地质样品正构烷烃组分分离纯化的部分问题探究

用实验室自配的标准正构烷烃样品分别经硅胶或氧化铝柱层析后发现,等量溶剂洗脱的情况下硅胶对长链正构烷烃无吸附而氧化铝具有一定吸附性。进一步通过用植物样品测试4种层析柱填充方法,发现不论是只用氧化铝填充还是上部硅胶下部氧化铝和上部氧化铝下部硅胶,都会对长链正构烷烃产生一定的吸附,且这种吸附效果随着碳链的增长而增强。在实验条件下,当碳链加长到C36时,用硅胶加氧化铝填充层析柱的吸附量已达到20%左右,而只用氧化铝填充层析柱的吸附量则高达50%。故建议对研究高碳数正构烷烃的地质样品组分提取时用单一的硅胶柱层析方法。同时,实验显示对于一些杂质多的正构烷烃样品经过尿素络合后比络合前"干净"得多。18个黄土-古土壤和植物样品平均回收率为50%左右,经过尿素络合后的样品正构烷烃各组分相对含量基本不会发生改变,也不会产生明显的同位素分馏效应。因此在进行非正构组分干扰较大的正构烷烃各组分相对含量或同位素分析时,可以选择尿素络合的方法来将其纯化。     

Effect of plant life form on relationship between δD values of leaf wax n-alkanes and altitude along Mount Taibai, China

We present δD_wax values from different forms of plants and soils, and δD_sw values from soil water along the northern slope of Mount Taibai, China. The results show a highly negative linear correlation of the δD_wax values for soils with altitude (R² 0.74) and we observed the same correlation for δD_sw values of soil water with altitude (R² 0.68). The δD_wax of living plants behaves like the soil, but does not exhibit a significant linear correlation with altitude (R² 0.11). The δD_wax values of woody plants and grasses also show a similar trend with respect to altitude with significant and no linear correlation, respectively (R² 0.50 for woody plants and 0.17 for grass), which suggest that the “altitude effect” can not be well documented for the δD_wax values of living plants, which may be due to differences in plant type and/or evapotranspiration controlled by the plant microclimate. The ε_wax-sw values of woody plants, grasses and soil show minor fluctuations with altitude. However, the ε_wax-sw and δD_wax values of woody plants are roughly 51‰ and 50‰ more positive, respectively, than those of grasses, suggesting that an “altitude effect” could be documented in the δD_wax of woody plants and grasses, with each responding independently to changes in precipitation along the altitude transect. Additionally, the ε_wax-sw values of soil are relatively constant with altitude, suggesting that the altitudinal change in the proportions between woody plant and grass input to soils will likely change the relationship between the δD_wax values of soil n-alkanes and altitude.     

煤矿三维地震勘探技术发展趋势

我国煤田三维地震勘探经过20余年的发展,已成为当前煤田地质勘探的主流技术,随着煤矿采掘现代化及安全保障系统对勘探精度要求的提高,三维地震勘探技术也须与之相适应,不断地探索与发展。参考近年来相关研究成果与勘探实例,对可在煤田地质勘探中大面积推广应用的三维地震勘探技术进行了介绍,其中包括：高密度空间采样、数字检波器、高精度静校正技术、叠前时间（深度）偏移技术、分频解释技术、波阻抗反演技术、相干体技术,同时也简要介绍了在煤田勘探方面有发展前景的多分量及各向异性技术。     

紫菜特征挥发性物质分析

应用顶空固相微萃取和气相色谱-质谱联用技术,对坛紫菜(Porphyra haitanensis)、条斑紫菜(Porphyra yezoensis)与其一个突变品系的生长藻体挥发性物质进行分析,共分离鉴定出66种挥发性组分,3个紫菜试样中分别含有36、44和45种.鉴定组分中有21种为紫菜共有挥发性物质,其中8-十七烯和...     

Characteristics of inorganic ions in precipitation at different altitudes in the Yulong Snow Mountain, China

The present study investigated the chemical composition of summer precipitation at different altitudes in Yulong Snow Mountain, hoping to obtain some basic information about the chemical characteristics of precipitation. A couple of precipitation samples at different altitudes in the Yulong Snow Mountain area in southeastern China were collected from July 26 to July 31, 2005 for chemical analyses. Sea-salt tracer analysis showed that Cl^? and Na⁺ had high proportion from marine sources, while the other ions mainly were from non-marine sources. Statistics showed that the cation concentrations ranged from 0.51 to 5.26 mg L^?1 and anion concentrations ranged from 0.99 to 4.90 mg L^?1. Further analysis showed that terrestrial ions, especially from the proximal terrestrial sources, largely affected the ion concentrations in precipitation. Ion concentrations of precipitation were correlated significantly with local atmospheric circulation at altitude 2,950–4,800 m, and also correlated closely with human activities at altitude 2,400–2,950 m. Limestone, the majority of local rocks, caused high cation concentrations in precipitation, such as Ca²⁺ and Mg²⁺. The majority of vapors in the region came from the Indian Ocean whereas parts came from the eastern Pacific. The inorganic ions in precipitation increased significantly in the Yulong Snow Mountain area during this century. Compared with most of the high altitude Mountains in China, the precipitations in the Yulong Snow Mountain area had higher concentrations of inorganic ions and low acidic ion concentrations. The conclusions can provide a basis for study of regional climate characteristics, environment and ecological characteristics of Yulong Snow Mountain area.     

重型动力触探在振冲施工质量控制及检测中的应用

振冲复合地基以其低成本、高效率等优势已经广泛的应用于水利水电、火电、工民建、石化、交通、市政、铁路等行业的地基处理中。振冲进行地基处理的规模和速度日新月异,使得施工过程中的质量控制变得非常重要。通过对重型动力触探在振冲碎石桩工程中的应用,论述了重型动力触探在振冲施工质量控制及检测中的重要性及适用性,并总结了其在工程中的应用经验。     

新疆准噶尔盆地西北缘晚泥盆世法门期地层之划分

新疆准噶尔沙尔布尔提山及其附近地区是中国准噶尔-兴安地层区上泥盆统及下石炭统发育的代表地区,其中和布克河中游东岸（萨尔巴根德山地区）是过去受到广泛关注的和布克河组建组典型地区,但因构造改造强烈,导致和布克河组原剖面的描述出现多种问题,其层序及与洪古勒楞组的关系长期以来有着不同的意见。经过多年的野外工作,文中建立了萨尔巴根德山地区法门阶的层序,鉴于该地区的层序与布龙果尔剖面基本相似,认为取消和布克河组的名称,而代之统一使用洪古勒楞组是合理的。萨尔巴根德山地区的法门阶地层由洪古勒楞组及黑山头组（下部）组成,其中洪古勒楞组含弓石燕类等腕足动物及“Cyrtoclymenia”、Platyclymenia等菊石,自下而上可划分为5段（均为新名称）：(1)萨尔巴段以大套灰岩为特征;(2)龙口段以大套灰绿色砂岩、砾岩、粉砂岩为特征;(3)杜古尔段以泥质灰岩及泥灰岩为特征;(4) 乌兰段以紫红色疙瘩状砂质灰岩、紫红色及灰绿色硅质粉砂岩、硅质泥岩为特征;(5)查斯段以灰色钙质砂岩钙质粉砂岩至砂质灰岩为特征。上覆黑山头组（下部）以深灰色硅质粉砂岩、硅质泥岩、硅质岩、细砂岩、紫红色粉砂质、硅质泥页岩为特征,含腕足类Syringothyris Spirifer腕足动物群及Cymaclymenia等菊石,属泥盆系顶部层位。     

Active phase of a substorm as a chain of two types of reconnection: In the closed plasma sheet and in the open tail lobes

The maps of the field-aligned current (FAC) density distribution in the ionosphere obtained by the TIM-2 magnetogram inversion technique are used to investigate the August 27, 2001 substorm. The open magnetic flux Ψ and intensity J of the substorm current wedge (SCW) have been determined with a step of 1–5 min. The substorm onsets are divided into two types, PSR (plasma sheet reconnection) and TLR (tail lobe reconnection). The fast expansion tailward of the PSR region is described as the transition from PSR to PSR+TLR. Assuming that the SCW FACs flow down into the ionosphere from the edges of the disruption region of the cross-tail dawn-dusk current, several parameters of the disruption region have been estimated. The disrupted magnetic field has been found to be ∼5% of the undisrupted one for PSR and ∼95% for PSR+TLR. The disturbance power Q for PSR is an order of magnitude lower than that for PSR+TLR. The abrupt growth of Q during the transition from PSR to PSR+TLR is observed over the entire SCW area from its near-Earth part to the midtail and distant tail.     

Molecular fossil and paleovegetation records of paleosol S4 and adjacent loess layers in the Luochuan loess section, NW China

Using gas chromatography-mass spectrometry (GC-MS) technique, a series of biomarkers were identi- fied, including n-alkanes, n-alkane-2-ones, isoprenoid etc. from the loess-paleosol samples collected from the S4 and adjacent L5, L4 of the Luochuan loess section, Northwestern China. Based on these data, especially n-alkanes and high-resolution magnetic susceptibility and grain size data, the pa- leoenvironment and paleovegetation history during S4 was reconstructed. The CPI (Carbon Predomi- nance Index) and correlation between n-alkanes and magnetic susceptibility and grain size data dem- onstrated that the molecular fossils in paleosol and loess layers can reflect the vegetation condition during the loess-paleosol formation, if the allochthonous organic inputs could be excluded reasonably. The ACL (average chain length) index is correlated well with paleomagnetic susceptibility and grain size variations, displaying their good synchrony with warm and humid climate. However, it relatively lagged behind the paleomagnetic susceptibility and the grain size variations when the climate began to deteriorate. During the formation period of paleosol, the n-alkanes was dominated by C31 homologue, indicating that the primary organic input originated from herbs. Our study also demonstrated that the herbs were more flourish than wood plants in Loess Plateau, especially in the Luochuan area during the warm and humid phase, and there was no typical forest vegetation developed in the studied period.     

Compositional characteristics of <Emphasis Type="Italic">n</Emphasis>-alkanes of the glaciers over the Tibetan Plateau and their environmental and climatic significances

We report on the concentration and compositional features of n-alkanes of natural and anthropogenic origins in the snow samples collected from the Qiyi glacier in the Qilian Mountains, the Yuzhufeng glacier in eastern Kunlun Mountains, the Xiaodongkemadi glacier in the Tanggula Mountains, and the Gurenhekou glacier in the Nyainqêntanglha Range. The results indicate a decrease in the total n-alkane concentration (T-HCs) from the northeast to the south over the Tibetan Plateau. The T-HCs in these studied areas were close to those in the Belukha and Sofiyskiy glacier, Russian Alati Mountains and the Dasuopu glacier in the Himalaya but were much higher than those in the Greenland ice sheet, suggesting that the mountain glaciers in the Asian continent may receive a higher loading of n-alkanes than the Greenland ice core. Moreover, the compositional characteristics of n-alkanes indicated that the n-alkanes in the studied areas were probably originated from the plant waxes as well as the fossil-fuel combustion exhaust, whereas the contribution from the lower organisms was small. In addition, the plant wax (C_n(wax)) and anthropogenic (non-C_n(wax)) contributions revealed that fast industrialization may have significant effects on the organic pollutant composition in glacier over the Tibetan Plateau and its circumference environment. Particularly, except for the Yuzhufeng glacier, the ΣnC₂₁ ⁻/ΣnC₂₂ ⁺ and (nC₁₅+nC₁₇+nC₁₉)/(nC₂₇+nC₂₉+nC₃₁) ratio decreased from the Qiyi glacier to the Gurenhekou glacier over the Tibetan Plateau, while the carbon preference index (CPI) values increased. These results indicate a decrease in terrigenous input while an increase in marine input from the northeast to the south over the Tibetan Plateau. These two ratios can be used as the climatic and environmental change indicators.