Wide-spaced sampling of humus in fennoscandia

In support of IGCP Project 259 (International Geochemical Mapping), a pilot survey designed to test the effectiveness of analysing dried humus collected at an extremely low sampling density (one composite sample per 23 000 km²) for geochemical mapping was carried out in 49 large catchment basins in Fennoscandia. The samples were analysed for their aqua-regia leachable contents of 30 elements by ICP-ES. The results were compared with those of till sampled at the same sites and with moss from previous surveys. The correlation with underlying bedrock was also studied.Geological features exert only a weak influence on the regional distribution of elements in humus. Exceptions are high levels of Ca and Sr in areas of carbonate bedrock and low contents of K in areas of Archean rocks. The distribution patterns of Co, Cr, Cu, Mg, Ni and Zn in humus coincide partly, and the levels correlate positively with those in till. The contents of Ni, Cr and Cu are lower in humus overlying acid magmatic rocks and arkose than other rock types.Pollution is the obvious source of high concentrations of Pb, Cd and Zn in southern Sweden and southern Norway. Acid fallout seems to cause leaching of Al, P and La from the humus horizon. The contents of these elements are low in the south where deposition of S and N is high and pH of rainwater is below 4.5. Deposition of sea salts gives high levels of Na, Mg, K and B along the coast of Norway and southern Sweden.The contents of several elements in humus correlate positively with the amount of organic matter (LOI). Comparison between four types of forest shows that the contents of Ca, Mg and Na in birch forest and of Cd, Mn, Pb and Zn in spruce forest are significantly higher than in other forest types. These features, however, are considered false and are due to sources such as atmospheric deposition of anthropogenic metals and sea salt.The results of the relatively strong chemical attack used for analyses of humus samples are less informative than those from till and overbank sediments. A weaker attack may have given more useful information. The humus horizon could be suited for environmental monitoring if used in global geochemical mapping.     

Enriched,HIMU-type peridotite and depleted recycled pyroxenite in the Canary plume: A mixed-up mantle

The Earth's mantle is chemically and isotopically heterogeneous, and a component of recycled oceanic crust is generally suspected in the convecting mantle [Hofmann and White, 1982. Mantle plumes from ancient oceanic crust. Earth Planet. Sci. Lett. 57, 421–436]. Indeed, the HIMU component (high µ = ²³⁸U/²⁰⁴Pb), one of four isotopically distinct end-members in the Earth's mantle, is generally attributed to relatively old (≥ 1–2 Ga) recycled oceanic crust in the form of eclogite/pyroxenite, e.g. [Zindler and Hart, 1986. Chemical geodynamics. Ann. Rev. Earth Planet. Sci. 14, 493–571]. Although the presence of the recycled component is generally supported by element and isotopic data, little is known about its physical state at mantle depths. Here we show that the concentrations of Ni, Mn and Ca in olivine from the Canarian shield stage lavas, which can be used to assess the physical nature of the source material (peridotite versus olivine-free pyroxenite) [Sobolev et al., 2007. The amount of recycled crust in sources of mantle-derived melts. Science 316, 412–417], correlate strongly with bulk rock Sr, Nd and Pb isotopic ratios. The most important result following from our data is that the enriched, HIMU-type (having higher ²⁰⁶Pb/²⁰⁴Pb than generally found in the other mantle end-members) signature of the Canarian hotspot magmas was not caused by a pyroxenite/eclogite constituent of the plume but appears to have been primarily hosted by peridotite. This implies that the old (older than ~ 1 Ga) ocean crust, which has more evolved radiogenic isotope compositions, was stirred into/reacted with the mantle so that there is not significant eclogite left, whereas younger recycled oceanic crust with depleted MORB isotopic signature (< 1 Ga) can be preserved as eclogite, which when melted can generate reaction pyroxenite.     

细粒酒精模型冰单轴压缩强度特征试验研究

介绍细粒酒精模型冰的单轴压缩强度试验研究的方法和结果．试验采用两种试样,即长方形和哑铃形．对长方形试样发生不同破坏模式发生的条件,即试样尺寸、加载速度和压头与试样接触面摩擦等效应进行了详细讨论．描述了细粒酒精模型冰单轴压缩强度的基本特征,并比较了两种试样的试验结果．     

Post‐Eocene intensification of deep‐water circulation in the central South Pacific: Micropalaeontological clues from dredged sites along the eastern Manihiki Plateau margin

Reconstruction of early Cenozoic deep‐water circulation is one of the keys to modelling Earth's greenhouse‐to‐icehouse surface evolution, but it has long been hampered by the paucity of information from the central South Pacific. To help overcome this knowledge gap, we present new micropalaeontological data from dredged carbonates (R/V Sonne Expedition SO193) at several eastern volcanic salients of the Manihiki Plateau. Interestingly, despite appreciable longitudinal separations among the dredged sites, ages indicated by the foraminiferal assemblages are consistently around the Middle Eocene (including mixed Turonian [Late Cretaceous]/Eocene at a single site), suggesting widespread post‐Eocene cessation of the pelagic sedimentation. By integrating with independent seismic and chronostratigraphic data (Deep Sea Drilling Project Leg 33) for large‐scale erosion of top‐Eocene–Oligocene sedimentary units on the eastern Manihiki Plateau, our results can be viewed as novel physical evidence for the intensification of central South Pacific deep‐water circulation since the Eocene/Oligocene climatic transition.     

Geochemical variations in the Cocos Plate subducting beneath Central America: implications for the composition of arc volcanism and the extent of the Galápagos Hotspot influence on the Cocos oceanic crust

New geochemical data from the Cocos Plate constrain the composition of the input into the Central American subduction zone and demonstrate the extent of influence of the Galápagos Hotspot on the Cocos Plate. Samples include sediments and basalts from Ocean Drilling Program (ODP) Site 1256 outboard of Nicaragua, gabbroic sills from ODP Sites 1039 and 1040, tholeiitic glasses from the Fisher Ridge off northwest Costa Rica, and basalts from the Galápagos Hotspot Track outboard of Central Costa Rica. Site 1256 basalts range from normal to enriched MORB in incompatible elements and have Pb and Nd isotopic compositions within the East Pacific Rise MORB field. The sediments have similar ²⁰⁶Pb/²⁰⁴Pb and only slightly more radiogenic ²⁰⁷Pb/²⁰⁴Pb and ²⁰⁸Pb/²⁰⁴Pb isotope ratios than the basalts. Altered samples from the subducting Galápagos Hotspot Track have similar Nd and Pb isotopic compositions to fresh Galápagos samples but have significantly higher Sr isotopic composition, indicating that the subduction input will have a distinct geochemical signature from Galápagos-type mantle material that may be present in the wedge beneath Costa Rica. Gabbroic sills from Sites 1039 and 1040 in East Pacific Rise (EPR) crust show evidence for influence of the Galápagos Hotspot ∼100 km beyond the morphological hotspot track.     

Inferred fault geometry and slip distribution of the 2010 Jiashian,Taiwan, earthquake is consistent with a thick-skinned deformation model

We invert measurements of coseismic displacements from 139 continuously recorded GPS sites from the 2010, Jiashian, Taiwan earthquake to solve for fault geometry and slip distribution using an elastic uniform stress drop inversion. The earthquake occurred at a depth of ~ 23 km in an area between the Western Foothills fold-and-thrust belt and the crystalline high mountains of the Central Range, providing an opportunity to examine the deep fault structure under Taiwan. The inferred rupture plane is oblique to the prominent orientation of thrust faults and parallel to several previously recognized NW-striking transfer zones that appear to connect stepping thrusts. We find that a fault striking 318°–344° with dip of 26°–41° fits the observations well with oblique reverse-sinistral slip under a low stress drop of about 0.5 MPa. The derived geodetic moment of 2.92 × 10¹⁸ N-m is equivalent to a M_w = 6.24 earthquake. Coseismic slip is largely concentrated within a circular patch with a 10-km radius at the depth between 10 and 24 km and maximum slip of 190 mm. We suggest this earthquake ruptured the NW-striking Chishan transfer fault zone, which we interpret as a listric NE-dipping lateral ramp with oblique slip connecting stepping thrust faults (ramps). The inferred slip on the lateral ramp is considerably deeper than the 7–15 km deep detachment identified in previous studies of western Taiwan. We infer an active basal detachment under western Taiwan at a depth of at least ~ 20–23 km based on these inversion results. The earthquake may have nucleated at the base of the lateral ramp near the intersection with the basal detachment. Coulomb stress change calculations suggest that this earthquake moved several NE-striking active thrust faults in western Taiwan nearer to failure.     

Volatile (sulphur and chlorine), major,and trace element geochemistry of mafic to intermediate tephras from the Chilean Southern Volcanic Zone (33–43°S)

Here we present the first systematic investigation of volatile geochemistry along the Southern Volcanic Zone (SVZ) of Chile. Holocene olivine-hosted melt inclusions in the most mafic tephras sampled from 16 volcanoes along the volcanic front of the SVZ between 33°S and 43°S were analysed for pre-eruptive sulphur, chlorine, and major element contents. These results are combined with trace element compositions of the host whole rocks. The highest fractionation-corrected gas contents occur in the least-degassed melt inclusions from small monogenetic cones of Los Hornitos, Cabeza de Vaca, and Apagado from both the transitional and the southern-central SVZ, reaching ~3,000 μg/g S and 1,400 μg/g Cl, while the lowest abundances of ~1,100 μg/g S and ~600 μg/g Cl were found in the central SVZ at Volcán Lonquimay, Volcán Llaima, and Volcán Villarrica. Chlorine co-varies with trace element indicators for the degree of melting and/or source enrichment, such that the lowest Cl contents are found in high-degree melts from the most depleted mantle sources. The size of the volcanic edifices correlates inversely with Cl abundances in the melt. This could reflect more extensive degassing during ascent through the complex magma plumbing systems beneath the stratovolcanoes or greater dilution during larger degrees of melting of more depleted sources, or a combination of these factors. Compared to other subduction zones, the SVZ melt inclusions exhibit Cl and S abundances in the same range as most of those from the Central American and those from the Marianas arcs.     

Temperature in lowland Danish streams: contemporary patterns,empirical models and future scenarios

Continuous temperature measurements at 11 stream sites in small lowland streams of North Zealand, Denmark over a year showed much higher summer temperatures and lower winter temperatures along the course of the stream with artificial lakes than in the stream without lakes. The influence of lakes was even more prominent in the comparisons of colder lake inlets and warmer outlets and led to the decline of cold‐water and oxygen‐demanding brown trout. Seasonal and daily temperature variations were, as anticipated, dampened by forest cover, groundwater input, input from sewage plants and high downstream discharges. Seasonal variations in daily water temperature could be predicted with high accuracy at all sites by a linear air‐water regression model (r²: 0·903–0·947). The predictions improved in all instances (r²: 0·927–0·964) by a non‐linear logistic regression according to which water temperatures do not fall below freezing and they increase less steeply than air temperatures at high temperatures because of enhanced heat loss from the stream by evaporation and back radiation. The predictions improved slightly (r²: 0·933–0·969) by a multiple regression model which, in addition to air temperature as the main predictor, included solar radiation at un‐shaded sites, relative humidity, precipitation and discharge. Application of the non‐linear logistic model for a warming scenario of 4–5 °C higher air temperatures in Denmark in 2070‐2100 yielded predictions of temperatures rising 1·6–3·0 °C during winter and summer and 4·4–6·0 °C during spring in un‐shaded streams with low groundwater input. Groundwater‐fed springs are expected to follow the increase of mean air temperatures for the region. Great caution should be exercised in these temperature projections because global and regional climate scenarios remain open to discussion. Copyright © 2006 John Wiley & Sons, Ltd.     

The surface energy balance at the Huygens landing site and the moist surface conditions on Titan

The Huygens Probe provided a wealth of data concerning the atmosphere of Titan. It also provided tantalizing evidence of a small amount of surface liquid. We have developed a detailed surface energy balance for the Probe landing site. We find that the daily averaged non-radiative fluxes at the surface are 0.7 W m^?2, much larger than the global average value predicted by McKay et al. (1991) of 0.037 W m^?2. Considering the moist surface, the methane and ethane detected by the Probe from the surface is consistent with a ternary liquid of ethane, methane, and nitrogen present on the surface with mole fractions of methane, ethane, and nitrogen of 0.44, 0.34, and 0.22, respectively, and a total mass load of ～0.05 kg m^?2. If this liquid is included in the surface energy balance, only a small fraction of the non-radiative energy is due to latent heat release (～10^?3 W m^?2). If the amount of atmospheric ethane is less than 0.6×10^?5, the surface liquid is most likely evaporating over timescales of 5 Titan days, and the moist surface is probably a remnant of a recent precipitation event. If the surface liquid mass loading is increased to 0.5 kg m^?2, then the liquid lifetime increases to ～56 Titan days. Our modeling results indicate a dew cycle is unlikely, given that even when the diurnal variation of liquid is in equilibrium, the diurnal mass variation is only 3% of the total liquid. If we assume a high atmospheric mixing ratio of ethane (>0.6×10^?5), the precipitation of liquid is large (38 cm/Titan year for an ethane mixing ratio of 2×10^?5). Such a flux is many orders of magnitude in excess of the photochemical production rate of ethane.     

Resistance to the deinstitutionalization of a region: Borders,identity and activism in a municipality merger

Regions are contested processes in which various layers of borders become articulated, deconstructed and reconstructed by both activists and advocates. While many scholars currently tend to highlight the relational character of spaces, this study – acknowledging that seeing regions as relational or territorial is a highly contextual matter – emphasizes the territorial approach by stressing the multiple layers of borders and how they help to constitute and nurture regional identity. Focusing on deinstitutionalization of a region, it is argued here that regional restructuring can trigger activism, as proved by the activist movement at issue in the case study. This case study of a merger between two municipalities in Finland illustrates that when threatened with integration, (old) regions seem to be of especial importance as bordered territories of identification.