Assessment of phosphogypsum impact on the salt-marshes of the Tinto river (SW Spain): role of natural attenuation processes

About 120 Mton of phosphogypsum from the fertiliser industry were stack-piled on the salt-marshes of the Tinto river (Spain). This paper investigates the capacity of salt-marshes to attenuate contamination due to downward leaching from phosphogypsum. Solids and pore-waters were characterized at different depths of the pile to reach the marsh-ground. In superficial zones, metals were highly mobile, and no reduced sulphur was found. However, pollutant concentration decreased in the pore-water in deeper oxygen-restricted zones. Metal removal occurred by precipitation of newly formed sulphides, being this process main responsible for the contamination attenuation. Pyrite-S was the main sulphide component (up to 2528 mg/kg) and occurred as framboids, leading to high degrees of pyritization (up to 97%). The sulphidization reaction is Fe-limited; however, excess of acid-volatile sulphide over other metals cause precipitation of other sulphides, mainly of Cu and As. This decrease in metal mobility significantly minimises the impact of phosphogypsums on the salt-marshes.     

Multidisciplinary approach of the hyperarid desert of Pampas de La Joya in southern Peru as a new Mars-like soil analog

The distribution of living organisms, organic matter, and chemical properties in Mars-like environments on Earth can be used as a model to guide the investigation of possible habitable environments on Mars. This work aims to demonstrate that the place known informally as the “Mar de Cuarzo” (Sea of Quartz) in the Pampas de La Joya desert southern Peru (between 16°S and 17°S latitude), contains soils with characteristics similar to those found on the Martian surface. Using a multidisciplinary approach, we studied the environmental data, geology, organic matter content, oxidant activity, and microbiology of this area. Our data show that (1) Mar de Cuarzo is a hyper arid area with a lower concentration of organic matter than those found in the Mars-like soils from Yungay area (Atacama Desert in Chile), while at the same time having, comparable extreme environmental conditions, and very low levels of microorganisms. (2) The detrital components of the soils come essentially from the Andean volcanic chain and local outcrops of Precambrian gneisses and Cretaceous granitic batholiths. (3) The presence of microclimates, geomorphological features, and the high influence of the “El Niño Southern Oscillation (ENSO)” allowed the formation of exotic and heterogeneous chemical deposits in these soils, including iron oxides, sulfates, and other evaporites. (4) Thermal volatilization in these soils (using methods similar to the Viking and Phoenix instruments) shows high oxidant activity. (5) Labeled release experiment (similar to the Viking instrument) shows high degradation of nutrients added in these soils.Altogether, the Mar de Cuarzo area in the Pampas de La Joya is an interesting place for astrobiological studies as a new analog to Mars, and for comparative analyses with other hyperarid analogs as Yungay.     

Basis for a streamflow forecasting system to Rincón del Bonete and Salto Grande (Uruguay)

This paper presents the basis for the design of streamflow prediction systems for the hydroelectric dams of Rincón del Bonete (Uruguay) and Salto Grande (Uruguay–Argentina). The prediction is made, independently, for each reservoir and each month of the year with two methodologies: data-driven statistical models and hybrid downscaling that includes atmospheric predictors. We determine a set of potential predictors and then fit linear models coupled with variable selection techniques, under the hypothesis of perfectly known predictors. The predictive skill of the schemes outperforms the climatological forecast throughout the year in both reservoirs (except August in Rincón del Bonete). This remains the case even when the forecast lead does not allow for the use of preceding flows as predictors. While in Rincón del Bonete it is not possible to distinguish a period of high predictability, in Salto Grande, there is a robust signal in March–May and October–December.     

On the motion of three rigid bodies: Central configurations

In the present paper, the motion of three rigid bodies is considered. With a set of new variables, and the 10 first integrals of the motion, the problem is reduced to a system of order 25 and one quadrature. The plane motions are characterized, and finally, an equation for the existence of central configurations (in particular, Lagrangian and Eulerian solutions) has been found. Besides, the case of three axisymmetric ellipsoids is studied.     

Challenges at the early stages of the environmental licensing procedure and potential contributions from geomorphology

Defining impact significance is the main technical task that influences decision-making during the Environmental Licensing Procedure(ELP).The ELP begins with screening to determine potentially signif-icant impacts of the proposed project.Scoping then follows to address any interventions deemed worthy of attention in the production of an Environmental Impact Assessment(EIA).This will include consider-ation of relevant landforms and geomorphological processes.However,preliminary assessments of envi-ronmental impacts often lack the scientific robustness to procure substantive and transactive effectiveness.This review presents an examination of the established practices of screening and scoping while highlighting the foremost challenges to improve the technical grounds of the ELP.The analysis of screening and scoping practices stresses the need for novel methods that ensure the sequential reasoning between their criteria while improving the preliminary evaluation of impact significance.Reducing the inherent subjectivity of discretionary judgment requires scientific methodologies that acknowledge the interaction between the natural system and human interventions,which has been addressed by geomor-phological research.The knowledge consolidated in this review opens the gate to explore the compatibil-ity between the United Nations strategy of Ecosystem Approach(EA)with the ELP through a novel geomorphological interpretation of the EIA.Therefore,this diagnosis demonstrate that screening and scoping practices would benefit from reliable methods that balance the precautionary principle with the efficient character required in the ELP.     

The thermal springs of Jordan

The thermal springs alongside Wadi Araba, Dead Sea and Jordan valley, Jordan, were investigated and sampled in a comprehensive field study of 2 weeks. Conventional physicochemical properties were measured in situ; dissolved solids and isotopic composition were analyzed. Two main spring locations on the east side of the Dead Sea were mapped. It became evident, that the hottest springs are among the closest to prominent faults; some springs are controlled by gas lift. Jordan’s hot springs are described by means of a broad hydrochemical and physicochemical data set and several figures are presented. Based on their hydrochemistry, the thermal springs are classified into four thermal provinces. Water genesis is discussed. Several geothermometers are applied to estimate reservoir temperatures. Observed discharge rate, water temperature and isotopic composition are compared with data from the literature. Although discharge and water temperature are reported to be constant over the last decades, groundwater overexploitation led to a shift of the isotopic composition, what is documented for the first time in Jordan. Thus, the effect of groundwater mining on Jordan’s hot springs can be stated as a fact.     

Analysis and interpretation of the seismic response of RC buildings in Concepción during the February 27, 2010, Chile earthquake

Observed trends in the seismic performance of eight severely damaged reinforced concrete (RC) structures after the February 27, 2010, Chile earthquake are presented in this article. After a reconnaissance and surveying process conducted immediately after the earthquake, several aspects not conventionally considered in building design were observed in the field. Most of the considered structures showed extensive localized damage in walls of lower stories and first basements. Several factors indicate that damage was brittle, and occurred mainly in recent RC structures supported on soft soils with some degree of vertical and/or horizontal irregularity. Non-ductile behavior has been inferred due to the lack of evidence of spread damage in the structure, and the fact that very similar structural configurations existed nearby without apparent damage. Some key aspects in understanding the observed damage are: geographical orientation of the building, presence of vertical and horizontal irregularities, wall thickness and reinforcement detailing, and lack of sources for energy dissipation. Additionally, results of a building-code type analysis are presented for the 4 most critical buildings, and Demand/Capacity ratios are calculated and compared with the observed behavior. It is concluded that the design codes must be revised relative to wall design provisions.     

The Arosa zone in Eastern Switzerland: oceanic, sedimentary burial, accretional and orogenic very low- to low grade patterns in a tectono-metamorphic mélange

In the area of Arosa?CDavos?CKlosters (Eastern Switzerland) the different tectonic elements of the Arosa zone mélange e.g. the Austroalpine fragments, the sedimentary cover of South Penninic ophiolite fragments, as well as the matrix (oceanic sediments and flysch rocks) show distinctively different metamorphic histories and also different climaxes (??peaks??) of Alpine metamorphism. This is shown by a wealth of Kübler-Index, vitrinite and bituminite reflectance measurements, and K-white mica b cell dimension data. At least six main metamorphic events can be recognized in the area of Arosa?CDavos?CKlosters: (1) A pre-orogenic event, typical for the Upper Austroalpine and for instance found in the sediments at the base of the Silvretta nappe but also in some tectonic fragments of the Arosa zone (Arosa zone mélange). (2) An epizonal oceanic metamorphism observed in the close vicinity of oceanic basement rocks units of the Arosa zone (South Penninic) is another pre-orogenic process. (3) A metamorphic overprint of the adjacent Lower Austroalpine nappes and structural fragments of the Lower Austroalpine in the Arosa zone. This metamorphic overprint is attributed to the orogenic metamorphic processes during the Late Cretaceous. (4) A thermal climax observed in the South Penninic sediments of the Arosa zone can be bracketed by the Austroalpine Late Cretaceous event (3) and the middle Tertiary event (5) in the Middle Penninic units and predates Oligocene extension of the ??Turba phase??. (6) North of Klosters, in the northern part of our study area, the entire tectonic pile from the North Penninic flysches to the Upper Austroalpine is strongly influenced by a late Tertiary high-grade diagenetic to low-anchizone event. In the Arosa zone mélange an individual orogenic metamorphic event is evidenced and gives a chance to resolve diagenetic?Cmetamorphic relations versus deformation. Six heating episodes in sedimentary rocks and seven deformation cycles can be distinguished. This is well explained by the propagation of the Alpine deformation front onto the foreland units. Flysches at the hanging wall of the mélange zone in the north of the study area (Walsertal zone) show data typical for low-grade diagenetic thermal conditions and are therefore sandwiched between higher metamorphic rock units and separated from theses units by a disconformity. The Arosa zone s.s., as defined in this paper, is characterised by metamorphic inversions in the hanging wall and at the footwall thrust, thus shows differences to the Walsertal zone in the north and to the Platta nappe in the south.