Effects of chemical environment on the solubility and incorporation mechanism for hydrogen in olivine

To investigate the solubility and the sites of incorporation of hydrogen in olivine as a function of point defect concentration, two-stage high-temperature annealing experiments have been carried out. The first annealing stage (the dry preannealing stage) was conducted at a total pressure of 0.1 MPa, a temperature of 1300° C and various oxygen fugacities in the range 10^?11–10^?4 MPa for times > 12 h. In these heat treatments, the samples were buffered against either orthopyroxene or magnesiowustite, or they remained unbuffered. The second annealing stage (the hydrothermal annealing stage) was performed at 300 MPa and 900–1050 ° C under a hydrogen fugacity of ～ 158 MPa for 1–5 h. Infrared spectra from the annealed samples revealed two distinct groups of bands. Group I bands occurred at wavenumbers in the range 3450–3650 cm^?1, while Group II bands occurred in the range 3200–3450 cm^?1. The hydrogen solubility associated with Group I bands is proportional to f _{O 2} to the 1/6 power for samples preannealed in contact with orthopyroxene, to the 1/3 power for samples preannealed in contact with magnesiowustite, and to the 1/13 power for samples preannealed in the absence of a solid-state buffer. The hydrogen concentration for Group II bands varies with f _{o 2} to the 1/3 power for opxbuffered samples, to the 1/2 power for mw-buffered samples, and to the 1/3 power for unbuffered samples. The dependence of hydrogen solubility on oxygen fugacity and orthopyroxene activity suggests that hydrogen is incorporated into the olivine structure via association with point defects. The presence of two distinct groups of absorption bands indicates that hydrogen is associated with two distinct lattice defects. The following point defect model for the mechanism of incorporation of hydrogen in olivine is consistent with these results: Hydrogen ions responsible for the Group I bands are associated with doubly charged oxygen interstitials, while hydrogen ions responsible for the Group II bands are associated with singly charged oxygen interstitials. Furthermore, the infrared bands observed in naturally derived olivines are present in spectra from our hydrothermally annealed crystals. Thus, the mechanisms of incorporation of hydrogen in olivine under geological conditions are the same as those operative under laboratory conditions. The maximum solubility reached in these experiments was ～ 360H/10⁶Si, which corresponds to ～ 0.002 wt% of H₂O. This value is a lower bound for the solubility of hydrogen in olivine under upper mantle conditions.     

The typing of Au and base-metal occurrences by plasma/mass spectrometry: initial results

This paper discusses the application of the newly developed ELAN 250 I.C.P./mass spectrometer to exploration geochemistry. This instrument combines an inductively coupled plasma with a quadrupole mass spectrometer. The combination of these two existing technologies makes it possible for the first time to perform stable-isotope and elemental analysis rapidly and concurrently.Particular attention is paid to the use of lead isotopes to type Au and base-metal occurrences. Data are presented on galena samples obtained from the Geological Survey of Canada and the Royal Ontario Museum. Consideration is also given to the potential usefulness of Pb isotopes and trace-element data to type mineral occurrences and to identify new ones.     

1904～1907年拉萨气候特征再分析

通过对以《有泰拉萨天气日志》为主的历史文献资料的深入挖掘 ,作者分析了 1 90 4年 2月 9日～ 1 90 7年 4月 1 7日拉萨的气候特征 :气候温暖 ,暖冬现象显著 ,而且 1 90 5年气温高于 1 90 4年 ;干旱气候占主导地位 ,间有多雨期 ;天气多变 ,多风 ,有雾 ;水灾、雪灾、干旱等自然灾害严重。拉萨与全球同时段的气候变化大体一致。     

新疆阿尔泰山南缘产于麦兹泥盆纪火山-沉积盆地铅锌矿床稳定同位素特征

麦兹火山-沉积盆地内铅锌矿呈似层状、透镜状,矿石构造以条纹条带状、块状、斑杂状为主,矿物成分相对简单,矿体直接容矿围岩为火山-沉积岩.矿床δ34S值为-20.6‰～-10‰;矿床石英流体包裹体水的δD值为-89.1‰～-49.48‰,δ18OSMOW值为4.7‰～1.2‰.矿化层中方解石的δ13C值介于-6.7‰～-14.3‰之间,δ18O值在10.3‰～12.9‰之间.矿床属火山-沉积岩容矿的块状硫化物矿床,介于典型的火山岩容矿的块状硫化物型矿床(VHMS)和典型沉积岩容矿的硫化物矿床(SEDEX型)之间的过渡类型(一种新类型块状硫化物矿床).     

利用GPS技术遥感大气对流层水汽含量的研究

讨论了利用 GPS系统探测大气对流层水汽含量的原理和数学模型 ,对利用 GPS遥感大气对流层水汽的加权平均温度、水汽含量随时间的变化等一些关键问题进行了探讨。通过对我国沿海地区大连、青岛、闸坡、坎门、厦门 5个测站的实验数据的解算 ,获得了较为满意的结果。     

甘肃北山造山带类型及基本特征

北山造山带经历多期次、多阶段的板块裂解－俯冲－碰撞－拼合的复杂地质演化历程，具多旋回复合造山的特色。通过对造山带构造单元的建立、古板块重建、原型盆地恢复、造山带结构、构造特征及造山机制和模式的研究，确定北山造山带类型为陆－增生弧碰撞造山带。     

论我省矿业发展的后发优势—兼论矿业对全省经济跨越式发展的作用

吉林省是我国非金属矿产资源较丰富的大省之一，矿泉水资源也质优量大，且具有竞争优势，开发利用率极为可观。本文从非金属的深细加工、尾矿利用，矿业结构调整以及矿泉水的开发规模等方面探讨了利用我省的资源发展地方经济的后发优势等问题。     

西扬子大陆区泥盆纪沉积演化与成矿

西扬子大陆区泥盆系因有丰富的矿产资源一直为地学界所关注.在泥盆纪盆地演化中,地质事件与成矿关系极为密切.盆地沉积类型有台地型和海槽型两种.台地型泥盆系在沉积建造、生物群落、地质事件及沉积矿产等多方面均能与中、下扬子区相对比,故归属南方区扬子型泥盆系;海槽型泥盆系与台地型泥盆系在时空上均紧密衔接,但成矿作用有明显差别.海槽型泥盆系多产出层控型金和多金属矿床,台地型则以沉积矿床为主.     

煤岩及煤岩加不同介质的热模拟地球化学实验--气态和液态产物的产率以及演化特征

对塔里木盆地侏罗系煤岩以及煤岩加不同介质等 4个系列以 50℃为一温阶,从 250～550℃进行热模拟实验,并对其气体产物、液态有机质进行了系统分析。结果表明:煤岩成烃过程是一个综合作用的过程,它的生气、生油与外界环境如水,粘土矿物等的辅助作用有关。随着热模拟温度的升高,各产气率呈增长趋势。介质的加入可降低有机质成烃温度,有利于液态物的产出。     

数字式智能化锚索预应力传感器的研究与设计

预应力传感器是锚固工程，预应力混凝土工程，预应力桥梁工程等领域进行监测，研究与试验必不可少的测量用传感器，在分析预应力传感器[研究现状的基础上，详细了介绍了数字式智能化锚索预应力传感器的工作原理，结论设计，计量检定结果，主要特点和应用情况。