Analysis of Cassini/CIRS limb spectra of Titan acquired during the nominal mission II: Aerosol extinction profiles in the 600–1420 cm spectral range

We have analyzed the continuum emission of limb spectra acquired by the Cassini/CIRS infrared spectrometer in order to derive information on haze extinction in the 3–0.02 mbar range (∼150–350 km). We focused on the 600–1420 cm⁻¹ spectral range and studied nine different limb observations acquired during the Cassini nominal mission at 55°S, 20°S, 5°N, 30°N, 40°N, 45°N, 55°N, 70°N and 80°N. By means of an inversion algorithm solving the radiative transfer equation, we derived the vertical profiles of haze extinction coefficients from 17 spectral ranges of 20-cm⁻¹ wide at each of the nine latitudes. At a given latitude, all extinction vertical profiles retrieved from various spectral intervals between 600 and 1120 cm⁻¹ display similar vertical slopes implying similar spectral characteristics of the material at all altitudes. We calculated a mean vertical extinction profile for each latitude and derived the ratio of the haze scale height (H_haze) to the pressure scale height (H_gas) as a function of altitude. We inferred H_haze/H_gas values varying from 0.8 to 2.4. The aerosol scale height varies with altitude and also with latitude. Overall, the haze extinction does not show strong latitudinal variations but, at 1 mbar, an increase by a factor of 1.5 is observed at the north pole compared to high southern latitudes. The vertical optical depths at 0.5 and 1.7 mbar increase from 55°S to 5°N, remain constant between 5°N and 30°N and display little variation at higher latitudes, except the presence of a slight local maximum at 45°N. The spectral dependence of the haze vertical optical depth is uniform with latitude and displays three main spectral features centered at 630 cm⁻¹, 745 cm⁻¹ and 1390 cm⁻¹, the latter showing a wide tail extending down to ∼1000 cm⁻¹. From 600 to 750 cm⁻¹, the optical depth increases by a factor of 3 in contrast with the absorbance of laboratory tholins, which is generally constant. We derived the mass mixing ratio profiles of haze at the nine latitudes. Below the 0.4-mbar level all mass mixing ratio profiles increase with height. Above this pressure level, the profiles at 40°N, 45°N, 55°N, at the edge of the polar vortex, display a decrease-with-height whereas the other profiles increase. The global increase with height of the haze mass mixing ratio suggest a source at high altitudes and a sink at low altitudes. An enrichment of haze is observed at 0.1 mbar around the equator, which could be due to a more efficient photochemistry because of the strongest insolation there or an accumulation of haze due to a balance between sedimentation and upward vertical drag.     

A seasonal climate model of the atmospheres of the giant planets at the voyager encounter time: I. Saturn's stratosphere

A radiative seasonal model which incorporates a multilayer radiative transfer treatment at wave-lengths longward of 7 μm is presented and applied to Saturn's stratosphere. Opacities due to H₂-He, CH₄, C₂H₂, and C₂H₆ are included. Season-dependent insolation is shown to produce a strong hemispheric asymmetry decreasing with depth at the Voyager encounter times, and seasonal amplitudes of 30°K at the poles are predicted in the high stratosphere. The ring-modulated dependence of the insolation and the orbital eccentricity are shown to have a significant effect. Calculations agree closely with the Voyager 1 and 2 radio occultation ingress profiles recorded at 76°S and 36.5°S for CH₄/H₂ = 3.5 + 1.4/? 1.0 × 10^?3;the estimated errors include modeling systematic errors and uncertainties in the occultations profiles. The possible role of aerosols in the stratospheric heating is analyzed. The Voyager 2 egress profile recorded at 31°S cannot be reproduced by calculations. Some constraints on the C₂H₂ and C₂H₆ abundances are derived. The upper portion of the occultation profiles (p < 3mbar) can be matched for C₂H₂/H₂ = 1.0 + 1.3/?0.6 × 10^?7, C₂H₆/H₂ = 1.5 + 1.8/?0.9 × 10^?6 at 76°S and C₂H₂/H₂ = 4 + 6/?4 × 10^?8, C₂H₆/H₂ = 6 + 9/?6 × 10^?7 at 36.5°N. At the northern occultation latitude, the discrepancy with the concentrations derived from analysis of IRIS spectra by R. Courtin, D. Gautier, A. Marten, B. Bézard, and R. Hanel (1984, Astrophys. J.287) can be explained by a sharp variation of the mixing ratios of these gases with altitude in the upper stratosphere. Other interpretations are discussed.     

Latitudinal variations of CO and OCS in the lower atmosphere of Venus from near-infrared nightside spectro-imaging

Spectro-imaging of Venus' nightside in the 2.3-μm window provides a powerful means of probing the lower atmosphere in the 25-40 km altitude range. We present observations recorded at the NASA/IRTF in February 2003 and August 2004, using the SpeX spectro-imager in the 2.1-2.5-μm region. Abundances of CO and OCS have been derived as a function of latitude for different longitudes. The CO abundance increases by about 15% between the equatorial region and higher latitudes (±40°). No longitudinal or temporal variations are observed. The OCS abundance shows the opposite variation in observational sets with sufficient S/N. These variations and anticorrelation are consistent with upwelling motions in the equatorial region and downwelling at higher latitudes.     

Chemical characterization of fine particulate matter during peak PM10 episodes in Apulia (South Italy)

Some peak PM10 episodes, occurred during PM monitoring campaigns performed on October 2005 and February and June 2006 in Bari town, have been characterized. Moreover back trajectories of air masses and Principal Component Analyses were applied. Three of the peak PM10 episodes investigated were related to local emissions of primary pollutants during poor atmospheric dispersion conditions. The other two peak PM10 episodes considered are related with long range transport air masses toward Apulia region: in one case the chemical characterization and the back trajectories analysis indicate that high PM10 value detected is due to the Saharan dust advection in the Apulia region; in the other case air masses with different origin give rise to high PM10 value.Moreover PM10 daily mean concentrations, presented in this paper collected from January 2005 to August 2007 and obtained by automatic device in six stations of air quality monitoring networks in Bari territory, do not show a seasonal trend for PM10 concentrations, contrary to the PM10 trend shown in the towns of North Italy. This can be explained mostly considering that our region presents generally meteo-climatic conditions that favour pollutants dispersion.     

Delivery and deposition of organic matter in surface sediments of Lagoa do Caçó (Brazil)

Elemental and isotopic compositions of organic matter in surficial sediments from five transects across Lagoa do Caçó (Brazil) were analyzed to identify the depth-related processes that affect the production and deposition of sedimentary organic matter in this shallow tropical lake. Each of four transverse transects began at a margin dominated by aquatic macrophytes (Eleocharis), crossed the central deep part of the lake, and terminated in the opposite, macrophyte-dominated margin. In each transect, TOC concentrations, C/N ratios, and δ¹³C values decreased between 0 and 4 m, whereas δ¹⁵N values increased. The variables remained stable in sediment from 4 m water depth to the center of the lake at 10 m. The depth-related patterns reflect differences in both the delivery and the deposition of organic matter in the lake. Organic matter is produced in abundance in the marginal area by emersed and submerged macrophyte vegetation that diminishes with depth and disappears at 4 meters. After the disappearance of macrophytes, organic matter is produced at low rates principally by open-lake phytoplankton. Drawdown of dissolved oxygen is high in the lake margins, but it is low in the oligotrophic open waters of the lake. Preservation of organic matter is consequently better in sediments of the lake margins than in deep waters. The depth-related pattern of organic matter delivery and deposition in the sediments of Lagoa do Caçó, in which water levels are sensitive to groundwater fluctuations, shows that the elemental and isotopic compositions of sediment organic matter can provide a record of changes in the paleohydrology of this and other similar shallow lake systems.     

GPCC's new land surface precipitation climatology based on quality-controlled in situ data and its role in quantifying the global water cycle

In 1989, the need for reliable gridded land surface precipitation data sets, in view of the large uncertainties in the assessment of the global energy and water cycle, has led to the establishment of the Global Precipitation Climatology Centre (GPCC) at Deutscher Wetterdienst on invitation of the WMO. The GPCC has calculated a precipitation climatology for the global land areas for the target period 1951–2000 by objective analysis of climatological normals of about 67,200 rain gauge stations from its data base. GPCC's new precipitation climatology is compared to several other station-based precipitation climatologies as well as to precipitation climatologies derived from the GPCP V2.2 data set and from ECMWF's model reanalyses ERA-40 and ERA-Interim. Finally, how GPCC's best estimate for terrestrial mean precipitation derived from the precipitation climatology of 786 mm per year (equivalent to a water transport of 117,000 km³) is fitting into the global water cycle context is discussed.     

Prediction of river water temperature: a comparison between a new family of hybrid models and statistical approaches

River water temperature is a key physical variable controlling several chemical, biological and ecological processes. Its reliable prediction is a main issue in many environmental applications, which however is hampered by data scarcity, when using data‐demanding deterministic models, and modelling limitations, when using simpler statistical models. In this work we test a suite of models belonging to air2stream family, which are characterized by a hybrid formulation that combines a physical derivation of the key equation with a stochastic calibration of parameters. The air2stream models rely solely on air temperature and streamflow, and are of similar complexity as standard statistical models. The performances of the different versions of air2stream in predicting river water temperature are compared with those of the most common statistical models typically used in the literature. To this aim, a dataset of 38 Swiss rivers is used, which includes rivers classified into four different categories according to their hydrological characteristics: low‐land natural rivers, lake outlets, snow‐fed rivers and regulated rivers. The results of the analysis provide practical indications regarding the type of model that is most suitable to simulate river water temperature across different time scales (from daily to seasonal) and for different hydrological regimes. A model intercomparison exercise suggests that the family of air2stream hybrid models generally outperforms statistical models, while cross‐validation conducted over a 30‐year period indicates that they can be suitably adopted for long‐term analyses. Copyright © 2016 John Wiley & Sons, Ltd.     

Der Einfluß der Vegetation auf die Schwankungen des CO2-Gehaltes der Atmosphäre

Zusammenfassung Mit Hilfe des Ultrarot-Absorptionsschreibers wurden Tagesgänge des CO₂-Gehaltes in verschiedenen Höhen über einem Weizenfeld registriert. Während sich nachts durch die Atmung der Vegetation CO₂ am Boden anreichert, verarmt die bodennahe Luftschicht tagsüber infolge der Assimilation an CO₂. Das CO₂-Gefälle wechselt demnach zweimal täglich (morgens und abends) sein Vorzeichen. Infolge größerer Turbulenz ist das Gefälle bei Tag kleiner als bei Nacht; nach Multiplikation mit der Windgeschwindigkeit als Relativmaß des Austausches ergeben sich aber glaubhafte Relativwerte für den vertikalen CO₂-Strom und damit für die Kohlenstoffbindung und-entbindung durch die Pflanzendecke.

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Summary With the help of an infrared absorption-recorder the daily variation of CO₂ content in different heights above a wheat field has been recorded. During the night the CO₂ content is accumulated at the plant level by respiration, during the day diminished by photosynthesis. The CO₂ gradient thus changes its sign (+ or –) twice a day in the morning and evening. The CO₂ gradient is smaller during the day than in the night due to the stronger turbulence of the air. In multiplying gradients with wind velocities (used as a measure for the eddy exchange) one gets reasonable relative values for the vertical CO₂-stream, and thus also for photosynthesis and respiration of vegetation.

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Résumé La variation diurne de la teneur de l'air en CO₂ a été mesurée à différentes hauteurs au-dessus d'un champ de froment à l'aide d'un appareil enregistreur de l'absorption à l'infra-rouge. Tandis que cette teneur augmente de nuit au voisinage du sol par la respiration végétale, elle diminue au cours du jour par suite de l'assimilation. Le gradient vertical de la teneur en CO₂ change par conséquent de signe deux fois par jour, le matin et le soir; il est plus faible de jour à cause de la turbulence accrue que de nuit. Après multiplication par la vitesse du vent, mesure relative de l'échange turbulent, on obtient des valeurs relatives mais vraisemblables du courant vertical de CO₂ et par conséquent de la fixation et de la libération du carbone par la végétation.

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Mit 7 Textabbildungen.

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Nach einem am 15. Oktober 1951 auf der Meteorologentagung in Bad Kissingen gehaltenen Vortrag.