Mixing and differentiation in the Oruanui rhyolitic magma, Taupo, New Zealand: evidence from volatiles and trace elements in melt inclusions

Large pyroclastic rhyolites are snapshots of evolving magma bodies, and preserved in their eruptive pyroclasts is a record of evolution up to the time of eruption. Here we focus on the conditions and processes in the Oruanui magma that erupted at 26.5 ka from Taupo Volcano, New Zealand. The 530 km³ (void-free) of material erupted in the Oruanui event is comparable in size to the Bishop Tuff in California, but differs in that rhyolitic pumice and glass compositions, although variable, did not change systematically with eruption order. We measured the concentrations of H₂O, CO₂ and major and trace elements in zoned phenocrysts and melt inclusions from individual pumice clasts covering the range from early to late erupted units. We also used cathodoluminescence imaging to infer growth histories of quartz phenocrysts. For quartz-hosted inclusions, we studied both fully enclosed melt inclusions and reentrants (connecting to host melt through a small opening). The textures and compositions of inclusions and phenocrysts reflect complex pre-eruptive processes of incomplete assimilation/partial melting, crystallization differentiation, magma mixing and gas saturation. ‘Restitic’ quartz occurs in seven of eight pumice clasts studied. Variations in dissolved H₂O and CO₂ in quartz-hosted melt inclusions reflect gas saturation in the Oruanui magma and crystallization depths of ∼3.5–7 km. Based on variations of dissolved H₂O and CO₂ in reentrants, the amount of exsolved gas at the beginning of eruption increased with depth, corresponding to decreasing density with depth. Pre-eruptive mixing of magma with varying gas content implies variations in magma bulk density that would have driven convective mixing. Electronic Supplementary Material Supplementary material is available for this article at and is accessible for authorized users.     

A safer city centre for all? Senses of `community safety' in Newcastle upon Tyne

In recent years, many city authorities in Europe and North America have sought to attract people back to city centres for leisure, shopping, business and residence. The planning measures commonly adopted take explicit account of issues of crime and safety. The concept of `community safety' as applied to the city centre is problematic, however, as users have diverse lifestyles, interests and values which impact on their own and others' safety. This paper reports on a study of the experiences and perceptions of safety of different groups of city centre users in Newcastle upon Tyne, England. While social identities and roles shaped the extent of concern and subsequent impacts on people's use of the city centre space, the research suggested that many concerns are genuinely shared. The paper investigates the congruence of a range of planning strategies with city centre users' safety concerns. Situational measures were viewed with scepticism, as fear centres on the presence and behaviour of others.     

G-Probe-1 - An International Proficiency Test for Microprobe Laboratories - Report on Round 1 : February 2002 (TB-1 Basaltic Glass)

Results are presented for round one of a new international proficiency testing programme designed for microprobe laboratories involved in the routine analysis of silicate minerals. The sample used for this round was TB-1, a basaltic glass fused and prepared by the USGS. Thirty nine laboratories contributed data to this round, the majority of major element results being undertaken by EPMA and the majority of trace elements by LA-ICP-MS. Assigned values were derived from the median of results produced by nine selected laboratories that analysed powdered material by conventional ICP-MS, INAA and XRF techniques using bulk powders of the sample. Submitted microprobe results were evaluated using a target precision calculated using the Horwitz function, adopting the same criteria as those used for "applied" geochemistry laboratories in the companion GeoPT proficiency testing programme for laboratories involved in the routine bulk analysis of silicate rocks. An evaluation of results from participating microprobe laboratories indicated that overall, data were compatible with this precision function. A comparison between the performance of bulk and microprobe techniques used in the analysis of the basaltic glass showed remarkably good agreement, with significant bias only observed for the major oxide MgO.     

Iterative resolution estimation in least‐squares Kirchhoff migration

We apply iterative resolution estimation to least‐squares Kirchhoff migration. Reviewing the theory of iterative optimization uncovers the common origin of different optimization methods. This allows us to reformulate the pseudo‐inverse, model resolution and data resolution operators in terms of effective iterative estimates. When applied to Kirchhoff migration, plots of the diagonal of the model resolution matrix reveal low illumination areas on seismic images and provide information about image uncertainties. Synthetic and real data examples illustrate the proposed technique and confirm the theoretical expectations.     

The last British Ice Sheet: growth, maximum extent and deglaciation

The growth, maximum lateral extent and deglaciation of the last British Ice Sheet (BIS) has been reconstructed using sediment, faunal and stable isotope methods from a sedimentary record recovered from the Barra Fan, north-west Scotland. During a phase of ice sheet expansion postdating the early "warmth" of Marine Isotope Stage 3 (MIS 3), ice rafting events, operating with a cyclicity of approximately 1500 years, are interspersed between warm, carbonate-rich interstadials operating with a strong Dansgaard-Oeschger (D-O) cyclicity. The data suggest that the BIS expanded westwards to the outer continental shelf break shortly after 30 Ky BP (before present) and remained there until about 15 Ky BP. Within MIS 2, as the ice sheet grew to its maximum extent, the pronounced periodicities which characterize MIS 3 are lost from the record. The exact timing of the Last Glacial Maximum is difficult to define in this record; but maxima in Neogloboquadrina pachyderma (sinistral) ع⁸O are observed between 21-17 Ky BP. A massive discharge of ice-rafted detritus, coincident with Heinrich event 1, is observed at about 16 Ky BP. Deglaciation of the margin is complete by about 15 Ky BP and surface waters warm rapidly after this date.     

Deep submarine pyroclastic eruptions: theory and predicted landforms and deposits

Submarine pyroclastic eruptions at depths greater than a few hundred meters are generally considered to be rare or absent because the pressure of the overlying water column is sufficient to suppress juvenile gas exsolution so that magmatic disruption and pyroclastic activity do not occur. Consideration of detailed models of the ascent and eruption of magma in a range of sea floor environments shows, however, that significant pyroclastic activity can occur even at depths in excess of 3000 m. In order to document and illustrate the full range of submarine eruption styles, we model several possible scenarios for the ascent and eruption of magma feeding submarine eruptions: (1) no gas exsolution; (2) gas exsolution but no magma disruption; (3) gas exsolution, magma disruption, and hawaiian-style fountaining; (4) volatile content builds up in the magma reservoir leading to hawaiian eruptions resulting from foam collapse; (5) magma volatile content insufficient to cause fragmentation normally but low rise speed results in strombolian activity; and (6) volatile content builds up in the top of a dike leading to vulcanian eruptions. We also examine the role of bulk-interaction steam explosivity and contact-surface steam explosivity as processes contributing to volcaniclastic formation in these environments. We concur with most earlier workers that for magma compositions typical of spreading centers and their vicinities, the most likely circumstance is the quiet effusion of magma with minor gas exsolution, and the production of somewhat vesicular pillow lavas or sheet flows, depending on effusion rate. The amounts by which magma would overshoot the vent in these types of eruptions would be insufficient to cause any magma disruption. The most likely mechanism of production of pyroclastic deposits in this environment is strombolian activity, due to the localized concentration of volatiles in magma that has a low rise rate; magmatic gas collects by bubble coalescence, and ascends in large isolated bubbles which disrupt the magma surface in the vent, producing localized blocks, bombs, and pyroclastic deposits. Another possible mode of occurrence of pyroclastic deposits results from vulcanian eruptions; these deposits, being characterized by the dominance of angular blocks of country rocks deposited in the vicinity of a crater, should be easily distinguishable from strombolian and hawaiian eruptions. However, we stress that a special case of the hawaiian eruption style is likely to occur in the submarine environment if magmatic gas buildup occurs in a magma reservoir by the upward drift of gas bubbles. In this case, a layer of foam will build up at the top of the reservoir in a sufficient concentration to exceed the volatile content necessary for disruption and hawaiian-style activity; the deposits and landforms are predicted to be somewhat different from those of a typical primary magmatic volatile-induced hawaiian eruption. Specifically, typical pyroclast sizes might be smaller; fountain heights may exceed those expected for the purely magmatic hawaiian case; cooling of descending pyroclasts would be more efficient, leading to different types of proximal deposits; and runout distances for density flows would be greater, potentially leading to submarine pyroclastic deposits surrounding vents out to distances of tens of meters to a kilometer. In addition, flows emerging after the evacuation of the foam layer would tend to be very depleted in volatiles, and thus extremely poor in vesicles relative to typical flows associated with hawaiian-style eruptions in the primary magmatic gas case. We examine several cases of reported submarine volcaniclastic deposits found at depths as great as 3000 m and conclude that submarine hawaiian and strombolian eruptions are much more common than previously suspected at mid-ocean ridges. Furthermore, the latter stages of development of volcanic edifices (seamounts) formed in submarine environments are excellent candidates for a wide range of submarine pyroclastic activity due not just to the effects of decreasing water depth, but also to: (1) the presence of a summit magma reservoir, which favors the buildup of magmatic foams (enhancing hawaiian-style activity) and episodic dike emplacement (which favors strombolian-style eruptions); and (2) the common occurrence of alkalic basalts, the CO₂ contents of which favor submarine explosive eruptions at depths greater than tholeiitic basalts. These models and predictions can be tested with future sampling and analysis programs and we provide a checklist of key observations to help distinguish among the eruption styles.     

Short‐term erosion rates from a 7Be inventory balance

Detailed soil erosion studies bene?t from the ability to quantify the magnitude of erosion over time scales appropriate to the process. An inventory balance for ⁷Be was used to calculate sediment erosion in a 30·73 m² plot during a series of runoff‐producing thunderstorms occurring over three days at the Deep Loess Research Station in Treynor, Iowa, USA. The inventory balance included determination of the pre‐ and post‐storm ⁷Be inventories in the soil, the atmospheric in?ux of ⁷Be during the event, and pro?les of the ⁷Be activity in the soil following the atmospheric deposition. The erosion calculated in the plot using the ⁷Be inventory balance was 0·058 g cm^?2, which is 23 per cent of the annual average erosion determined using ¹³⁷Cs inventories. The calculated erosion from the mass balance is similar to the 0·059 g cm^?2 of erosion estimated from the amount of sediment collected at the outlet of the 6 ha ?eld during the study period and the delivery ratio (0·64). The inventory balance of ⁷Be provides a new means for evaluating soil erosion over the time period most relevant to quantifying the prediction of erosion from runoff. Copyright © 2003 John Wiley & Sons, Ltd.