Synthesis and characterization of reusable nano-order SO<Subscript>3</Subscript>H-KIT-5 as a heterogeneous catalyst for eco-friendly synthesis of 1,4-dihydropyridines

A novel nanocatalyst silica-bonded sulfuric acid supported on KIT-5 as an organic–inorganic hybrid with high activity was prepared successfully. The KIT-5 with high surface area was reacted with chlorosulfonic acid via simple and rapid method. This efficient and reusable heterogeneous catalyst sulfuric acid nanocatalyst catalyzed one-pot synthesis of β-dicarbonyl compounds, aldehyde and ammonium acetate in the presence of 0.05 g of nanocatalyst at room temperature via solvent-free conditions to afford excellent yields of 1,4-dihydropyridines. This nanocatalyst was fully characterized by XRD, SEM–EDXS and Map analyses. The morphology of the catalyst surface by SEM images shows all porous of KIT-5 after the reaction was filled with the SO₃H groups. The average size determines around 22–24 nm. This catalyst can be reused five times without any significant loss of activity, too. The ease of separation, high activity, high surface area and reaction under open air condition are the main advantages of this catalyst.     

Geometry of a convergent zone, Central British Columbia, Canada

The Canadian Cordillera is separable into two major northerly trending tectonic units—the Pacific Orogen and the Columbian Orogen, with the latter further separated into the Omineca Crystalline Belt and the easterly Rocky Mountain Fold and Thrust Belt. Synkinematic metamorphism of Jurassic age within the Omineca Belt is thought to be associated with accretion of westerly terranes of the Pacific Orogen—more specifically the Quesnellia terrane—that was thrust easterly over the Omineca Belt towards the craton. Mylonitic rocks mark the margin between these two belts and this margin is well-exposed near Crooked Lake, central British Columbia.Structural analysis across the zone of convergence between these two terranes indicates that the cratonic basement and the accreted cover sequences have several phases of deformation and metamorphism in common. The initial common phase of deformation, wherein convergence is accomplished, is characterized by easterly verging folds that are superposed by a second common phase having westerly verging folds that deform the zone of convergence and control the present regional map pattern. A final common phase of deformation produced easterly verging folds.Change in vergence direction is interpreted as resulting from change in direction of transport related to subduction process: first obduction of Quesnellia onto the Omineca craton, followed later by easterly subduction of an oceanic Quesnellia below the craton.All evidence of transport direction(s) points to convergence occurring at very high angles to the zone of convergence. There appears to be no evidence of transport parallel with the strike of the zone. If transport has taken place parallel to the strike of the zone, then this transport occurred before convergence or evidence of this motion has been destroyed during the convergence.     

Malta: macropolitical threats

Despite constitutional neutrality and non-alignment, for the last decade Malta has dabbled in Western security circles. By pledging commitment to the European CFSP and forging closer associations with NATO the government consummated allegiances with the hegemonic flank of their region and the only remaining superpower. However, Maltese security in the post-Cold War era is about more than just power fealty. Whilst not overlooking the still highly relevant military threats to security, this paper elucidates three macropolitical threats that are too impetuous for the worlds most powerful security organizations to handle. Indeed, future Maltese membership of the WEU or closer ties with NATO may even exacerbate these menaces.     

3.3 Millimeter limb brightening measurements during the 30 June 1973 total solar eclipse

Solar limb brightening measurements at a wavelength of 3.3 mm were made during the 30 June 1973 total solar eclipse from a site at Lake Rudolf, Kenya. The results show that at this wavelength there is a limb brightening of about 20%, occurring within one half arc min of the limb.     

Plasmasphere convection patterns observed simultaneously from two ground stations

Whistler data recorded during a 14 h period on 10–11 July 1973 at Siple (L = 4.17) and Sanae (L = 3.98) have been used to compare the apparent plasma convection patterns observed from these Antarctic stations. Two distinct bulges in the plasmasphere are seen at both stations, each bulge corresponding to an apparent outflowed followed by in flow of plasma. These structures do not coincide in U.T. or M.L.T. The first bulge is seen at Siple almost 1 h earlier in M.L.T. than at Sanae and the second bulge almost 3 h earlier. This is interpreted in terms of a fairly rapid westward and inward movement of the plasmasphere structure.     

Isolation of integrals for centroid orbits in stellar system models

In this paper we present two solutions for isolating integrals of the centroid motion in a non-stationary stellar system under the ellipsoidal hypothesis with point-axial symmetry.Paper presented at the 11th European Regional Astronomical Meetings of the IAU on New Windows to the Universe, held 3–8 July, 1989, Tenerife, Canary Islands, Spain.     

Patuxent Landscape Model. III. Model calibration

Using the LHEM/SME the Patuxent Landscape Model (PLM) was built to simulate fundamental ecological processes in the watershed scale driven by temporal (nutrient loadings, climatic conditions) and spatial (land use patterns) forcings. The model addresses the effects of both the magnitude and spatial patterns of land use change and agricultural practices on hydrology, plant productivity, and nutrient cycling in the landscape. The spatial resolution for the full Patuxent watershed is 1 km², while subwatersheds are analyzed at a 200 × 200 m resolution to allow adequate depiction of the pattern of ecosystems and human settlement on the landscape. The temporal resolution is different for various components of the model. We used a modular, multiscale approach to calibrate and test the model. Model results show good agreement with data.     

On the yearly phase delay of winter intraseasonal mode in the western United States

In the western United States, persistent and recurrent flow patterns not only modulate precipitation events but also result in prolonged surface inversion episodes. In this region, the frequency of persistent ridge/trough events ranges between 20 and 40 days, well within the intraseasonal timescale. Based on NCEP reanalysis data starting at 1949, with a focus on the interior West, we observed that episodes of prolonged ridge/trough events appear to occur about a week later every year and resets every 5–7 years—a previously undocumented phenomenon examined herein. Diagnostic analyses indicate that the interplay between regional intraseasonal flow patterns and the North Atlantic Oscillation (NAO) alternates the preferred timeframe for the persistent ridge/trough events to occur. This may result from different phases of the NAO shifting the winter mean ridge and such shifts modulate the occurrence and timing of persistent ridge/trough events. When the timing changes evolve around the quasi-6 years cycle of the NAO, the resultant evolution forms what appears to be a steady phase delay in the ridge/trough events year after year. These results are a further step in disclosing the multiple-scale interaction between intraseasonal and interannual modes and its regional climate/weather impact.     

Analysis of geodetic satellite (Geos I) observations in North America

Geos I observations made at thirty optical and four Secor stations were analyzed in the geometric and short-arc modes for the purpose of detecting systematic distortions in the North American Datum. The results indicate that the Nad at its origin (Meades Ranch, Kansas) requires an easterly rotation in azimuth and a westerly rotation in the prime vertical plane, both in the magnitude of one second of arc to fit the satellite data. There is also evidence of the need for a reduction in scale of about 1:200.000.