Barometric pumping effects on soil gas studies for geological and environmental characterization

Data from two free soil gas sampling programs are evaluated for the effects of barometric pumping over time on measured soil gas volumes. One program collected data from the trapped atmosphere immediately above two hazardous waste landfill areas. Of these areas, one had extremely high soil gas emanations, whereas the other had a more modest soil gas release. The second experimental program involved the collection of free soil gas samples on a rough grid with an approximate spacing of 1.6 km over a 720-sq-km area. This reconnaissance effort was designed to establish regional soil gas background values and to establish the utility of this method as a geological mapping tool in the Atlantic Coastal Plain. Methane, ethane, propane, and hydrogen data are used for this study. The data suggest that there is a predictable change in soil gas volume with a given change in barometric pressure. The rate of change is greater with large soil gas volumes in permeable soils versus lower soil gas volumes in impermeable soils; however, a simple linear relationship seems to generate a predictable curve with a margin of error of approximately 50%. Furthermore, the results of this study indicate that barometric pumping effects should be strongly considered during soil gas screening efforts at hazardous waste sites as well as in regional studies for hydrocarbon source potential mapping.     

Stokes problem for infinite vertical plate with constant heat flux

An exact solution for the Stokes problem for an infinite vertical plate has been derived on taking into account the constant heat flux at the plate. It has been observed that the velocity of the fluid increases with increasingt (time) orG (the Grashof number).     

CM-like interplanetary dust particles in lower stratosphere during 1989 October and 1991 June/July

Abstract— The stratospheric interplanetary dust particles L2005T12 and L2011O3 are linked to CM chondrite matrix. Particle L2005T12 is dominated by tabular grains of partially dehydrated greenalite-rich serpentine. Its amorphous matrix contains abundant smectite nanocrystals and annular Fe, Ni, S units. A uniquely stratified (partial) maghémite rim occurs only on S-rich parts of the matrix. Formation of this rim and Mg depletions in the matrix occurred during atmospheric entry heating of this particle. Particle L2011O3 has large iron sulfide and magnesiowüstite grains in an amorphous low-Al, ferromagnesiosilica matrix. Hydrous crystallisation of this matrix produced ultrafine-grained smectites and disseminated iron sulfides. Atmospheric entry heating of both particles is indicated by the partial iron oxide rim, vesicular sulfides, and the scatter of matrix compositions due to loss of Mg. While many uncertainties remain, the high incidence of chondritic rough particles, which include an unknown amount of CM-like particles, in the lower stratosphere during 1984, 1989, and 1991 suggests annual variations in their abundances. The timing of lower stratospheric dust samplings is critical to collect these particles.     

Investigation of carbon monoxide in heavy traffic intersections of municipal districts

In this research, an investigation of carbon monoxide in heavy traffic intersections of Kerman municipal districts in 2003–2004 has been performed. Kerman City is located at the south-eastern part of Iran. Carbon monoxide in highly toxic for human health and natural ecosystems in metropolition districts especially due to high traffic and industrial activities. For this reason, it was decided to investigate and find out the high concentration of CO pollutants in heavy traffic intersections of Kerman City. In this regards 21 heavy traffic squares and intersections were selected and the concentration of CO were measured. In the middle of each month during the year, sampling and measurement were scheduled three times at daily times according 7–12 a.m.; 12–16 and 16–20 p.m. In each period, 12 samples of 5 minutes were collected and CO concentration for 1-hr was calculated. The results obtained indicate that the hourly mean concentrations were lower than WHO guidelines and also lower than measurements of 1989, which has already done. In spite of more cases and higher populations, natural gas distribution was the cause of decline in CO concentrations.     

Prime controls on Archaean–Palaeoproterozoic sedimentation: Change over time

Although the principle of uniformitarianism may be applied to the Precambrian sedimentary record as a whole, certain periods of the Archaean and Palaeoproterozoic witnessed a changing pattern of prime influences controlling the depositional systems. This paper examines the major controls on sedimentation systems and environments during the Archaean and Palaeoproterozoic within the broader perspective of Earth evolution. Earth's earliest sedimentary system (4.4?-3.7 Ga) was presumably comprised of deep oceanic realms and probably influenced primarily by bolide impacts, major tsunamis, localized traction and global contour current patterns, and bathymetry. As continental crust began to form, the impact-dominated, tsunami type sedimentation gave way to wider varieties of sedimentary environments, known from the oldest sedimentary records. During early continental crustal evolution (c. 3.7–2.7 Ga), sedimentation was essentially of greenstone-type. Volcanic and volcaniclastic rocks were the major components of the greenstone belts, associated with thin carbonates, stromatolitic evaporites, BIF, pelites and quartzites and lesser synorogenic turbidites, conglomerates and sandstones. Volcanism and active tectonism (reflecting dynamic depositional settings during island arc and proto-continental nucleus formation) were the predominant factors influencing sedimentation during this phase of Earth evolution. Transgressions and regressions under the combined influence of tectonics and eustasy are reflected in fining- and coarsening-upwards successions from the proto-cratonic settings; low freeboard enabled the transgression to affect large areas of the proto-cratons. As the earliest, relatively stable craton formed, through a combination of plate tectonic and mantle-thermal processes, continents and supercontinents with the potential for supercontinental cycles started to influence sedimentation strongly. Major controls on Neoarchaean–Palaeoproterozoic sedimentation systems (2.7–1.6 Ga) were provided by a combination of superplume events and plate tectonics. Two global-scale ‘superevents’ at c. 2.7 Ga and c. 2.2–1.8 Ga were accompanied by eustatic rise concomitant with peaks in crustal growth rates, and large epeiric seas developed. The operation of first-order controls leading to development of vast chemical sedimentary platforms in these epeiric seas and concomitant palaeo-atmospheric and palaeo-oceanic evolution combined to provide a second-order control on global sedimentary systems in the Neoarchaean–Palaeoproterozoic period. The supercontinental cycle had become well established by the end of the Palaeoproterozoic, with the existence of large cratons across broad spectrums of palaeolatitude enabling erg development. The entire spectrum of sedimentary systems and environments came into existence by c. 1.8 Ga, prime influences on sedimentation and depositional system possibly remaining essentially uniform thereafter.     

Generation of correlated properties in heterogeneous porous media

The spatial distribution of rock properties in porous media, such as permeability and porosity, often is strongly variable. Therefore, these properties usefully may be considered as a random field. However, this variability is correlated frequently on length scales comparable to geological lengths (for example, scales of sand bodies or facies). To solve various engineering problems (for example, in the oil recovery process) numerical models of a porous medium often are used. A need exists then to understand correlated random fields and to generate them over discretized numerical grids. The paper describes the general mathematical methods required to do this, with one particular method (the nearest neighbor model) described in detail. How parameters of the mathematical model may be related to rock property statistics for the nearest neighbor model is shown. The method is described in detail in one, two, and three dimensions. Examples are given of how model parameters may be determined from real data.     

A SIMPLE SOIL MOISTURE INDEX TO FORECAST CROP YIELDS

Neutron probe soil moisture measurements obtained biweekly during the growing season between 1982 and 1991 from multiple depths under grass-covered plots at 17 Illinois Climate Network sites are used to forecast crop yields. A Soil Moisture Index (SMIX) that combines the effect of intensity, duration, and timing of drought or excessively wet conditions was computed by integrating the quantity of available soil moisture throughout the rooting zone over the growing season. Relationships between the SMIX values and crop yields are evaluated at county, regional, and statewide scales. Coefficients of determination (r ²) for relationships between the SMIX values and maize, soybeans, and hay yields at the statewide level are 0.88, 0.74, and 0.81, respectively, when the period of integration is terminated at the end of the growing season. This new soil index can be employed to forecast yields as early as 12 weeks before harvest for the state of Illinois. However, predictions with RMSE ≤ 10% of the mean yield can be achieved only for SMIX integration periods ending 5, 9, and 6 weeks before harvest for maize, soybeans, and hay, respectively. Nomograms are presented for using the relationships between the SMIX values and crop yields to forecast Illinois's major crops well before harvest.     

Hydrogen ionization and n=2 population for model spicules and prominences

Using slab model atmospheres that are irradiated from both sides by photospheric, chromospheric, and coronal radiation fields we have determined the ionization and excitation equilibrium for hydrogen.The model atom consists of two bound levels (n = 1 and n = 2) and a continuum. Ly- was assumed to be optically thick with the transition in detailed radiative balance. The Balmer continuum was assumed to be optically thin with the associated radiative ionization dominated by the photospheric radiation field (T _rad = 5940 K). The ionization equilibrium was determined from an exact treatment of the radiative transfer problem for the internally generated Ly-c field and the impressed chromospheric and coronal field (characterized by T _rad = 6500K).Our calculations corroborate the hypothesis that N₂, the n = 2 population density, is uniquely determined by the electron density N _e. We also present ionization curves for 6000K, 7500K, and 10000K models ranging in total hydrogen density from 1 × 10¹⁰/cm³ to 3 × 10¹²/cm³. Using these curves it is possible to obtain the total hydrogen density from the n = 2 population density in prominences and spicules.The National Center for Atmospheric Research is sponsored by the National Science Foundation.     

A study of the young open cluster NGC 6611

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