The Zn abundance and isotopic composition of diatom frustules,a proxy for Zn availability in ocean surface seawater

We have developed cleaning methods for extracting diatomopal from bulk marine sediment samples, for measurement of both zinc (Zn) abundance and isotope composition. This cleaning technique was then applied to a set of Holocene core-top samples from the Southern Ocean. The measured δ⁶⁶Zn (reported relative to the JMC_Lyon standard) and Zn/Si ratios from the Southern Ocean diatom_opal samples range from 0.7 to 1.5‰, and from 14 to 0.9 μmol/mol, respectively. The Zn abundance and isotope composition data show a clear correlation with opal burial rates and other oceanographic parameters. In common with previous work, we interpret the systematic changes in the Zn/Si ratio to be linked to the variability in the concentrations of bioavailable Zn in the ambient surface seawater where the diatom opal is formed. This variability is likely to be primarily controlled by the degree to which Zn is taken up into phytoplankton biomass. The observed systematic pattern in the δ⁶⁶Zn compositions of the diatom_opal core-top samples is, similarly, likely to reflect changes in the δ⁶⁶Zn composition of the ambient Zn in the surface waters above the core-top sites, which is progressively driven towards isotopically heavier values by preferential incorporation of the lighter isotopes into phytoplankton organic material. Thus, the systematic relationship between Zn isotopes and abundance observed in the core-top diatom_opal samples suggests a potential tool for investigating the biogeochemical cycling of Zn in the past surface ocean for down-core diatom_opal material. In this respect, it may be possible to test hypotheses that attribute variations in atmospheric CO₂ on glacial–interglacial timescales to the degree to which trace metals limited primary productivity in HNLC zones.     

The Middle Miocene to Recent Davis Strait Drift Complex: implications for Arctic�CAtlantic water exchange

A large-scale contourite drift complex has been recognised on multi-channel 2D reflection seismic data acquired in the south-eastern Davis Strait and adjacent Labrador Sea slope offshore West Greenland between 63°?C66°N. Based on well-tie data, the drift complex developed from the Middle Miocene to the Recent. It has been mapped in a wide variety of water depths ranging from about 700?m, at a NNW-ESE-elongated crest located above structural highs in the Davis Strait, to more than 2,000?m beyond the slope to the Labrador Sea. The overall drift geometry has been described by subdivision into two first-order seismic units, enabling the generation of time-isochore maps. The reflection patterns demonstrating current-related deposition are illustrated by seismic examples. The time-isochores of the two first-order seismic units show lateral changes in their depocentres: the lower unit is absent in a zone slightly displaced south-westwards of the present-day crest, indicating changes in the prevailing deepwater current system during the Early Pliocene. The observations can be explained by two alternative palaeoceanographic scenarios: (1) either the present-day oceanographic setting with Arctic?CAtlantic water exchange across the Davis Strait was largely established by the mid-Miocene, with only minor adjustments during the Early Pliocene caused by tectonic movements, or (2) it became established during the Early Pliocene as a consequence of enhanced northward flow across the Davis Strait due to lowering of the sill depth.     

An assessment of an oil spill in Gladstone, Australia - impacts on intertidal areas at one month post-spill

In January 2006, 25 tonnes of heavy fuel oil spilled into the Port of Gladstone in Queensland, Australia, from the breached hull of a bulk carrier ship. Over the following days, approximately 18 tonnes of the oil was recovered, however a certain amount of oil was deposited in the intertidal areas of Port Curtis leaving a highly visible, viscous residue. The objectives of this research were to assess the immediate impacts on the intertidal habitat and to gain baseline information for future comparative assessments. Sediment PAH and metal concentrations, mangrove communities and intertidal macroinvertebrates were assessed within one month post-spill at oil-impacted sites; adjacent sites which were not visibly impacted; and reference sites which were located outside the recorded distribution of the oil spill. Highest PAH concentrations were found at the impacted sites, with concentrations of some PAHs exceeding Australian and New Zealand Sediment Quality Guidelines (ANZECC/ARMCANZ, 2000). These sites contained very few or no crab holes in the high intertidal area, indicating a low crab density in comparison to reference sites. Little immediate impact was evident on the mangrove and macrobenthic communities, however future surveys may show evidence of longer-term impacts on these communities.     

Deriving effects of pressure depletion on elastic framework moduli from sonic logs

We have developed a method to determine the effect of pore pressure depletion on elastic framework moduli, by utilizing sonic logs from wells drilled at different locations through a reservoir at varying depletion stages. This is done by first inverting the sonic logs for elastic framework bulk and shear moduli, thus carefully removing pressure dependent fluid effects. By crossplotting these elastic framework moduli against an increase in net stress (which is directly related to depletion), we derive the stress sensitivity of the elastic framework moduli. We found that the observed stress sensitivity was consistent with time-lapse seismic results and that the sensitivity derived from the sonic logs was much smaller than predicted by hydrostatic measurements on core samples. This method is applicable to depletion scenarios in mature fields and can be used both for modelling and inverting time-lapse seismic data for effects of pore pressure depletion on seismic data.     

Crustal contaminants in the Permian Oslo Rift, South Norway: constraints from Precambrian geochemistry

During the late Paleozoic Oslo rifting event, the SW part of the Baltic Shield was penetrated by mantle-derived magmas from a depleted lithospheric or sublithospheric source. Along the way to their final emplacement, these magmas may have interacted with a heterogeneous continental crust, consisting of a mosaic of continental terranes, each with its unique composition and internal crustal history. Information on radiogenic isotope ratios and trace element distributions in the Precambrian terranes surrounding the rift can be used to define characteristic crustal components. These components may be used as endmembers in petrogenetic modelling of the Oslo Rift magmatic system. Based on available data, six endmember components can be identified, and (semi) quantitatively characterized in terms of Sr, Nd and Pb isotopes and selected trace elements. Data on the distribution of rock-types along the rift flanks allow estimates to be made of the relative importance of the components in different parts of the rift. Combining these data with petrological information may allow a realistic understanding of crust–magma interaction in the Oslo Rift magmatic system.     

Lu–Hf and U–Pb isotope systematics of zircons from the Storgangen intrusion, Rogaland Intrusive Complex, SW Norway: implications for the composition and evolution of Precambrian lower crust in the Baltic Shield

The Storgangen orebody is a concordantly layered, sill-like body of ilmenite-rich norite, intruding anorthosites of the Rogaland Intrusive Complex (RIC), SW Norway. 17 zircon grains were separated from ca. 5 kg of sand-size flotation waste collected from the on-site repository from ilmenite mining. These zircons were analysed for major and trace elements by electron microprobe, and for U–Pb and Lu–Hf isotopes by laser ablation microprobe plasma source mass spectrometry. Eight of the zircons define a well-constrained (MSWD=0.37) concordant population with an age of 949±7 Ma, which is significantly older than the 920–930 Ma ages previously reported for zircon inclusions in orthopyroxene megacrysts from the RIC. The remaining zircons, interpreted as inherited grains, show a range of ²⁰⁷Pb/²⁰⁶Pb ages up to 1407±14 Ma, with an upper intercept age at ca. 1520 Ma. The concordant zircons have similar trace element patterns, and a mean initial Hf isotope composition of ¹⁷⁶Hf/¹⁷⁷Hf_{949 Ma}=0.28223±5 (_Hf=+2±2). This is similar to the Hf-isotope composition of zircons in a range of post-tectonic Sveconorwegian granites from South Norway, and slightly more radiogenic than expected for mid-Proterozoic juvenile crust. The older, inherited zircons show Lu–Hf crustal residence ages in the range 1.85–2.04 Ga. One (undated) zircon plots well within the field of Hf isotope evolution of Paleoproterozoic rocks of the Baltic Shield. These findings indicate the presence of Paleoproterozoic components in the deep crust of the Rogaland area, but do not demonstrate that such rocks, or a Sveconorwegian mantle-derived component, contributed significantly to the petrogenesis of the RIC. If the parent magma was derived from a homogeneous, lower crustal mafic granulite source, the lower crustal protolith must be at least 1.5 Ga old, and it must have an elevated Rb/Sr ratio. This component would be indistinguishable in Sr, Nd and Hf isotopes from some intermediate mixtures between Sveconorwegian mantle and Paleoprotoerzoic felsic crust, but it cannot account for the initial ¹⁴³Nd/¹⁴⁴Nd of the most primitive, late Sveconorwegian granite in the region, without the addition of mantle-derived material.     

The limb effect of the Ki resonance line, 769.9 n m

Low-noise observations have been obtained to search for a possible limb effect in the K i 769.9 nm resonance line. The observations were carried out along the north/south diameter of the solar disc. The data were individually corrected for the effects of straylight on the velocity measurements. A small, but significant limb effect is detected. The total shift in the line core from center to limb corresponds to 125 m s^–1 with an uncertainty of < 30 m s^–1.