Use of sequential extraction procedure for assessing the environmental impact at regional scale of the São Domingos Mine (Iberian Pyrite Belt)

São Domingos is one of the most emblematic Portuguese mining districts in the Iberian Pyrite Belt (IPB). The beginning of mining exploitation in the area has been dated back to pre-Roman times, remaining in activity until 1966 when it was definitely halted. The intense mining labours are reflected in the presence of a huge amount of sulphide-mining wastes and downstream production of acid mine drainage (AMD). The mining wastes in the area are highly heterogeneous, and numerous different types may be recognized, including slags, iron oxides, smelting ashes, brittle and blocks of pyrite, leaching tank refuses, industrial landfill and other residues coming from ore extraction (gossan wastes and country rocks). The chemical speciation of potentially toxic elements (As, Cd, Cr, Cu, Fe, Mn, Pb, S, Sb and Zn) in all mine wastes from São Domingos was determined by modified BCR-sequential extraction procedure (European Community Bureau of Reference) and combined with the mass/volume proportions of each waste to quantify the potential risk of this mining district at regional scale. Analytical recoveries by sequential extraction, with respect to a pseudo-total metal content digestion, were generally acceptable (100 ± 17%). The oxidizable fraction corresponds with metals bound to sulphides and released easily under oxidizing conditions in AMD production processes. This is the most polluting fraction for the environment in this type of residues. Part of this fraction is retained by precipitation of soluble secondary minerals in warm periods, moving to the bio-available fraction that is dissolved in rainy periods. Just considering the bio-available fraction, all mine wastes from São Domingos may leach up to 172514 ton of Fe, 10564 ton of S, 6644 ton of Pb, 2610 ton of Zn, 1126 ton of Mn, 1032 ton of Cu, 183 ton of Cr, 109 ton of As, 34 ton of Sb and 0.9 ton of Cd. The process of precipitation and re-dissolution of efflorescent salts formed directly by oxidation of the oxidizable fraction is seasonally repeated, which causes an annual self-feeding and releasing of the bio-available fraction. Thus, the present study shows the pollutant potential of this IPB mining district and explains the spoiled state of the fluvial courses in the region.     

Kinematic constraints between stellar systems in superposition

Some kinematic consequences of a superposition of two stellar systems are studied. Chandrasekhar's axially-symmetric model has been adopted for each one of the subsystems. The solution of Chandrasekhar's equations provides us with a potential function, which must be shared by both stellar subsystems and, thus, some relationships between the kinematic parameters of both, subsystems are obtained. In the case of a stationary potential function the whole set of second-order centred moments may be explained.Gotta serve somebody... (Bob Dylan) may be U may be ₂.Paper presented at the 11th European Regional Astronomical Meetings of the IAU on New Windows to the Universe, held 3–8 July, 1989, Tenerife, Canary Islands, Spain.     

Numerical modelling of surfacewater/groundwater flows for freshwater/saltwater hydrology: the case of the alluvial coastal aquifer of the Low Guadalhorce River, Malaga, Spain

This applied research deals with the numerical modelling and transient simulation of the joint surfacewater/groundwater flows that characterize the freshwater/saltwater hydrology of the coastal alluvial valley of the Low Guadalhorce River, Malaga, Spain. The MELEF model used was mainly adapted and calibrated for a simulation period of two hydrological years 1989/1990–1990/1991, before the current channelling of the river, where floods and low precipitations have been recorded. The model calibration process was performed with the aid of phreatic levels measured in numerous wells and piezometers, as well as recharges from precipitation and irrigation on the alluvial surface, which was also assessed by the hydrologic model SSMA-2. The present numerical approach can predict the forthcoming hydrology of the coastal alluvial of the Guadalhorce River after its final channelling.     

Patterns of halite (NaCl) crystallisation in building stone conditioned by laboratory heating regimes

The crystallisation of soluble salts within the pores of the stone is widely recognised as a major mechanism causing the deterioration of the stone-built architectural heritage. Temperature, in turn, is one of the main controls on this process, including salt precipitation, the pressure of crystallisation and the thermal expansion of salts. Most laboratory experiments on decay generated by salts are just carried out with convective heating regimes, while in natural environments building stones can undergo radiative and convective heating regimes. The thermal response of stone to these different heating regimes is noticeably different and might influence the crystallisation patterns of a salt within a stone. The aim of this work is to raise awareness on the different patterns of crystallisation of NaCl within a porous stone tested with different heating regimes (convection and radiation) and the implications that this could have on the design of experimental modelling of natural weathering conditions in laboratory simulations. Results show that heating regime affects the sodium chloride distribution within a stone with high percentage of microporosity. In this case, radiation heating facilitates the generation of subefflorescences, while convection heating promotes efflorescences. This has a clear implication both on the stone decay in natural environments and on the methodologies for testing salt decay, as subefflorescences are more destructive than efflorescences. In this sense, the use of convective heating in laboratory experimentation might underestimate the potential damage that sodium chloride may generate. This counsels the use of radiation heating test methods in addition to convection for the laboratory study of salt crystallisation.     

Scenarios in tropical forest degradation: carbon stock trajectories for REDD+

Background

Human-caused disturbance to tropical rainforests—such as logging and fire—causes substantial losses of carbon stocks. This is a critical issue to be addressed in the context of policy discussions to implement REDD+. This work reviews current scientific knowledge about the temporal dynamics of degradation-induced carbon emissions to describe common patterns of emissions from logging and fire across tropical forest regions. Using best available information, we: (i) develop short-term emissions factors (per area) for logging and fire degradation scenarios in tropical forests; and (ii) describe the temporal pattern of degradation emissions and recovery trajectory post logging and fire disturbance.

Results

Average emissions from aboveground biomass were 19.9 MgC/ha for logging and 46.0 MgC/ha for fire disturbance, with an average period of study of 3.22 and 2.15 years post-disturbance, respectively. Longer-term studies of post-logging forest recovery suggest that biomass accumulates to pre-disturbance levels within a few decades. Very few studies exist on longer-term (>10 years) effects of fire disturbance in tropical rainforests, and recovery patterns over time are unknown.

Conclusions

This review will aid in understanding whether degradation emissions are a substantial component of country-level emissions portfolios, or whether these emissions would be offset by forest recovery and regeneration.

     

Simplification bias: lessons from laboratory and field experiments on flow through aquatic vegetation

We present a critical analysis of experimental findings on vegetation–flow–sediment interactions obtained through both laboratory and field experiments on tidal and coastal environments. It is well established that aquatic vegetation provides a wide range of ecosystem services (e.g. protecting coastal communities from extreme events, reducing riverbank and coastal erosion, housing diverse ecosystems), and the effort to better understand such services has led to multiple approaches to reproduce the relevant physical processes through detailed laboratory experiments. State-of-the-art measurement techniques allow researchers to measure velocity fields and sediment transport with high spatial and temporal resolution under well-controlled flow conditions, yielding predictions for hydrodynamic and sediment transport scenarios that depend on simplified or bulk vegetation parameters. However, recent field studies have shown that some simplifications on the experimental setup (e.g. the use of rigid elements, a single diameter, a single element height, regular or staggered layout) can bias the outcome of the study, by either hiding or amplifying some of the relevant physical processes found in natural conditions. We discuss some observed cases of bias, including general practices that can lead to compromises associated with simplified assumptions. The analysis presented will identify potential pathways to move forward with laboratory and field measurements, which could better inform predictors to produce more robust, universal and accurate predictions on flow–vegetation–sediment interactions. © 2020 John Wiley & Sons, Ltd.     

Model sensitivity experiments on data assimilation,downscaling and tides for the representation of the Cape São Tomé Eddies

Ocean Dynamics - The impacts of data assimilation, downscaling, and tidal forcing were investigated with focus on the representation of the Cape São Tomé Eddy (CSTE). Sea level anomaly...