The effect of low level supplementary heating on diving duration

The exothermic reaction which proceeds when small sachets containing particulate mixtures of iron and magnesium are flooded with sea water, has been used for thermal support of free divers. Initial application of such generators to heating of the hands (Burton and Chan, 1981), and later extension to heating of the torso, have been described previously (Chan and Burton, 1981, 1982). Of considerable interest during field trials of the torso heating system was a strong subjective impression among those taking part, that significant increases of dive duration and decreases of perceived discomfort could be obtained with relatively low levels of power generation, for example less than 50% of that required for thermal balance. In this paper, a simple mathematical model of human stored heat loss is used to rationalize this observation. Also it successfully predicts voluntary exposure times of unheated divers who become cold. When used to estimate body heat debt, the model enables documented dives by this laboratory and by others, including recent exposures in Antarctica using low level supplementary heating, to be analysed.     

Detection of the water-soluble fraction of crude oil by the blue crab, Callinectes sapidus

The ability of the blue crab, Callinectes sapidus, to detect petroleum hydrocarbons was measured with behavioural techniques. When presented with a water-soluble fraction of Prudhoe Bay crude oil, blue crabs abruptly changed antennular orientation, began rhythmic beating of the maxillipedal flagellae, and increased antennular flicking rate. The threshold concentration at which 50% of the crabs detected the water-soluble fraction was 2 × 10^?6 mg/litre. The blue crab apparently can readily detect petroleum hydrocarbons at concentrations found in chronically polluted areas as well as oil spill situations.     

Semisubmersible response to transient ice forces

The paper presents an analytical and experimental study on the transient response of semisubmersibles to bergybit impact and the strength of bergybit ice to high strain-rate loadings. Two approaches have been proposed for the solution of the semisubmersible-bergybit interaction problem, one using the energy approach and the other using the conventional structural dynamics approach with initial velocity conditions. In addition the local behaviour of the impacted regions have been analysed for deformation and failure. Numerical results have been given for local behaviour of an impacted column and global behaviour of semisubmersible-bergybit system. Experimental study has been reported on the impact strength of iceberg ice at strain rates of 10⁻³, 10⁻² and 10⁻¹; the indentation impact strength of ice is found to be 3–4 times the unaixial compressive strength, at the same strain rate.     

Distributions of dissolved and particulate biogenic thiols in the subartic Pacific Ocean

Dissolved and particulate concentrations of the biogenic thiols cysteine (Cys), arginine–cysteine (Arg–Cys), glutamine–cysteine (Gln–Cys), γ-glutamate–cysteine (γ-Glu–Cys) and glutathione (GSH) were measured in the subartic Pacific Ocean in the summer of 2003 using high performance liquid chromatography (HPLC) with precolumn derivatization as reported in previous work. In this study, a preconcentration protocol for the derivatized thiols was utilized to extend detection limits of dissolved thiols to picomolar levels. The measured concentrations of particulate and dissolved thiols were uncoupled, with distinctive depth profiles and large differences in the particulate to dissolved ratios between individual compounds. Glutathione was the most abundant particulate thiol whereas the most abundant dissolved thiol was γ-Glu–Cys, with concentrations as high as 15 nM. Given the relatively small pool of intracellular γ-Glu–Cys and the very low dissolved concentrations of GSH, we hypothesize that glutathione released from cells is rapidly converted to the potentially degradation resistant γ-Glu–Cys outside the cell. The relatively high concentrations of other dissolved thiols compared to particulate concentrations implies both biological exudation and slow degradation rates. Some thiols appear to vary with changes in nutrient availability but this effect is difficult to decouple from changes in community structure inferred from pigment analyses. Dissolved thiol concentrations also exceed typical metal concentrations in the subartic Pacific, supporting previous arguments that they may be important in metal speciation.     

Analysis of seawater for dissolved cadmium, copper and lead: An intercomparison of voltammetric and atomic absorption methods

An intercomparison study of voltammetric and atomic absorption spectrometric methods for determining cadmium, lead and copper in seawater samples was conducted. The voltammetric approach utilizes differential pulse anodic stripping voltammetry using a rotating, glassy carbon, mercury film electrode under conditions developed to minimize contamination sources and to enhance sensitivity for seawater matrices. The atomic absorption approach involves a concentration step using either an organic solvent extraction of metal dithiocarbamate chelates or a Chelex-100 column with detection by graphite furnace atomic absorption spectrometry. Similar and consistent results were obtained using both methods for the three trace metals studied on a wide range of natural seawater samples. Both methods are comparable in sensitivity for cadmium and copper, however the voltammetric method is better suited for the analysis of lead in seawater because of its enhanced sensitivity and low blank. An advantage of the voltammetric approach is its amenability towards real-time shipboard analysis.     

Bioerosion by chemosynthetic biological communities on Holocene submarine slide scars

Geomorphic, stratigraphic, and faunal observations of submarine slide scars that occur along the flanks of Monterey Canyon in 2.0–2.5 km water depths were made to identify the processes that continue to alter the surface of a submarine landslide scar after the initial slope failure. Deep-sea chemosynthetic biological communities and small caves are common on the sediment-free surfaces of the slide scars, especially along the headwall. The chemosynthetic organisms observed on slide scars in Monterey Canyon undergo a faunal succession based in part on their ability to maintain their access to the redox boundaries in the sediment on which they depend on as an energy source. By burrowing into the seafloor, these organisms are able to follow the retreating redox boundaries as geochemical re-equilibration occurs on the sole of the slide. As these organisms dig into the seafloor on the footwall, they often generate small caves and weaken the remaining seafloor. While chemosynthetic biological communities are typically used as indicators of fluid flow, these communities may be supported by methane and hydrogen sulfide that are diffusing out of the fresh seafloor exposed at the sole of the slide by the slope failure event. If so, these chemosynthetic biological communities may simply mark sites of recent seafloor exhumation, and are not reliable fluid seepage indicators.     

Seagrass landscape-scale changes in response to disturbance created by the dynamics of barrier-islands: A case study from Ria Formosa (Southern Portugal)

This study documents long-term changes of a Zostera noltii landscape induced by a natural cyclic event in a coastal lagoon. The barrier-islands forming this system are very dynamic with drifting movements controlling ecological patterns and processes occurring in this area. Changes in the areal extent of the Z. noltii meadows were assessed using historical aerial photographs from 1940, 1980, 1989, 1996 and 1998. Landscape indices such as total patch area (TA), mean patch size (MPS), number of patches (NP), mean shape coefficient of variation (CV) and landscape fractal dimension (D) were calculated for each year and related to an index of disturbance intensity. The spatial distribution of the Z. noltii meadows varied greatly during the studied period and changes observed were related to the disturbance created by the barrier-islands' spatial dynamics. After an artificial inlet relocation the Z. noltii area, number of patches, patch mean size and coefficient of variation decreased. The fractal dimension of the Z. noltii landscape increased by 50% showing that besides a decrease in total area, number of patches, and patch mean area, patch fragmentation was an important consequence of this anthropogenic disturbance.Seagrass natural distribution patterns changed in response to natural and human-induced activities. This study emphasizes the importance of the landscape approach and the historical perspective when studying seagrass changes and the importance of taking into consideration long-term changes in seagrass landscapes to avoid confusion between man-induced effects with natural cyclic events.