic peraluminous granites. New data suggest that the volcano-plutonic and sedimentary successions of the Shyok suture zone exposed in northern Ladakh are equivalent to the successions exposed along the Northern suture in Kohistan. It is likely that the o istan and Ladakh blocks evolved as one single tectonic domain uring the Cretaceous-Palaeogene. Subsequently, collision, suturing and accretion of the Indian plate along the Indus suture (50–60 Ma) together with tectonic activity along the Nanga Parbataramosh divided Kohistan and Ladakh into two arealy distinct magmatic arc terranes. The activity and a dextral offset along the Karakoram fault (Holocene-Recent) disrupted the original tectonic relationships. © 1999 Éditions scientifiques et médicales Elsevier SAS     

Differential behaviour of a Lesser Himalayan watershed in extreme rainfall regimes

Climatic extremes including precipitation are bound to intensify in the global warming environment. The present study intends to understand the response of the Tons sub-watershed in Lesser Himalaya, in 3 years with entirely different hydrological conditions (July 2008–June 2011) in terms of discharge, sediment flux and denudation rates. Within an uncertainty limit of ±20%, the mean interannual discharge (5.74 ± 1.44 m ³ s ^?1) (±SE), was found highly variable (CV: 151%; 0.8–38 m ³ s ^?1). In a normal rainfall year (2008–2009; ～1550 mm), the discharge was 5.12 ± 1.75 m ³ s ^?1, whereas in a drought year (2009–2010), it reduced by 30% with the reduction in ～23% rainfall (CV: 85%). In an excessive rainfall year (once-in-a-century event) (2010–2011; ～3050 mm), discharge as well as total solid load was ～200% higher. Monsoon months (July–September) accounted for more than 90% of the annual solid load transport. The ratio of dissolved to suspended solid (C/P ratio) was consistently low (<1) during monsoon months and higher (1–7) during the rest of the dry period. C/P ratio was inversely (R ²=0.49), but significantly (P <0.001) related to the rainfall. The average mechanical erosion rate in the three different rainfall years was 0.24, 0.19 and 1.03 mmyr ^?1, whereas the chemical erosion was estimated at 0.12, 0.11 and 0.46 mmyr ^?1, respectively. Thus, the average denudation rate of the Tons sub-watershed has been estimated at 0.33 mmyr ^?1 (excluding extreme rainfall year: 1.5 mmyr ^?1). Our results have implications to understand the hydrological behaviour of the Lesser Himalayan watersheds and will be valuable for the proposed and several upcoming small hydropower plants in the region in the context of regional ecology and natural resource management.     

Visible-Near Infrared Reflectance Spectroscopy for Rapid Characterization of Salt-Affected Soil in the Indo-Gangetic Plains of Haryana,India

Management of salt-affected soils is a challenging task in the input intensive rice-wheat cropping zone of the Indo-Gangetic plains (IGP). Timely detection of salt-affected areas and assessment of the degree of severity are vital in order to narrow down the potential gap in yield. Conventional laboratory techniques of saturation extract electrical conductivity (EC_e) and sodium adsorption ration (SAR) for soil salinity assessment are time-consuming and labour intensive; the VNIR (visible-near infrared) reflectance spectroscopy technique provides ample information on salinity and its attributes in an efficient and cost-effective way. This study aims to develop robust soil reflectance spectral models for rapid assessment of soil salinity in the salt affected areas of the IGP region of Haryana using VNIR reflectance spectroscopy. The results indicated that the spectral region between 1390 and 2400 nm was highly sensitive to measure changes in salinity. The developed hyperspectral models explained more than 80 % variability in EC_e, and other salinity related attributes (saturated extract Na⁺, Ca²⁺ + Mg²⁺, Cl^? and SAR) in the validation datasets. With the increasing availability of data from hyperspectral sensors in near future, the study will be very useful in real time monitoring of soils in the spatio-temporal context; enabling the farmers of IGP area to deal with salt degradation more effectively and efficiently.     

Estimating apparent thermal diffusivity of soil using field temperature time series

Reliable estimates of soil thermal properties such as heat capacity, thermal conductivity, and diffusivity are important in analysis of heat transmission through soils in applications such as shallow geothermal applications, buried electrical conduits, and in general heat/fluid flow analyses. A number of analytical, numerical and experimental methods are available to determine the soil thermal properties. In this paper, the analytical and numerical methods developed on the basis of one-dimensional heat conduction equation are used to estimate the apparent thermal diffusivity of soil. Three of the four analytical methods, Amplitude, Phase, and Arctangent provide explicit equations for the apparent thermal diffusivity. Two methods, Harmonic and Numerical, make use of large number of temperature measurements to implicitly solve for the apparent thermal diffusivity. The temperature time series data monitored at different depths in two field sites in Melbourne, Australia for more than 2 year period were used to estimate the apparent thermal diffusivity of soil down to 2 m depth. The apparent thermal diffusivity was calculated using all five methods and compared with laboratory experimental results. The effectiveness of each method in predicting the thermal diffusivity was compared and observed discrepancies were discussed. Finally, the observed soil temperature data for a 12 month period are used to model the temperature variation in the ground analytically using Harmonic method and the model prediction for the following 12 month was compared independently with the field measurements. The analytical model prediction is found to be in good agreement with the field monitored data.     

Assessing the utility of 210Pb geochronology for estimating sediment accumulation rates on river floodplains in Fiji

Low‐energy gamma ray spectroscopy has been employed to estimate floodplain sedimentation rates using measurements of ²¹⁰Pb in floodplain alluvium. The utility of the technique is assessed through the analysis of excess (unsupported) ²¹⁰Pb profiles in three sediment cores taken from the floodplain of the Labasa River on Vanua Levu in northern Fiji. A low‐energy germanium spectrometer (LEGe) was used for the nondestructive determination of excess ²¹⁰Pb in a region cultivated intensively with sugarcane. Measured average historical (c. 25 years) vertical accretion rates are between 2.2 and 4.4 cm yr^?1. The findings are broadly comparable with published sedimentation rates from analyses of radionuclide profiles elsewhere in the tropical South Pacific Islands, but the rates are higher than those measured previously at the same Labasa River sites using ¹³⁷Cs profiles. Accelerated soil erosion owing to cane burning and land tillage seems to be largely responsible for sediment production, although flood‐related effects such as channel accretion by coarse bedload and the emplacement of large organic debris also influence floodplain sedimentation. However, application of the ²¹⁰Pb technique in Fiji (and perhaps neighbouring island countries) is found to have serious drawbacks compared to the more robust ¹³⁷Cs method, owing principally to the low ²¹⁰Pb concentrations in the sandy alluvial sediment tested.     

Numerical analysis of an experimental pipe buried in swelling soil

This paper investigates the pipe–soil interaction for pipes buried in expansive soil when subjected to swelling soil movement due to increase in moisture content. A laboratory experiment has been undertaken on a plastic pipe in a large-scale pipe box. A three dimensional numerical model is developed to analyse the pipe response, using FLAC^3D computer program. The pipe is assumed to behave as a linearly elastic material, while the soil is modelled as a nonlinear material with Mohr–Coulomb failure criterion. The water flow and soil/pipe deformations are decoupled, where water flow is calculated using simplified capillary rise theory on the basis of measurements made. A reasonably good agreement between the experimental results and model predictions is reported.     

Bianchi type-I cosmological models with time dependent q and Λ-term in general relativity

On getting motivation from increasing evidence for the need of a geometry that resembles Bianchi morphology to explain the observed anisotropy in the WMAP data, Einstein’s field equations with variable cosmological “constant” are considered in presence of perfect fluid for a homogeneous and anisotropic Bianchi type-I space-time. Einstein’s field equations are solved by considering a time dependent deceleration parameter which affords a late time acceleration in the universe. The cosmological constant Λ is found to be a decreasing function of time and it approaches a small positive value at the present epoch which is corroborated by consequences from recent supernovae Ia observations. From recently developed Statefinder pair, the behavior of different stages of the evolution of the universe has been studied. The physical significance of the cosmological models have also been discussed.