The Berriedale Limestone contains mostly bryozoans, brachiopods and bivalves, with some intraclasts and rare pellets. The faunal diversity is low and the fauna are similar to the modern cold-water foramol faunal assemblage. Micrite, microspar and spar occur as equant to well developed rhombs of calcite. The coarse spar cements are bored and are ruptured by dropstones, indicating submarine origin of low-Mg calcite at water-temperatures of around 3°C. The mixing zone cementation was preceded by erosion of early formed crystals. The eroded crystals occur as inclusions in mixing zone cements.
The fauna are characterized by heavy δ13C and light δ18O. The whole-rock field of δ18O-δ13C falls at the edge of “Normal Marine Limestone” and deviates to lighter δ18O values (down to −16.7‰ PDB). Lightest δ18O values ( −22‰ PDB) of fresh-water sparry calcite cement are similar to those in the Early Permian continental tillites, suggesting that the Permian sea was diluted by isotopically light melt waters. Micrite δ18O values (−9.2 to −12.6‰ PDB) are within the range of whole-rock values. The δ18O values of calcite in shales are lighter than limestone values.
The δ18O values of the fauna give an unrealistic range of sea-water temperatures because the fauna have equilibrated with variable amounts of melt waters. However, calculated original δ18O values of the fauna indicate temperatures < 4°C. The heaviest δ18O of fauna gives cold temperatures of 9°C (with δw −2.8‰) and −3°C (with δw −6‰). The lightest values of sparry calcite cements (−22‰ PDB) indicate that the limestone reacted with cold melt waters.
The δ18O of Permian sea is estimated to be about +1.2‰ and was diluted by melt waters as light as −27‰ SMOW. 相似文献