Composition and source identification of polycyclic aromatic hydrocarbons in mangrove sediments of Peninsular Malaysia: indication of anthropogenic input

This is a comprehensive study of the composition, origin and sources of specific polycyclic aromatic hydrocarbons (PAHs) in sediments of mangrove estuary in the western part of Peninsular Malaysia. Mangrove sediments were analyzed for 17 PAHs by gas chromatography–mass spectrometry. Total PAH concentrations in the sediments ranged from 20 to 112 ng/g on a dry-weight basis. High molecular weight PAHs were abundant in the sediments. Parent PAH ratios revealed that pyrogenic input has important contribution to the sedimentary PAHs. Ratios of alkylated PAHs indicate that the sedimentary PAHs were influenced by petrogenic PAHs, which implies that petrogenic input has contribution to the sedimentary PAHs but that it is not a major factor in distribution of PAHs within the estuary. Combustion-derived PAHs show a positive and very strong correlation with total PAHs (R ² = 0.926, p < 0.05). Total methylphenanthrenes show very weak correlation with total PAHs (R ² = 0.0928, p < 0.05). The PAH concentrations were found to increase with distance from the upstream of the estuary to the coastal area of the Straits of Malacca. For the assessment of sediment contamination using biological thresholds, none of the individual studied PAH compounds exceeded the values of the effect range low–effect range median guideline and the threshold effects level–probable effects level guideline. This study demonstrates that the sediments of the mangrove ecosystem facing the Straits of Malacca and Sumatra are influenced by anthropogenic PAH inputs as a result of human activities such as biomass burning, vehicle emissions and boating activities.     

低幅值小应变振动下土体弹性刚度的非线性特征与表述方法

随着高速铁路建设的兴起,轨道以及沿线附近建筑物承受低幅值小应变振动荷载的作用。对于小应变振动下土体的有限元计算,如何确定连接应力和应变之间纽带的刚度张量E,对于建立合理的预测模型来分析高速铁路轨道以及沿线建筑物的沉降变形至关重要。低幅值小应变振动下剪切模量G和阻尼比D随剪应变幅值的变化是反映土体刚度及阻尼特征最重要的两个参数。通过共振柱试验发现,振动荷载作用下土体的剪切模量G必须通过振动应变幅值和固结围压共同来确定,即使在小应变（剪应变幅值10-6相似文献   

Comparison of the Ordovician-Carboniferous Boundary Between Korea and NE China: Implications for Correlation and Tectonic Evolution

There is a great hiatus between Ordovician and Carboniferous strata in the Northeast China and Korean Peninsula. In order to understand geology and tectonic evolution, and to find out the similarities and differences in both regions, two sections in the Western Hill near Beijing in NE China and several sections in the Korean Peninsula were selected to examine their geologic boundaries between Lower and Upper Paleozoic strata to compare their characteristic features. At four sites in the two sections in the Western Hill near Beijing were examined their contact relations. The Hui Yu section is the same horizon where one site is top of a quarry hill and the other of down hill. Mid-Carboniferous Qingshuijian Formation rests on the Ordovician Majiagou Formation. Limestone beds are more commonly intercalated with shale and sandstone at site 2 of the Hui Yu section, while at site 1, conglomerate beds are dominant. Site 1 of the Se Shu Fen section shows eroded and concealed karst topography and conglomerate beds are intercalated within shale beds. Silurian and Devonian strata are absent in these areas. In the Korean Peninsula, most O-C contacts occur between Ordovician limestone formation and Carboniferous strata, although Silurian strata occur beneath the Carboniferous strata in the Jeongseon area and Pyeongnam Basin. Most contact relations are parallel unconformity and angular unconformity is rarely seen. The O-C relations in both regions are similar to each other, and these indicate that the Korean Peninsula was located near or belonged to the Sino-Korean paraplatform during Paleozoic time.     

二红洼镁铁-超镁铁杂岩体特征及成因

新疆哈密二红洼镁铁-超镁铁杂岩体地表分南北两个岩体,深部可能连为一体,可划分为两个侵入期、四个岩相.第一侵入期构成岩体的主体部分,分异良好,由重力结晶分异形成自橄揽岩相、橄榄辉长岩相向含石英苏长辉长岩相的分异趋势,基性程度依次降低.岩浆多次贯入使得纵向上橄榄岩相和橄榄辉长岩相重复出现.第二侵入期辉长苏长岩相分异程度低,岩性稳定,为岩浆快速冷凝的产物.岩浆属于拉斑玄武岩系列,发生过金属硫化物熔离,有利于铜镍硫化物成矿.     

Geological Controls on the CBM Productivity of No.15 Coal Seam of Carboniferous–Permian Taiyuan Formation in Southern Qinshui Basin and Prediction for CBM High-yield Potential Regions

Coalbed methane (CBM) resources in No.15 coal seam of Taiyuan Formation account for 55% of the total CBM resources in southern Qinshui Basin (SQB), and have a great production potential. This study aims at investigating the CBM production in No.15 coal seam and its influence factors. Based on a series of laboratory experiments and latest exploration and development data from local coal mines and CBM companies, the spatial characteristics of gas production of No.15 coal seam were analyzed and then the influences of seven factors on the gas productivity of this coal seam were discussed, including coal thickness, burial depth, gas content, ratio of critical desorption pressure to original coal reservoir pressure (RCPOP), porosity, permeability, and hydrogeological condition. The influences of hydrological condition on CBM production were analyzed based on the discussions of four aspects: hydrogeochemistry, roof lithology and its distribution, hydrodynamic field of groundwater, and recharge rate of groundwater. Finally, a three-level analytic hierarchy process (AHP) evaluation model was proposed for predicting the CBM potentials of the No.15 coal seam in the SQB. The best prospective target area for CBM production of the No.15 coal seam is predicted to be in the districts of Panzhuang, Chengzhuang and south of Hudi.     

大兴安岭地区内生铜矿床的成因类型、成矿时代与成矿动力学背景

大兴安岭地区位于兴蒙造山带的东段,构造、岩浆活动强烈,蕴藏着丰富的内生有色金属、贵金属矿产资源。本文通过对该区内生铜矿床的地质特征、成因类型和年代学研究,初步将区内内生铜矿床划分为斑岩型、浅成热液高硫化型(铜银、铜锡)和接触交代型三种成因类型,除铜锡矿床外,它们的成矿作用均与高钾钙碱系列I型花岗质岩浆密切相关;其中斑岩型和浅成热液高硫化型(铜、银)的成矿分别发生在485Ma、180~170Ma和170~160Ma;而浅成热液高硫化型(铜锡)矿床与A型花岗质岩浆相关,成矿在150~135Ma之间;接触交代型与它们相伴生,主要发生在180~160Ma和150~135Ma。其成矿动力学背景分别与早古生代兴安地块与松嫩地块的拼合碰撞造山、中侏罗世的西伯利亚板块和华北板块的陆缘增生带碰撞缝合造山与早白垩世碰撞造山后的地壳伸展减薄作用过程相适应,矿床在不同阶段的造山挤压与伸展转换或造山期后的伸展阶段就位,这项研究为深入研究该区内生多金属成矿规律提供了科学依据。     

滇西施甸地区二叠纪卧牛寺组大陆溢流玄武岩的发现

施甸地区的卧牛寺组玄武岩分布广泛。通过近年的野外工作,发现施甸地区的卧牛寺组玄武岩中缺乏沉积夹层,其岩石学特征和地球化学特征均与峨眉山玄武岩相似,具有大陆溢流相喷发的特点。     

下扬子区二叠系烃源岩评价与生源环境

基于下扬子区海域-陆域钻井岩心和露头岩样, 通过有机岩石学和有机地球化学方法, 应用有效指标参数, 从不同维度综合分析下扬子区上二叠统大隆组、龙潭组和下二叠统孤峰组、栖霞组4套烃源岩在纵向及平面上的有机地球化学特征、生烃潜力和生源环境。根据测试数据及前人研究资料, 栖霞组和大隆组烃源岩的有机质丰度为中等-好级别, 龙潭组烃源岩的有机质丰度为一般-中等级别, 孤峰组烃源岩有机质丰度达到很好级别。下二叠统烃源岩有机质丰度在平面展布上表现出海域优于陆域的特点, 上二叠统则反之。根据干酪根碳同位素特征, 栖霞组烃源岩有机质类型最好, 为Ⅰ~Ⅱ型; 其他3套烃源岩均为Ⅱ~Ⅲ型母质类型。4套烃源岩成熟度参数镜质体反射率主频分布范围为1.3%~2.0%, 均达到高热演化阶段, 在平面展布上表现出明显的非均一性。二叠系4套烃源岩生物来源以低等水生生物为主, 有机质均在贫氧的弱还原-弱氧化条件下保存, 其中大隆组沉积的水体动荡频繁和生物变化较明显。综合认为, 下扬子区二叠系烃源岩有机质丰度高, 类型较好, 具有形成大型油气田的良好物质基础, 尤其是以往被忽略的孤峰组烃源岩评价等级被提高, 是一套潜在的优质烃源岩, 其对该区进一步的油气勘探具有重要的指导意义。     

北秦岭二郎坪群抱树坪组沉积时代与构造环境

二郎坪群抱树坪组作为北秦岭早古生代重要的沉积记录,其研究程度较低。本文通过对抱树坪组内火山岩夹层和花岗斑岩脉进行岩石学、地球化学和锆石U- Pb测年研究,旨在进一步确定其沉积时代与构造环境。研究结果表明：豫西夏馆地区抱树坪组火山岩夹层已变质为（黑云）阳起钠长片岩,常与黑云石英片岩呈“互层状”产出;岩石原岩为安山质凝灰岩,具有相对低的SiO2（52. 56%~62. 04%）、较高的Al2O3（10. 70%~18. 55%）、低的MgO（4. 06%~6. 21%）和FeOT/MgO（1. 23~1. 81）,富集轻稀土元素和大离子亲石元素Rb、Th、U、K,相对亏损高场强元素Nb、Ta、P、Ti,具镁安山质岩石的特点;结合地球化学特征及前人研究认为,抱树坪组可能形成于活动陆缘弧后盆地。获得黑云阳起钠长片岩原岩的结晶锆石U- Pb年龄为446. 0±1. 7 Ma,以及侵入其中花岗斑岩脉的成岩年龄为430. 0±3. 0 Ma,首次将抱树坪组的形成时代准确地限定为晚奥陶世至早志留世。综合区域研究成果认为,小寨组和抱树坪组在地层层序和地层时代上符合广义二郎坪群的划分方案,但大庙组、火神庙组及由小寨组和抱树坪组构成的整体三者在形成时代上表现为近于同时性,在空间上主体呈现近平行关系,可能主体属时代大体相当的不同沉积环境的产物;在大地构造属性方面,认为二郎坪群是在约470 Ma之前由于商丹洋向北俯冲而形成的火山岛弧,在470~436 Ma转化为弧后盆地,至约430 Ma之前最终完成消减闭合。