江西东乡铜矿床成因:铜和硫同位素联合约束

东乡铜矿床的赋矿岩石以石炭系砂岩和燕山期花岗斑岩为主。文章对东乡铜矿床同位素地球化学进行了研究,探讨了成矿物质来源及矿床成因。东乡矿区块状矿石和花岗斑岩的黄铁矿δ~(34)S值(0.3‰~1.2‰)非常接近深部地幔硫的值,其δ~(34)S值呈现明显的塔式分布,分布范围较窄,表明矿石中的硫主要来自深源岩浆。δ~(65)Cu值分布范围较窄(-2.10‰~0.17‰),整体接近于零附近,明显不同于块状硫化物矿床(δ~(65)Cu=-0.98‰~3.14‰)、矽卡岩型矿床(δ~(65)Cu=-1.29‰~2.98‰)和热液脉型矿床中δ~(65)Cu值(-3.70‰~0.44‰)的分布范围,其δ~(65)Cu值变化范围大于岩浆矿床的δ~(65)Cu值(-0.62‰~0.40‰),更接近于斑岩型矿床的δ~(65)Cu值(-1.16‰~0.81‰),表明东乡铜矿与岩浆热液作用具有密切的成因联系。因此,推断东乡铜矿为岩浆热液型矿床。     

新疆东天山突出山铜铁矿床地球化学特征与地质意义

突出山铜铁矿床是东天山雅满苏石炭纪弧前-岛弧带中代表性的铁多金属矿床, 矿体呈透镜状、脉状、似层状赋存于上石炭统底坎尔组下亚组火山岩中。矽卡岩阶段包裹体均一温度为151℃~>380℃, 盐度为1.91%~23.18% NaCl_eq, 密度为0.76~1.09 g/cm³, 热液硫化物阶段包裹体均一温度为101℃~280℃, 盐度为0.35%~23.05% NaCl_eq, 密度为0.74~1.13 g/cm³, 表明成矿流体属于中-高温、中-低盐度、中-低密度的NaCl-H₂O体系。(绿泥石)绿帘石矽卡岩、磁铁矿(镜铁矿)矿石、含磁铁矿灰岩的稀土配分模式均为轻稀土相对富集的右倾型(LREE/HREE=2.85~9.21), 以出现负铕异常(δEu=0.22~1.09)和铈异常不发育为特征, 与底坎尔组火山岩相似, 表明成矿物质来源于底坎尔组火山岩。矿区矽卡岩可能是火山热液交代碳酸盐岩形成的, 成矿条件为中-高温、较为宽广的氧化还原环境, 矿床成因属火山热液交代型。     

Early J2 basalts in SE China: Incipience of large-scale late Mesozoic magmatism

Magmatism in SE China was dormant during 204–180 Ma, but was reactivated in 180–170 Ma (early J₂), and then became more and more intensive towards the end of early Cretaceous. The small-scale early J₂ magmatism is the incipience to long-term and large-scale magmatism in this region. A near east-west (EW) trend volcanic belt was distributed across south Hunan, south Jiangxi and southwest Fujian was formed during early J₂ time. Along this belt from the inland toward the coast, the lithology of basalts changes from alkali into tholeiite, and the amount of erupted volcanic rocks and the proportions of rhyolites coexisting with the basalts increase. On the basis of geochemical characteristics of these basalts, we infer that the melting degree of source rocks and the extent of fractional crystallization and crustal contamination all increased whereas the depth of mantle source decreased from the inland to the coast, which led to the variations of geological characteristics of the volcanic belt. In early J₂, the western spreading Pacific plate began to subduct underneath SE China continental block, reactivating near EW trend deep fault that was originally formed during the Indosinian event. The stress of the western spreading Pacific plate and the extent of asthenosphere upwelling increased from the inland to the coast, which is consistent with the generation and evolution of early J₂ basalts.     

攀西红格钒钛磁铁矿矿田富钴硫化物中钴的地球化学特征及其地质意义

攀西红格钒钛磁铁矿矿田白草矿区发育富钴硫化物矿物,关于其成因和形成环境方面的研究较为薄弱。本文采用矿物学、矿物化学、地球化学等方法对其进行系统研究。矿石中主要富钴硫化物为磁黄铁矿（Po）、黄铁矿（Py）、镍黄铁矿（Pn）、硫钴镍矿（Se）。磁黄铁矿Co、Ni平均质量分数分别为0.21%、0.42%,Co/Ni平均值为1.10;黄铁矿Co、Ni平均质量分数分别为0.18%、0.29%,Co/Ni平均值为0.77;镍黄铁矿Co、Ni平均质量分数分别为2.67%、34.30%,Ni/Fe平均值为1.08、S/Fe平均值为1.91、M/S^#平均值为1.13;硫钴镍矿Co、Ni平均质量分数分别为24.30%、22.90%,Co/Ni平均值为1.06。根据Po-Py矿物温度计,白草矿区富钴硫化物结晶温度在267~490℃之间,表明其形成于中高温的条件。通过与地幔包体镍黄铁矿S/Fe、M/S^#特征值的对比,结合磁黄铁矿具有陨硫铁（Tr）同质多象晶体的特征,认为白草矿区硫化物具有地幔源的特征,说明成矿物质来源于地幔。白草矿区钴地球化学特征研究表明,在硫化物熔体分离过程中,钴迁移至单硫化物固溶体形成Po-Py固溶体,再由Po-Py固溶体中迁移至Pn、Se,形成了Se、Pn、Po-Py、Ccp（黄铜矿）中Co质量分数依次递减的现象。     

哈达门沟金矿床成岩成矿时代的定点定年研究

哈达门沟大型钾长石 -石英脉型金矿床位于华北地台北缘西段的乌拉山地区。矿区西部的大桦背花岗岩和矿区内的伟晶岩脉与金矿化均具有较为密切的空间关系 ,这导致不少研究者认为哈达门沟金矿床与大桦背岩体或伟晶岩之间也具有时间和成因联系。通过采用先进的高灵敏的高分辨率的离子探针 (SHRIMP)对大桦背岩体、伟晶岩脉和钾长石化蚀变岩进行的锆石 U- Pb定点定年研究表明 :伟晶岩脉形成于 (1836± 5)× 10 6a,属吕梁旋回 ;大桦背岩体形成于 (353± 7)× 10 6a,应为海西旋回早期产物 ;金矿化年龄小于或等于 (132± 2 )× 10 6a,应为燕山晚期。这些年龄结果说明 ,本区金矿化比大桦背岩体晚至少 2 2 0× 10 6a,这排除了金矿化与大桦背岩体和伟晶岩脉之间有任何成因联系的可能性。蚀变岩的年龄还证明 ,虽然乌拉山和胶东地区金矿床的围岩和年龄不同 ,但两地区的金矿化却几乎同时发生。此外 ,大桦背岩体的形成年龄与华北地块和蒙古古陆块碰撞作用发生的时间基本一致 ,因此大桦背岩体的 SHRIMP年龄为这一碰撞作用提供了可靠的年代学证据。     

辉钼矿Re-Os同位素定年方法的改进与应用

公认的Re-Os同位素定年代表物辉钼矿,目前已在金属硫化物矿床年代学研究领域获得了广泛的应用。本研究采用浓HNO₃分解辉钼矿样品,大大地简化了Re和Os的化学制备过程,并根据辉钼矿中正常Os含量水平相对放射成因¹⁸⁷Os可以忽略的特点,以正常Os标准为稀释剂,实现了仪器测量过程中Os同位素质量分馏的在线校正,改善了分析数据的质量。该方法经辉钼矿国家标准物质进行验证,获得了满意的Re、Os含量及Re-Os年龄数据,并且在南岭地区与连阳复式岩体相关的姓坪夕卡岩型钼矿床成矿年龄研究中获得了成功应用。在实际应用中,为了获得有意义的能反映真实地质事件的年龄数据,辉钼矿样品不仅要有足够的取样量,而且还要保证粒度细、混合均匀。     

2019年12月26日湖北应城M4.9地震震源参数及余震活动性研究

2019年12月26日湖北应城发生M4.9有感地震,其震感波及武汉大部分地区。为了分析该地震的发震构造及余震活动性,本文利用波形拟合方法测定了不同速度模型下该地震的震源机制解和矩心深度,并用Bootstrapping抽样反演技术评价反演结果;此外,利用模板匹配技术匹配主震和目录余震波形,获取了更为完整的余震目录。结果显示,应城地震以走滑为主,矩心深度7.5km左右,矩震级M_W4.67;应城地震有1个前震和17个余震,余震序列缺少M2~4事件,表明应城地震为孤立型地震,M2以下地震的b值为0.8。     

塔里木盆地多期改造-晚期定型复合构造与油气战略选区

受关键构造变革期制约,叠合盆地具有分期差异变形特征。从变形角度分析,塔里木盆地可以追溯出5期主要的构造改造作用,即加里东中期、加里东晚期-海西早期、海西晚期、印支-燕山期和喜马拉雅期,并影响塔里木盆地的发展演化历史。通过对塔北、塔中和库车已知油气聚集区解剖表明:古生代多期改造形成的断裂、褶皱、隆升、剥蚀和岩溶作用,对台盆区巨型海相碳酸盐岩古岩溶油气藏的形成具有重要的控制作用;中、新生代多期改造过程,对前陆褶皱-冲断带大规模油气聚集成藏具有重要的控制作用;这些已知油气聚集区带都是在喜马拉雅晚期最终定型的,总体构成多期改造-晚期定型复合构造油气聚集模式。综合分析了塔里木新区分期差异构造变形特征,在此基础上,依据叠合盆地多期改造-晚期定型构造模式,对塔里木新区进行了区块评价和油气战略选区,认为巴楚隆起、麦盖提斜坡和西昆仑山前褶皱-冲断带是近期油气勘探突破的首选地区,塔东地区、塘古巴斯坳陷和阿瓦提断陷具有良好的油气勘探前景。     

Zircon M127 – A Homogeneous Reference Material for SIMS U–Pb Geochronology Combined with Hafnium,Oxygen and,Potentially, Lithium Isotope Analysis

In this article, we document a detailed analytical characterisation of zircon M127, a homogeneous 12.7 carat gemstone from Ratnapura, Sri Lanka. Zircon M127 has TIMS‐determined mean U–Pb radiogenic isotopic ratios of 0.084743 ± 0.000027 for ²⁰⁶Pb/²³⁸U and 0.67676 ± 0.00023 for ²⁰⁷Pb/²³⁵U (weighted means, 2s uncertainties). Its ²⁰⁶Pb/²³⁸U age of 524.36 ± 0.16 Ma (95% confidence uncertainty) is concordant within the uncertainties of decay constants. The δ¹⁸O value (determined by laser fluorination) is 8.26 ± 0.06‰ VSMOW (2s), and the mean ¹⁷⁶Hf/¹⁷⁷Hf ratio (determined by solution ICP‐MS) is 0.282396 ± 0.000004 (2s). The SIMS‐determined δ⁷Li value is ?0.6 ± 0.9‰ (2s), with a mean mass fraction of 1.0 ± 0.1 μg g^?1 Li (2s). Zircon M127 contains ~ 923 μg g^?1 U. The moderate degree of radiation damage corresponds well with the time‐integrated self‐irradiation dose of 1.82 × 10¹⁸ alpha events per gram. This observation, and the (U–Th)/He age of 426 ± 7 Ma (2s), which is typical of unheated Sri Lankan zircon, enable us to exclude any thermal treatment. Zircon M127 is proposed as a reference material for the determination of zircon U–Pb ages by means of SIMS in combination with hafnium and stable isotope (oxygen and potentially also lithium) determination.     

Absorption properties of urban/suburban aerosols in China

The broadband diffuse radiation method is improved to retrieve the aerosol refractive index imaginary part （AIP） and broadband （400-1000 nm mean） single scattering albedo （SSA）. In this method, four sets of SSA selection criteria are proposed for quality control. The method is used to retrieve AIP, SSA and absorptive optical thickness （AbOT） from routine hourly-exposed pyrheliometer and paranometer measurements over 11 sites （meteorological observatories） in China during 1998-2003. Apart from one suburban site （Ejin Qi）, the other urban sites are all located around big or medium cities. As shown in the retrieval results, annual mean SSA during 1998-2003 changes from 0.941 （Wuhan） to 0.849 （Lanzhou）, and AIP from 0.0054 to 0.0203. The 11-site average annual mean SSA and AIP are 0.898 and 0.0119, respectively. SSA during winter is smaller for most sites. There is an evidently positive correlation between SSA and aerosol optical thickness （AOT） for all sites. There is also a positive correlation between SSA and relative humidity for most sites, but a negative correlation for a few sites, such as Kashi and ǚrǚmqi in Northwest China.