Immobilization of toxic elements in mine residues derived from mining activities in the Iberian Pyrite Belt (SW Spain): Laboratory experiments

In the mining environments of the Iberian Pyrite Belt (IPB), the oxidation of sulphide wastes generates acid drainage with high concentrations of SO₄, metals and metalloids (Acid Mine Drainage, AMD). These acid and extremely contaminated discharges are drained by the fluvial courses of the Huelva province (SW Spain) which deliver high concentrations of potentially toxic elements into the Gulf of Cádiz. In this work, the oxidation process of mine tailings in the IPB, the generation of AMD and the potential use of coal combustion fly ash as a possible alkaline treatment for neutralization of and metal removal from AMD, was studied in non-saturated column experiments. The laboratory column tests were conducted on a mine residue (71.6 wt% pyrite) with artificial rainfall or irrigation. A non-saturated column filled solely with the pyrite residue leached solutions with an acid pH (approx. 2) and high concentrations of SO₄ and metals. These leachates have the same composition as typical AMD, and the oxidation process can be compared with the natural oxidation of mine tailings in the IPB. However, the application of fly ash to the same amount of mine residue in another two non-saturated columns significantly increased the pH and decreased the SO₄ and metal concentrations in the leaching solutions. The improvement in the quality of leachates by fly ash addition in the laboratory was so effective that the leachate reached the pre-potability requirements of water for human consumption under EU regulations. The extrapolation of these experiments to the field is a promising solution for the decontamination of the fluvial courses of the IPB, and therefore, the decrease of pollutant loads discharging to the Gulf of Cádiz.     

Assessment of phosphogypsum impact on the salt-marshes of the Tinto river (SW Spain): role of natural attenuation processes

About 120 Mton of phosphogypsum from the fertiliser industry were stack-piled on the salt-marshes of the Tinto river (Spain). This paper investigates the capacity of salt-marshes to attenuate contamination due to downward leaching from phosphogypsum. Solids and pore-waters were characterized at different depths of the pile to reach the marsh-ground. In superficial zones, metals were highly mobile, and no reduced sulphur was found. However, pollutant concentration decreased in the pore-water in deeper oxygen-restricted zones. Metal removal occurred by precipitation of newly formed sulphides, being this process main responsible for the contamination attenuation. Pyrite-S was the main sulphide component (up to 2528 mg/kg) and occurred as framboids, leading to high degrees of pyritization (up to 97%). The sulphidization reaction is Fe-limited; however, excess of acid-volatile sulphide over other metals cause precipitation of other sulphides, mainly of Cu and As. This decrease in metal mobility significantly minimises the impact of phosphogypsums on the salt-marshes.     

Human impacts on Laguna de Bay, Philippines and management strategies for their mitigation

Laguna de Bay is the largest lake in the Philippines bordering metropolitan Manila, the nation's capital and the industrial hub of the country. As a multiple-use resource the lake is of prime importance for its fisheries, as a transport route and as a water source for the cooling of industrial plants and for irrigation. The lake is also envisaged to supply the domestic water needs of the basin in the year 2000. With rapid urbanization, industrial development and deforestation of its watershed, Laguna de Bay has been stressed with sedimentation, overexploitation of its fisheries and pollution. Various management strategies have been adopted by government to address such human impacts. Among the major programs are the installation of a hydraulic control structure, implementation of a zoning and management plan and the formulation of a master plan. There is need for an integrated approach for the management of the Laguna de Bay basin for its sustainable development.     

Temporal variability of disturbances: is this important for diversity and structure of marine fouling assemblages?

Natural communities are constantly changing due to a variety of interacting external processes and the temporal occurrence and intensity of these processes can have important implications for the diversity and structure of marine sessile assemblages. In this study, we investigated the effects of temporal variation in a disturbance regime, as well as the specific timing of events within different regimes, on the composition and diversity of marine subtidal fouling assemblages. We did this in a multi‐factorial experiment using artificial settlement tiles deployed at two sites on the North East coast of England. We found that although there were significant effects of disturbances on the composition of assemblages, there were no effects of either the variation in the disturbance regime or the specific timing of events on the diversity or assemblage composition at either site. In contrast to recent implications we conclude that in marine fouling assemblages, the variability in disturbance regimes (as a driving force) is unimportant, while disturbance itself is an important force for structuring robust ecosystems.     

Population genetics and evolutionary demography of Ucides cordatus (Decapoda: Ocypodidae)

Variation in a fragment of the mitochondrial control region was investigated to assess the population history of the mangrove land crab, Ucides cordatus L., based on 100 individuals from five locations throughout the Brazilian coast. There was considerable variability in the studied fragment, with every individual showing a distinct haplotype. When regions of ambiguous alignment were removed, 90 haplotypes were still recognized, of which only 1 was shared among locations. There was no statistically significant evidence for geographical structure in the pattern of genetic variability based on a nested clade analysis, even though the geographical distances among the farthest collection sites exceeded 3000 km. Moreover, the mismatch distribution of pairwise differences showed a smooth unimodal distribution that is consistent with a recent population expansion of U. cordatus, either when each location was analysed in isolation or when all samples were combined. Interestingly, the estimates for the duration of such expansion vary latitudinally, suggesting that the expansion of the population of U. cordatus proceeded in a southward direction. These results indicate a possible relationship between the growth in the population of the mangrove land crab and the dynamics of mangrove ecosystems during the Quaternary.     

Polychaete Communities Related to Plant Covering in the Médiolittoral and Infralittoral Zones of the Balearic Islands (Western Méditerranean)

Abstract. The polychaete fauna of the subtidal in the médiolittoral and the infralittoral hard bottom zones of the Balearic Islands at depths from 0 to 40m contained 220 species. Five different polychaete communities could be identified by changes in abundance, species richness, species composition, diversity, and trophic structure. In the very clear waters of these islands the infralittoral zone extends to a depth of 40 m and allows us to investigate whether former proposed models of polychaete distribution can be extended to this particular situation.     

Soil liquefaction potential induced by the andalusian earthquake of 25 December 1884

On 25 December 1884, an earthquake of epicentral intensityI ₀ = IX in the MSK scale caused great damage in a large area in the provinces of Granada and Málaga, in the south of Spain. The reports of the Spanish, Italian and French Commissions that studied the earthquake described ground phenomena in seven different sites which can be identified as soil liquefaction.By means of dynamic penetration tests carried out in the above sites, the corresponding soil profiles (based on SPT data and water table depth) were established, and the occurrence of liquefaction was proved in five out of seven of these sites. Also, the intensities at such locations and the magnitude of the earthquake were estimated.From the geotechnical data and the cyclic stress ratio induced by the earthquake, liquefaction conditions were confirmed in all the five sites which presumably liquefied. Then, possible values of the minimum ground surface accelerations necessary for the onset of liquefaction at each location were calculated. The results obtained were completed with data reported in six liquefaction case studies from Japan and the United States, from which design charts relating soil acceleration with normalized SPT values for different intensity levels were drawn.Finally, by using standard attenuation curves, the above data were translated into epicentral distances, and good agreement with the known epicentral area was found. As a result, a consistent approach for liquefaction hazard and source location problems has been developed. The proposed method combines in its formulation historical evidence and earthquake engineering techniques.     

An Interdisciplinary Methodology for the Characterization and Visualization of the Heritage of Roadway Corridors

Roads, particularly since the advent of motorized traffic, have hugely impacted contemporary landscapes. Although their significance was noted in the 1980s, specific roadway‐heritage studies are scarce. Research in different disciplines has identified certain features of roads, but an integrated approach to roadway heritage or a consensus on what this constitutes are lacking. This article proposes an interdisciplinary methodology to assess roadway heritage. Roadways are interpreted within the framework of semantic openness that currently characterizes heritage studies, territory being the basic element of interpretation. Rather than a fragmented approach to conservation, the research defines integrated heritage configurations where natural, cultural, and historical features combine to produce a cohesive form of heritage. GIS (Geographical information systems) technology is used with an online database to assess the complexity of roadway heritage. ICT (Information and communications technology) strategies to raise public awareness are outlined. The methodology is applied to assess the historical N‐340 Mediterranean roadway corridor in Spain.