Noble-metal mineralization in the Semenov-2 hydrothermal field (13°31′N), mid-atlantic ridge

The porous fine-grained to microcrystalline copper-zinc ore of the Semenov-2 hydrothermal field, a site in the Semenov hydrothermal cluster discovered in 2007 (13°31′N, MAR), is anomalously enriched in Au (22–188 ppm) and Ag (127–1787 ppm). Chalcopyrite, isocubanite, würtzite, and opal are major minerals; sphalerite, marcasite, pyrite, and covellite are auxiliary; and galena, pyrrhotite, native gold, silver telluride, barite, and aragonite are sporadic. Gold containing 0.31 to 23.07 wt % Ag occurs as up to 9-μm-sized subhedral, dendritelike, and elongated grains mostly hosted in opal and less frequently in sphalerite and in pores within isocubanite-chalcopyrite aggregate. An elongated grain (2 × 4 μm in size) of the Ag-Te phase was found in a pore. So far only basalts have been dredged from the Semenov-2 field, but anomalous gold and silver concentrations suggest the influence of ultramafic rocks; the latter were found 1.5 km westward, in the Semenov-1 hydrothermal field. Mineral assemblage and morphology of gold particles indicate its primary origin in contrast to the hydrothermal fields hosted in basalts, where gold is a product of remobilization. Zonal gold grains, found on oceanic floor for the first time, are characterized by low Ag content in the cores and high Ag content in the outer rims, reflecting variation in formation conditions.     

3d transition metal L-edge X-ray absorption studies of the dichalcogenides of Fe, Co and Ni

The X-ray absorption spectra of the transition metal L_3,2-edges of the dichalcogenides FeS₂ (pyrite), FeSe₂, FeTe₂, CoS₂, CoSe₂, CoTe₂, NiS₂, NiSe₂ and NiTe₂ have been studied. These spectra are compared with theoretical simulations make using the atomic multiplet approach assuming on octahedral site for the metal atoms. The Ni spectra can be closely simulated using this approach but the Fe and Co spectra show less good fits to the experimental data. The reasons for this and its implications for the use of L-edge spectra in the study of such minerals are discussed in terms of the covalency and the ground states of the compounds; these results indicate the mixing of the ground states increases in the order Ni<Co<Fe.     

Catagenesis of organic matter at the top and base of the Jurassic complex in the West Siberian megabasin

Thermal maturation for the top and base of the Jurassic in the West Siberian megabasin was modeled on the basis of the vitrinite reflectance (R_vt⁰) data using mathematical modeling and computer simulations. The values of thermal maturation are found to vary within substages PC₃-MC₃² for the top (or being equivalent to PC₃-MC₁² on the periphery and southern part of the basin, or to MC₂-MC₃² in the north) and PC₃-AC₃ for the base of the Jurassic (or being equivalent to PC₃-MC₂ on the periphery and southern part of the basin or MC₃¹-AC₃ in the north). Thermal maturity levels of the Jurassic in West Siberia are controlled by depths of burial and peak temperatures which the source rocks were subjected to during this period. The situation is further complicated by high heat flows superimposed on the regional background, which are observed in deep fault zones and in the proximity of numerous igneous bodies.     

Weathering of ilmenite from Chavara deposit and its comparison with Manavalakurichi placer ilmenite,southwestern India

The magnetic fractions of ilmenite from the beach placer deposit of Chavara, southwest India have been studied for mineralogical and chemical composition to assess the range of their physical and chemical variations with weathering. Chavara deposit represents a highly weathered and relatively homogenous concentration. Significant variation in composition has been documented with alteration. The most magnetic of the fractions of ilmenite, separated at 0.15 Å, and with a susceptibility of 3.2 × 10^?6 m³ kg^?1, indicates the presence of haematite–ilmenite intergrowth. An iron-poor, titanium-rich component of the ilmenite ore has been identified from among the magnetic fractions of the Chavara ilmenite albeit with an undesirably high Nb₂O₅ (0.28%), Cr₂O₃ (0.23%) and Th (149 ppm) contents. The ilmenite from Chavara is compared with that from the nearby Manavalakurichi deposit of similar geological setting and provenance. The lower ferrous iron oxide (2.32–14.22%) and higher TiO₂ (56.31–66.45%) contents highlight the advanced state of alteration of Chavara. This is also evidenced by the relatively higher Fe³⁺/Fe²⁺ ratio compared to Manavalakurichi ilmenite. In fact, the ilmenite has significantly been converted to pseudorutile/leucoxene.     

Comparative Analysis of a Transition Region Bright Point with a Blinker and Coronal Bright Point Using Multiple EIS Emission Lines

Since their discovery 20 year ago, transition region bright points have never been observed spectroscopically. Bright point properties have not been compared with similar transition region and coronal structures. In this work we have investigated three transient quiet Sun brightenings including a transition region bright point (TR BP), a coronal bright point (CBP) and a blinker. We use time-series observations of the extreme-ultraviolet emission lines of a wide range of temperature T (logT=5.3?–?6.4) from the EUV Imaging Spectrometer (EIS) onboard the Hinode satellite. We present the EIS temperature maps and Doppler maps, which are compared with magnetograms from the Michelson Doppler Imager (MDI) onboard the SOHO satellite. Doppler velocities of the TR BP and blinker are ≤?25 km?s^?1, which is typical of transient TR phenomena. The Doppler velocities of the CBP were found to be ≤?20 km?s^?1 with exception of those measured at logT=6.2 where a distinct bi-directional jet is observed. From an EM loci analysis we find evidence of single and double isothermal components in the TR BP and CBP, respectively. TR BP and CBP loci curves are characterized by broad distributions suggesting the existence of unresolved structure. By comparing and contrasting the physical characteristics of the events we find that the BP phenomena are an indication of multi-scaled self-similarity, given the similarities in both their underlying magnetic field configuration and evolution in relation to EUV flux changes. In contrast, the blinker phenomena and the TR BP are sufficiently dissimilar in their observed properties as to constitute different event classes. Our work is an indication that the measurement of similar characteristics across multiple event types holds class-predictive power, and is a significant step towards automated solar atmospheric multi-class classification of unresolved transient EUV sources. Finally, the analysis performed here establishes a connection between solar quiet region CBPs and jets.     

Propagating Linear Waves in Convectively Unstable Stellar Models: A Perturbative Approach

Linear time-domain simulations of acoustic oscillations are unstable in the stellar convection zone. To overcome this problem it is customary to compute the oscillations of a stabilized background stellar model. The stabilization affects the result, however. Here we propose to use a perturbative approach (running the simulation twice) to approximately recover the acoustic wave field while preserving seismic reciprocity. To test the method we considered a 1D standard solar model. We found that the mode frequencies of the (unstable) standard solar model are well approximated by the perturbative approach within 1 μHz for low-degree modes with frequencies near 3 mHz. We also show that the perturbative approach is appropriate for correcting rotational-frequency kernels. Finally, we comment that the method can be generalized to wave propagation in 3D magnetized stellar interiors because the magnetic fields have stabilizing effects on convection.