A seismic hazard map of India and adjacent areas

We have produced a probabilistic seismic hazard map showing peak ground accelerations in rock for India and neighboring areas having a 10% probability of being exceeded in 50 years. Seismogenic zones were identified on the basis of historical seismicity, seismotectonics and geology of the region. Procedures for reducing the incompleteness of earthquake catalogs were followed before estimating recurrence parameters. An eastern United States acceleration attenuation relationship was employed after it was found that intensity attenuation for the Indian region and the eastern United States was similar. The largest probabilistic accelerations are obtained in the seismotectonic belts of Kirthar, Hindukush, Himalaya, Arakan-Yoma, and the Shillong massif where values of over 70% g have been calculated.     

Identification and mapping of riverbed sediment facies in the Columbia River through integration of field observations and numerical simulations

In the Hanford Reach of the Columbia River, a thin layer of recent alluvium overlies the sedimentary formations that comprise the unconfined groundwater aquifer. Experimental and modelling studies have demonstrated that this alluvial layer exerts significant control on the exchange of groundwater and surface water (hydrologic exchange flux), and is associated with elevated levels of biogeochemical activity. This layer is also observed to be strongly heterogeneous, and quantifying the spatial distribution of properties over the range of scales of interest is challenging. Facies are elements of a sediment classification scheme that groups complex geologic materials into a set of discrete classes according to distinguishing features. Facies classifications have been used as a framework for assigning heterogeneous material properties to grid cells of numerical models of flow and reactive transport in subsurface media. The usefulness of such an approach hinges on being able to relate facies to quantitative properties needed for flow and reactive transport modelling, and on being able to map facies over the domain of interest using readily available information. Although aquifer facies have been used in various modelling contexts, application of this concept to riverbed sediments is relatively new. Here, we describe an approach for categorizing and mapping recent alluvial (riverbed) sediments based on the integration of diverse observations with numerical simulations of river hydrodynamics. The facies have distinct distributions of sediment texture that correspond to variations in hydraulic properties, and therefore provide a useful framework for assigning heterogeneous properties in numerical simulations of hydrologic exchange flows and biogeochemical processes.     

Do weak AR4 models bias projections of future climate changes over Australia?

Regional climate projections using climate models commonly use an “all-model” ensemble based on data sets such as the Intergovernmental Panel on Climate Change’s (IPCC) 4th Assessment (AR4). Some regional assessments have omitted models based on specific criteria. We use a criteria based on the capacity of climate models to simulate the observed probability density function calculated using daily data, model-by-model and region-by-region for each of the AR4 models over Australia. We demonstrate that by omitting those climate models with relatively weak skill in simulating the observed probability density functions of maximum and minimum temperature and precipitation, different regional projections are obtained. Differences include: larger increases in the mean maximum and mean minimum temperatures, but smaller increases in the annual maximum and minimum temperatures. There is little impact on mean precipitation but the better models simulate a larger increase in the annual rainfall event combined with a larger decrease in the number of rain days. The weaker models bias the amount of mean warming towards lower increases, bias annual maximum temperatures to excessive warming and bias precipitation such that the amount of the annual rainfall event is under-estimated. We suggest that omitting weak models from regional scale estimates of future climate change helps clarify the nature and scale of the projected impacts of global warming.     

The Al2O3 contents of enstatite in equilibrium with garnet in the system MgO-Al2O3-SiO2 at 15–40 kbar and 900°–1,600° C

Forty-six reversed determinations of the Al₂O₃content of enstatite in equilibrium with garnet were made in the P/T range 15–40 kbar/900–1,600° C in the MgO-Al₂O₃-SiO₂ system. Starting materials were mixtures of synthetic pyrope+Al-free enstatite and pyrope+enstatite (5–12% Al₂O₃). Al₂O₃ contents in reversal run pairs closely approached common values from both the high- and low-Al sides. Most experiments were done in a piston-cylinder device using a NaCl medium; some runs at very high temperatures were made in pyrex/NaCl or pyrex/talc assemblies. The measured enstatite compositions, expressed as mole fractions of Mg₂(MgAl)(AlSi₃)O₁₂(X _Opy ^En ) were fitted by a Monte-Carlo method to the equilibrium condition: $$\begin{gathered} \Delta H_{970}^0 - 970\Delta S_{970}^0 \hfill \\ + \mathop \smallint \limits_1^P \Delta V_{970}^0 dP - \mathop \smallint \limits_{970}^T \Delta S_T^0 dT + RT\ln X_{Opy}^{En} = 0 \hfill \\ \end{gathered}$$ where the best fit parameters of ΔH, ΔS and ΔV (1 bar, 970 K) for the reaction pyrope=opy are 2,040 cal/mol, 2.12 eu and 9.55 cc/mol. In addition to the determination of Al₂O₃ contents of enstatite, the univariant reaction pyrope+forsterite=enstatite+spinel was reversibly located in the range 1,100–1,400°C. A “best-fit” line passes through 22, 22.5 and 25 kbar at 1,040, 1,255 and 1,415°C, respectively. Our results for the univariant reaction are in agreement with previous studies of MacGregor (1974) and Haselton (1979). However, comparison of the experimentally determined curve with thermochemical calculations suggests that there may be a small error in the tabulated ΔH _f(970,1) ⁰ value for enstatite. A value of?8.32 rather than?8.81 kcal/mole (Charlu et al. 1975) is consistent with the present data. Application of garnet-enstatite-spinel-forsterite equilibria to natural materials is fraught with difficulties. The effects of nonternary components are poorly understood, and the low solubilities of Al₂O₃ in enstatite under most geologically reasonable conditions make barometric or thermometric calculations highly sensitive. More detailed studies, including reversed determinations in low-friction assemblies, are sorely needed before the effects of important diluents such as Fe, Ca and Cr can be fully understood.     

Gastric lavage as a non-lethal method for stingray (Myliobatiformes) diet sampling

Understanding the trophic interactions of ecologically important mesopredators such as Myliobatiformes (stingrays) is vital, but, given their susceptibility to overexploitation, the collection of stomach contents for dietary analysis necessitates the use of non-lethal methods. We provide a detailed method of using gastric lavage to collect stomach contents from the ‘Vulnerable’ porcupine ray Urogymnus asperrimus at the St Joseph Atoll of the Amirantes Group, Seychelles. Rays were captured by hand, inverted and restrained while a plastic hose, connected to a bilge pump, was inserted into the stomach to flush out the contents. A high percentage (94.5%) of gastric lavage attempts resulted in the collection of stomach contents. There was no visual evidence of stress or short-term, post-release mortality and, given the success and relative ease of this technique, we conclude that the described method of gastric lavage is an effective, non-lethal means of obtaining stomach contents from stingrays.     

Chemotaxonomic investigation of phytoplankton in the shelf ecosystem of the KwaZulu-Natal Bight,South Africa

Phytoplankton community structure was elucidated during summer and winter in the KwaZulu-Natal Bight using pigment and CHEMTAX analyses. The surface pattern in January 2010 indicated that diatoms, haptophytes and prasinophytes tended to be the most prominent groups inshore and in the southern sector of the bight, whereas Prochlorococcus and Synechococcus were more dominant in the north and towards the offshore region. At the deep chlorophyll maximum (DCM), diatoms were dominant in the inner bight and in the south, with prasinophytes being the prominent flagellates, but this changed to Prochlorococcus and pelagophytes being the important groups in the northern sector and outer part of the bight. A different pattern was observed at the surface in July 2010, where diatoms, haptophytes, prasinophytes and cryptophytes in varying proportions comprised most of the community in the inner half of the bight, whereas Synechococcus and haptophytes were the main groups in the outer sector. A similar pattern occurred at the DCM, except that Synechococcus was less prominent and pelagophytes were distributed across the bight in both the inshore and offshore zones. Observations and relationships between phytoplankton groups and environmental parameters indicated that the groups were most closely related to temperature, accounting for 24–64% of the deviance. The influence of nutrients on phytoplankton was less clear but nitrate and silicate seemed to account for some of the patchy distribution patterns.     

Cytosolic metal distribution as an indicator of toxicity in sea urchins from the Southern California Bight

Sea urchins (Strongylocentrotus purpuratus) were collected from intertidal stations at Point Dume, Redondo Beach and White's Point in the Southern California Bight. Cytosolic metal levels varied both within and between stations, with the highest levels found in organisms from White's Point. Examination of the cytosolic metal distribution by Sephadex G-75 gel chromatography indicated that organisms adapted to increased levels of trace metals by producing more of a metallothionein-like metal-binding protein. Histological and histochemical examinations indicated that these organisms were not stressed over the range of metal concentrations encountered in this study.     

Correlation and characterisation of individual glass shards from tephra deposits using trace element laser ablation ICP‐MS analyses: current status and future potential

Laser ablation inductively coupled plasma mass spectrometry (LA‐ICP‐MS) is a high spatial resolution analytical method which has been applied to the analysis of silicic tephras. With current instrumentation, around 30 trace elements can be determined from single glass shards as small as ～ 40 µm, separated from tephra deposits. As a result of element fractionation during the ablation process using a 266 nm laser, a relatively complex calibration strategy is required. Nonetheless, such a strategy gives analyses which are accurate (typically within ±5%) and have an analytical precision which varies from ～ ±2% at 100 ppm, to ～ ±15% at 1 ppm. Detection limits for elements used in correlation and discrimination studies are well below 1 ppm. Examples of the application of trace element analysis by LA‐ICP‐MS in tephra studies are presented from the USA, New Zealand and the Mediterranean. Improvements in instrumental sensitivity in recent years have the potential to lower detection limits and improve analytical precision, thus allowing the analysis of smaller glass shards from more distal tephras. Laser systems operating at shorter wavelengths (e.g. 193 nm) are now more widely available, and produce a much more controllable ablation in glasses than 266 nm lasers. Crater sizes of <10 µm are easily achieved, and at 193 nm many of the elemental fractionation issues which mar longer wavelengths are overcome. By coupling a short wavelength laser to a modern ICP‐MS it should be possible to determine the trace element composition of glass shards as small as 20 µm and, providing sample preparation issues can be overcome, the determination of the more abundant trace elements in glass shards as small as 10 µm is within instrumental capabilities. This will make it possible to chemically fingerprint tephra deposits which are far from their sources, and will greatly extend the range over which geochemical correlation of tephras can be undertaken. Copyright © 2007 John Wiley & Sons, Ltd.     

Palynological analyses in the laminated sediment of Lake Holzmaar (Eifel, Germany): duration of Lateglacial and Preboreal biozones

The laminated sediment of Lake Holzmaar (Germany) has provided a continuous varve chronology for the last 3500 varve years (vy) and beyond that a floating varve chronology back to more than 22500 vy BP. This chronology in calendar years, in combination with palynology, enables us to determine the timing and the magnitude of Lateglacial and Early Holocene environmental changes on land (from 13838 to 10930 vy BP). The palynological diagram has a mean time resolution of 27 vy between samples. This paper establishes for the first time the biozonation for Lake Holzmaar below the Laacher See Tephra. Fifteen pollen subzones grouped in four biozones are defined by cluster analysis. After a period disturbed by microturbidites, only a part of the Bølling is present. Three cold periods have been evidenced by pollen analyses: the Older Dryas (96-vy-long), the Younger Dryas (654-vy-long) and the Rammelbeek phase (237-vy-long). The Allerød (883-vy-long) is bipartite with a first Betula -dominated period followed by a Pinus -dominated one. The Younger Dryas is also bipartite, with first a decrease of winter temperatures along with a change to a more continental climate. It is followed by a drier phase with a second decrease in temperatures, probably this time also affecting summer temperatures. The Preboreal is 702-yr-long. The duration of most phases corresponds to published records, except for that of the Younger Dryas. Cluster and rate-of-change analyses indicate a sharp change in the terrestrial vegetation assemblages that may be caused by a sedimentary hiatus of erosive origin during this cold and dry period. As a result, the chronology of Holzmaar has to be revised most likely below the middle of the Younger Dryas. Comparison with the varve record of Meerfelder Maar, a neighbour maar lake, suggests adding 320 vy below 12025 vy.     

Further studies upon a steel works effluent

Despite its visual impact and the substantial release of effluent from a steel works on the Cumbrian coast, an earlier study suggested that it was likely to have little environmental effect. A further examination of this plant has been made and the original conclusion confirmed.