Physical controls on sand composition and relative durability of detrital minerals during ultra‐long distance littoral and aeolian transport (Namibia and southern Angola)

Sediment in coastal Namibia to southern Angola is supplied dominantly from the Orange River with minor additional fluvial input and negligible modifications by chemical processes, which makes this a great test case for investigating physical controls on sand texture and composition. This study monitored textural, mineralogical and geochemical variability in beach and aeolian‐dune sands along a ca 1750 km stretch of the Atlantic coast of southern Africa by using an integrated set of techniques, including image analysis, laser granulometry, optical microscopy, Raman spectroscopy and bulk‐sediment geochemistry. These results contrast with previous reports that feldspars and volcanic detritus break down during transport, that sand grains are rounded rapidly in shallow‐marine environments, and that quartzose sands may be produced by physical processes. Mechanical wear is unable to modify the relative abundance of detrital components, including pyroxene and mafic volcanic rock fragments traditionally believed to be destroyed rapidly. The sole exceptions are poorly lithified or cleaved sedimentary/metasedimentary rock fragments, readily lost at the transition to the marine environment, and slow‐settling flaky micas, winnowed and deposited offshore. Coastal sediments tend to be depleted in relatively mobile amphibole, preferentially entrained offshore or re‐deposited in sheltered beaches, while less mobile garnet is retained onshore. No detrital mineral displays a significant increase in grain roundness after 300 to 350 km of longshore transport in high‐energy littoral environments from the Orange mouth to south of the Namib Erg, but all minerals get rapidly rounded after passing into the dunefield. Pyroxene and opaques get rounded faster than harder quartz and garnet, but sand mineralogy remains unchanged. Excepting strong transient selective‐entrainment effects, physical processes are unable to modify sand composition significantly. Selective mechanical breakdown can be largely neglected in quantitative provenance analysis of sand and sandstone even in the case of ultra‐long‐distance transport in high‐energy environments dominated by strong persistent winds and waves.     

Statistical Characteristics of Xenoliths in the Antioch Kimberlite Pipe,Marshall County,Northeastern Kansas

Geometrical characteristics of xenoliths in the Antioch kimberlite pipe have been considered in statistical terms. A method of conversion of 2D intersections to 3D dimensions was used. It has been shown that the Rosin-Rammler distribution of mass leads to the Weibull distribution of sizes, whereas a fractal distribution of sizes can be expressed as the Pareto distribution. Lognormal, Weibull, and Pareto distributions have been tested as model distributions. The Pareto distribution could be the most appropriate model for the distribution of xenoliths. This conclusion is in agreement with the general concept that the xenoliths formed as a result of an underground explosion without additional breakage occurring during magma transport. The final distribution may be shifted from the initial model as a result of processes of redistribution and sorting of xenoliths in liquid-crystalline flows.     

Late Quaternary ice-rich permafrost sequences as a paleoenvironmental archive for the Laptev Sea Region in northern Siberia

Ice-rich permafrost sequences with large polygonal ice wedges represent excellent archives for paleoenvironmental reconstruction. Such deposits contain numerous well-preserved records (ground ice, paleosols, peat beds, different types of fossils), which permit characterization of environmental conditions during a clearly defined period of the past 60 ka. Based on field investigations carried out within framework of the German-Russian project "Laptev Sea System 2000" on the Bykovsky Peninsula (SE of the Lena Delta) results from cryolithological studies, sedimentological analyses, as well as new radiocarbon data are presented. For the first time it is shown that the Ice Complex accumulated without significant interruptions from approximately 60 k.y. B.P. until the end of the Pleistocene. Geochemical data (total organic carbon, C/N, '¹³C_org) and the mass-specific magnetic susceptibility clearly show changing environmental conditions from stadial to interstadial times in the Late Pleistocene and during the transition to the Holocene. These results permit us to reconstruct the development of an Arctic periglacial landscape in the coastal lowland during Ice Complex formation in the Late Quaternary. This evolution coincided generally with the global environmental trend up to marine isotope stage 4.     

A diagnostic modelling framework to construct indices of biotic integrity: A case study of fish in the Zeeschelde estuary (Belgium)

We propose a coherent regression model building framework to construct fish-based indices. More specifically, we concentrate on the selection of an optimal set of metrics which remains a difficult problem. The paper departs from the observation that an index of biotic integrity (IBI) is analogous to a diagnostic model in medicine assessing the health condition of a patient from a series of biomarkers. In the same vein, an IBI is a diagnostic model predicting the ecosystem condition of a site from a set of (scored) metrics. Metrics are community attributes sensitive to anthropogenic pressure and their scores express the “distance to target” to a reference condition. In a medical context, Receiver Operating Characteristic (ROC) curves are commonly used to assess the diagnostic accuracy of laboratory tests. An ROC curve plots the sensitivity of a test (Se; the capacity to detect a disease or degradation) as a function of its false positive fraction (FPF) which is the complement of the specificity (Sp = 1 - FPF; the capacity to recognise a healthy person or a reference condition). The ROC curve represents the strength of the index to discriminate between degraded and reference sites. Higher curves correspond to stronger tests as then a higher sensitivity can be combined with a lower false positive fraction. Hence, it is intuitively clear to use summary statistics of the ROC curve as criteria to optimise medical tests or biotic indices. In this paper, we illustrate the value of this modelling framework with a case study in the Zeeschelde estuary in Belgium. In essence, a “traditional” IBI is an average of metrics scoring relevant properties of the ecosystem. We demonstrate this average score model (AVG) is a special member of the more flexible predictive logistic model (PLM) family. The selection of a set of metrics becomes equivalent to variable selection in statistical model building. We apply model building techniques as best subsets regression to facilitate the search for an optimal suite of metrics from a candidate set and use cross-validation to avoid overfitting. The results show that a few metrics suffice to discriminate between most-impacted and least-impacted sites.     

Strain development in unconfined coals exposed to CO2, CH4 and Ar: Effect of moisture

Field experiments and laboratory studies have shown that swelling of coal takes place upon contact with carbon dioxide at underground pressure and temperature conditions. Understanding this swelling behavior is crucial for predicting the performance of future carbon dioxide sequestration operations in unminable coal seams conducted in association with methane production. Swelling is believed to be related to adsorption on the internal coal surface. Whereas it is well established that moisture influences the sorption capacity of coal, the influence of water on coal swelling is less well-defined. This paper presents the results of laboratory experiments to investigate the effect of moisture on coal swelling in the presence of carbon dioxide, methane and argon. Strain development of an unconfined sample of about 1.0–1.5 mm³ at 40 °C and 8 MPa (and at other pressures) was observed in an optical cell under a microscope as a function of time. Both air dried and moisturized samples were used. Results confirmed different swelling behaviors of coal with different substances: carbon dioxide leads to higher strain than methane, while exposure to argon leads to very little swelling. The experiments on moisturized samples seem to confirm the role of moisture as a competitor to gas molecules for adsorption sites. Adsorption of water could also explain the observed swelling due to water uptake at atmospheric pressure. A re-introduction of carbon dioxide, after intermediate gas release, results in higher strains which indicate a drying effect of the carbon dioxide on the coal. The results of this study show that the role of water cannot be ignored if one wants to understand the fundamental processes that are taking place in enhanced coalbed methane operations.     

Small is profitable: No support for the optimal foraging theory in sea stars Asterias rubens foraging on the blue edible mussel Mytilus edulis

Doubt has been shed recently on the most popular optimal foraging theory stating that predators should maximize prey profitability, i.e., select that prey item that contains the highest energy content per handling time. We hypothesized that sea stars do not forage on blue mussels according to the classical optimal foraging theory but are actively avoiding damage that may be caused by e.g. capture of foraging on too-strong mussel shells, hence the sea stars will have a stronger preference for mussels that are smaller than the most profitable ones. Here we present experimental evidence of the sea star Asterias rubens as a predator that indeed chooses much smaller blue mussels Mytilus edulis to forage on than the most profitable ones. Hence this study does not support the optimal foraging theory. There may be other constraints involved in foraging than just optimizing energy intake, for example predators may also be concerned with preventing potential loss or damage of their foraging instruments.     

Late Triassic tectonic inversion in the upper Yangtze Block: Insights from detrital zircon U–Pb geochronology from south‐western Sichuan Basin

The Sichuan Basin and the Songpan‐Ganze terrane, separated by the Longmen Shan fold‐and‐thrust belt (the eastern margin of the Tibetan Plateau), are two main Triassic depositional centres, south of the Qinling‐Dabie orogen. During the Middle–Late Triassic closure of the Paleo‐Tethys Ocean, the Sichuan Basin region, located at the western margin of the Yangtze Block, transitioned from a passive continental margin into a foreland basin. In the meantime, the Songpan‐Granze terrane evolved from a marine turbidite basin into a fold‐and‐thrust belt. To understand if and how the regional sediment routing system adjusted to these tectonic changes, we monitored sediment provenance primarily by using detrital zircon U‐Pb analyses of representative stratigraphic samples from the south‐western edge of the Sichuan Basin. Integration of the results with paleocurrent, sandstone petrology and published detrital zircon data from other parts of the basin identified a marked change in provenance. Early–Middle Triassic samples were dominated by Neoproterozoic (~700–900 Ma) zircons sourced mainly from the northern Kangdian basement, whereas Late Triassic sandstones that contain a more diverse range of zircon ages sourced from the Qinling, Longmen Shan and Songpan‐Ganze terrane. This change reflects a major drainage adjustment in response to the Late Triassic closure of the Paleo‐Tethys Ocean and significant shortening in the Longmen Shan thrust belt and the eastern Songpan‐Ganze terrane. Furthermore, by Late Triassic time, the uplifted northern Kangdian basement had subsided. Considering the eastward paleocurrent and depocenter geometry of the Upper Triassic deposits, subsidence of the northern Kangdian basement probably resulted from eastward shortening and loading of the Songpan‐Ganze terrane over the western margin of the Yangtze Block in response to the Late Triassic collision among Yangtze Block, Yidun arc and Qiangtang terrane along the Ganze‐Litang and Jinshajiang sutures.