柴达木盆地石炭系烃源岩和煤岩生物标志物特征及其地球化学意义

采自柴达木盆地东北部石炭系烃源岩和煤岩的生物标志化合物研究表明,研究样品的有机质演化已达高成熟阶段,其母质来源以水生生物为主,同时有较丰富的陆源物质输入。除煤岩的沉积古环境较氧化且经历过较强的降解过程外,其余样品的沉积古环境均属于较还原环境,沉积介质为咸水环境,有机质总体丰度高。因此该区石炭系海陆交互相含煤沉积是一套较一般侏罗系为好的烃源岩系,有较好的生烃潜力。     

新疆西准噶尔苏云河钼矿床含矿岩体地球化学和年代学

苏云河钼矿床位于新疆西准噶尔巴尔鲁克山西段,容矿岩石为二长花岗岩和二长花岗斑岩。这些花岗岩具有类似的地球化学特征:富集Rb、Th、U和LREE,相对亏损Ba、P、Ti,属于高钾钙碱性I型花岗岩系列,局部经历过强烈的分离结晶作用。LA-ICPMS锆石U-Pb定年结果显示苏云河钼矿区的成岩年龄为309.3~310.2 Ma,这表明与成矿有关的岩浆活动发生于晚石炭世。黑云母的Ti温度计表明Ⅰ号和Ⅲ号岩体的结晶温度相近,为695~728℃;而Ⅱ号岩体的结晶温度较低,为642~668℃。同时根据角闪石-斜长石压力计获得Ⅰ号和Ⅲ号岩体的结晶压力为(3.0~3.9)×108Pa。综合地球化学研究表明,苏云河钼矿区3个岩体均形成于岛弧环境。此外,以苏云河钼矿床为代表的巴尔鲁克山成矿带与哈萨克斯坦境内的巴尔喀什成矿带在岩石地球化学、成岩成矿时代等方面具有许多类似的特点,表明巴尔鲁克山成矿带可能是巴尔喀什成矿带在中国境内的延伸。     

水泥-粉煤灰浆液在水电站隧洞灌浆中的应用

针对三叉水电站引水隧洞Ⅳ标段围岩地质条件,详细分析了水泥-粉煤灰浆液在该工程引水隧洞灌浆中的应用情况。从应用情况综合分析可以得出,隧洞灌浆采用水泥-粉煤灰浆液是可行的,完全能满足设计要求,在保证灌浆质量的前提下,可以降低部分施工成本,具有较好的推广应用价值。     

华南寒武纪早期刺胞动物演化框架

刺胞动物是华南寒武纪早期海洋生态系统的重要组成部分,针对这类化石的研究有助于深入了解寒武纪多幕式爆发事件。本文主要根据寒武纪早期扬子板块陕南宽川铺生物群、湖北岩家河生物群以及澄江生物群产出的刺胞动物,探讨刺胞动物在寒武纪早期的演化框架,取得了以下初步认识。截至目前,所发现的寒武纪早期刺胞动物绝大多数都属于水母超纲,珊瑚纲的化石记录在寒武系幸运阶、第二阶保存较为罕见。其中寒武系幸运阶刺胞动物的化石记录全部属于底栖类型,体型小,且具有多种类型的身体辐射对称形式,绝大多数类型可以确定属于直接发育。第二阶刺胞动物仍以底栖固着类型为主,体形增大,仅见两、四辐射对称形式;而寒武系第三阶刺胞动物仍有底栖固着类型,但游泳的水母开始出现,体型增大明显,代表水母冠群的出现,以及世代交替的复杂生命周期的正式建立。从幸运阶到第三阶刺胞动物体型明显增大,可能与海水氧气含量增加有关。在寒武纪大爆发的背景下,刺胞动物的分异度和丰度在寒武系幸运阶就已经达到顶峰,然后在第二阶、第三阶开始衰减,这种变化可能与两侧对称动物辐射演化有关。华南刺胞动物的化石记录表明,寒武纪大爆发并非纯粹的一幕式爆发,其中充斥着一系列生物群的替代甚至灭绝事件。     

The Lower Changjiang (Yangzi/Yangtze River) metallogenic belt, east central China: intrusion- and wall rock-hosted Cu–Fe–Au, Mo, Zn, Pb, Ag deposits

The lower valley of Changjiang, from Wuhan of the Hubei Province in the west to Zhenjiang of the Jiangsu Province in the east, contains more than 200 polymetallic (Cu–Fe–Au, Mo, Zn, Pb, Ag) deposits and is one of the most important metallogenic belts in China. This metallogenic belt, situated at the northern margin of the Yangzi craton and bordered by the Dabieshan ultrahigh pressure metamorphic belt to the north, consists mainly of Cambrian–Triassic marine clastic sedimentary rocks and carbonate and evaporite rocks, which overlay a Precambrian basement and are intruded by Yanshanian (205 to 64 Ma) granitoid intrusions and subvolcanic complexes. Repeated tectonism from Late Proterozoic to Triassic resulted in extensively developed networks of faults and folds involving the Cambrian–Triassic sedimentary strata and the Precambrian basement. The Yanshanian granitoid intrusions and subvolcanic complexes in the Lower Changjiang metallogenic belt are characterized by whole-rock δ¹⁸O of +8‰ to +10‰, initial ⁸⁷Sr/⁸⁶Sr of 0.704 to 0.708, and εNd^t from −10 to −17 and have been interpreted to have originated from mixing between juvenile mantle and old crustal materials. Also, the Yanshanian granitoids exhibit eastward younging and increase in alkalinity (i.e., from older calc–alkaline in the west to younger subalkaline–alkaline in the east), which are related to oblique collision between the Yangzi and Sino-Korean cratons and tectonic evolution from early compressional to late extensional or rifting regimes. Most polymetallic deposits in the Lower Changjiang metallogenic belt are clustered in seven districts where the Yanshanian magmatism is particularly extensive: from west to east, Edong, Jiurui, Anqing–Guichi, Luzhong, Tongling, Ningwu and Ningzhen. Mineralization is characterized by the occurrence of three distinct types of orebodies in individual deposits: orebodies in Yanshanian granitoid intrusions, skarn orebodies at the contact zones between the Yanshanian intrusions and Late Paleozoic–Early Mesozoic sedimentary rocks, and stratabound massive sulfide orebodies in the Late Paleozoic–Early Mesozoic sedimentary strata. The most important host sedimentary strata are the Middle Carboniferous Huanglong Formation, Lower Permian and Lower–Middle Triassic carbonate and evaporite rocks. The intrusion-hosted and skarn orebodies exhibit well-developed zonation in alteration assemblages, metal contents, and isotopic compositions within individual deposits, and apparently formed from hydrothermal activities related to the Yanshanian magmatism. The stratabound massive sulfide orebodies in the Late Paleozoic–Early Mesozoic sedimentary strata have long been suggested to have formed from sedimentary or volcano-sedimentary exhalative processes in shallow marine environments. However, extensive research over the last 40 years failed to produce unequivocal evidence for syngenetic mineralization. On the basis of geological relationships and isotope geochemical characteristics, we propose a carbonate-hosted replacement deposit model for the genesis of these stratabound massive sulfide orebodies and associated skarn orebodies. This model suggests that epigenetic mineralization resulted from interactions between magmatic fluids evolved from the Yanshanian intrusions with carbonate and evaporite wall rocks. Mineralization was an integral but distal part of the larger hydrothermal systems that formed the proximal skarn orebodies at the contact zones and the intrusion-hosted orebodies. The stratabound massive sulfide deposits of the Lower Changjiang metallogenic belt share many features with the well-studied, high-temperature, carbonate-hosted replacement deposits of northern Mexico and western United States, particularly with respect to association with small, shallow granitoid complexes, structural and stratigraphic controls on mineralization, alteration assemblages, geometry of orebodies, metal association, metal zonation and isotopic systematics.     

湖南株洲地区Cd、Pb污染土壤的修复实验

以海泡石、膨润土和生石灰为修复材料,对湖南株洲地区重金属元素Cd、Pb污染农田土壤进行了室内修复实验。盆栽小白菜的正交实验结果表明,对于Cd含量为1.23 mg/kg、Pb含量为136.7 mg/kg的土壤,当每10 kg土壤添加膨润土60 g、海泡石20 g、石灰6 g时,种植的小白菜中Cd含量为0.154 mg/kg,Pb含量为0.141mg/kg。与未修复土壤的实验结果对比,小白菜中Cd含量降低61%,Pb含量降低46%。     

北黄海盆地东部坳陷中生界沉积特征及演化

北黄海盆地是我国近海勘探及研究程度均较低的中新生代叠合断陷盆地, 而东部坳陷是其内最具油气勘探前景的二级构造单元。通过岩芯观察与测井相分析, 结合三维地震资料, 认为东部坳陷中生界主要发育扇三角洲、辫状河三角洲、三角洲与湖泊沉积。受构造演化阶段的制约, 不同时期具有不同的沉积演化特征。其中中侏罗世处于湖盆的初期断陷期, 半深湖-深湖亚相发育, 仅在坳陷边缘见少量小规模的扇三角洲沉积。晚侏罗世处于断陷扩展期, 整体为一个完整的湖进-湖退旋回, 早期北部缓坡发育三角洲沉积, 南部及东部陡坡见扇三角洲沉积, 中后期则由于湖平面上升, 发育暗色泥岩为主的湖泊沉积, 晚期北部缓坡见小规模三角洲前缘沉积。早白垩世处于断陷萎缩期, 垂向发育2个正旋回沉积序列, 其中旋回下部以扇三角洲、辫状河三角洲相为主, 向上渐变为滨浅湖沉积。     

田黄萝卜纹的矿物组成与成因分析

萝卜纹是田黄的重要鉴定特征。本文通过岩石薄片、X射线衍射分析和电子探针分析等手段,确定萝卜纹的组成矿物为伊利石;萝卜纹的成因为田黄的原岩受到构造应力作用后产生了显微裂隙,次生的伊利石填充了显微裂隙;显微裂隙中的伊利石与岩石中的主要矿物迪开石光学性质差别较大而呈丝缕状(萝卜纹)。     

琥珀与仿琥珀塑料的放大检查

目前市场上仿琥珀产品很多,对其鉴别较困难。通过放大检查琥珀与仿琥珀塑料样品的包裹体与外部特征,结果发现,两者存在较多的差异,如蜜蜡与仿蜜蜡塑料的条纹、爆花琥珀与仿爆花琥珀塑料的裂隙盘、植物珀与仿植物珀塑料的植物枝节特征、虫珀与仿虫珀塑料的昆虫特征等,这些均可用于鉴别琥珀与仿琥珀塑料。     

热处理褐铁矿去除水中的Mn2+

本文利用褐铁矿中针铁矿经热脱水相变获得以纳米晶赤铁矿为主要物相的纳米-微米多级孔结构材料,并用于模拟净化富Mn~(2+)地下水。同时考察了热处理温度、初始pH值、初始Mn~(2+)浓度、吸附反应时间等对材料去除溶液中Mn~(2+)的影响。XRD、TEM、BET表征结果表明,300℃热处理产物中赤铁矿孔径最小为2.7 nm,比表面积最大达到107.4 m~2/g。吸附实验结果表明,在pH值5~10的范围内,p H值对煅烧褐铁矿颗粒对Mn~(2+)去除效果影响较小;材料在贫氧条件下对水中低浓度Mn~(2+)的最大吸附量为6.45 mg/g;吸附动力学符合准二级动力学模型;褐铁矿热处理形成的纳米晶赤铁矿对Mn~(2+)具有吸附和催化氧化作用,其中的杂质锰氧化物对Mn~(2+)的吸附和催化氧化具有增强作用。