Sorption-desorption kinetics and toxic cell concentration in marine phytoplankton microalgae exposed to Linear Alkylbenzene Sulfonate

Linear Alkylbenzene Sulfonates (LAS) are ubiquitous surfactants. Traces can be found in coastal environments. Sorption and toxicity of C₁₂-LAS congeners were studied in controlled conditions (2-3500 μg C₁₂LAS/L) in five marine phytoplanktonic species, using standardized methods. IC₅₀ values ranged from 0.5 to 2 mg LAS/L. Sorption of ¹⁴C₁₂-6 LAS isomer was measured at environmentally relevant trace levels (4 μg/L) using liquid scintillation counting. Steady-state sorption on algae was reached within 5 h in the order dinoflagellate > diatoms > green algae. The sorption data, fitted a L-type Freundlich isotherm, indicating saturation. Desorption was rapid but a low LAS fraction was still sorbed after 24 h. Toxic cell concentration was 0.38 ± 0.09 mg/g for the studied species. LAS toxicity results from sorption on biological membranes leading to non-specific disturbance of algal growth. Results indicate that LAS concentrations in coastal environments do not represent a risk for these organisms.     

Lateral friction in the oceans as an effect of potential vorticity mixing

Abstract

Applying a mixing-length calculation to potential vorticity rather than to momentum a new type of lateral friction appears in the oceanic mass transport equations. This friction is evaluated for the special case of horizontally homogeneous, quasi-geostrophic turbulence. The main effect is a westward force arising from the so-called β-term. This produces an additional southward interior transport and a strengthening of the western boundary current. A turbulent exchange coefficient K^H = 10⁸ em²s^?1 is sufficient to give a Gulf Stream transport twice that obtained by the classical Sverdrup model.     

A seasonal dipolar eddy near Ras Al Hamra (Sea of Oman)

Trajectories and hydrological data from two Argo floats indicate that warm and salty water at 200–300-m depths was ejected from the coast of Oman, near Ras al Hamra, in spring 2008, 2011, and 2012. This warm and salty water, Persian Gulf Water (PGW), once ejected from the coast, recirculated cyclonically in the western Sea of Oman, but also flowed eastward along the Iranian and Pakistani coasts. There, it was expelled seaward by mesoscale eddies as shown by other float data. Seasonal maps of salinity were computed from all available Argo floats; they showed that, in spring, PGW is present in the middle and north of the Sea of Oman, contrary to fall, when the salinity maxima lie southeast of Ras al Hadd. The ejection of PGW from Ras al Hamra is related here to the influence of a mesoscale dipolar eddy which often appears near this cape in spring. The time-averaged and empirical orthogonal functions of altimetric maps over 11 years for this season confirm the frequent presence and the persistence of this feature. From surface currents and hydrology, deep currents were computed via thermal wind balance, and the associated shear and strain fields were obtained. This deformation field is intense near Ras al Hamra, with an offshore direction. This flow structure associated with the mesoscale dipole explains PGW ejection from the coast. This observation suggests that PGW distribution in the Northern Arabian Sea can be strongly influenced by seasonal mesoscale eddies.     

Etude des Déformations et Inclinaisons du Sous-sol: Développements Instrumentaux et Applications dans la Région Sismique d’Arette,France

We present a modified version of a tilt and strain meter conceived to have great sensibility and good stability. These instruments were deployed in a cave at the seismic Pyrenean region of Arette (France). We set in evidence several types of phenomena, of which deformations brought about by water recharge filling up fissures on the massif are of importance. Owing to the redundance in the data, the study of the co-seismic deformations allows one to separate instrumental displacements and local readjustments from regional motions.     

Direct simulation of solute recycling in irrigated areas

Solute recycling from irrigation can be described as the process that occurs when the salt load that is extracted from irrigation wells and distributed on the fields is returned to the groundwater below irrigated surfaces by deep percolation. Unless the salt load leaves the system by means of drains or surface runoff, transfer to the groundwater will take place, sooner or later. This can lead to solute accumulation and thus to groundwater degradation, particularly in areas where extraction rates exceed infiltration rates (semi-arid and arid regions). Thus, considerable errors can occur in a predictive solute mass budget if the recycling process is not accounted for in the calculation. A method is proposed which allows direct simulation of solute recycling. The transient solute response at an extraction well is shown to be a superposition of solute mass flux contributions from n recycling cycles and is described as a function of the travel time distribution between a recycling point and a well. This leads to an expression for a transient ‘recycling source’ term in the advection–dispersion equation, which generates the effect of solute recycling. At long times, the ‘recycling source’ is a function of the local capture probability of the irrigation well and the solute mass flux captured by the well from the boundaries. The predicted concentration distribution at steady state reflects the maximum spatial concentration distribution in response to solute recycling and can thus be considered as the solute recycling potential or vulnerability of the entire domain for a given hydraulic setting and exploitation scheme. Simulation of the solute recycling potential is computationally undemanding and can therefore, for instance, be used for optimisation purposes. Also, the proposed method allows transient simulation of solute recycling with any standard flow and transport code.     

Evidence of an early alteration process driven by magmatic fluid in Mururoa volcano

Evidence for a deuteric alteration process induced by a magmatic fluid has been found in the feeder zone of the Mururoa volcano (French Polynesia). Within the dikes, where basaltic glass does not show any evidence of pervasive alteration, vesicles are filled with dioctahedral smectites and calcite, while olivine phenocrysts are replaced by dioctahedral smectites, ankerite and calcite.The ¹³C signature of carbonates, the carbon and H₂O content of the whole rocks and their impoverishment in deuterium are compatible with the presence of magmatic CO₂ during the crystallization of intruding lavas and exclude contamination by seawater. Mass balance calculations on selected thin sections photographs of partly filled up vesicles and replaced olivine crystals, constrain, assuming a closed system interaction, the chemical composition of the initial fluid and the respective amounts of the initial solid phases involved in the alteration process. Thermodynamic modelings using the EQ3/6 software package correctly predict the mineralogic, chemical and isotopic exchanges accompanying alteration, thus validating the closed system assumption. The model which allows prediction of the influence of CO₂ on the alteration products, shows that, above a 0.25 CO₂ mole fraction in the initial fluid, the alteration is entirely controlled by the chemical composition of the initial solid phases. The presence of CO₂ implies the precipitation of dioctahedral smectites and carbonates instead of the magnesian smectites commonly observed in CO₂-free systems.The Mururoa feeder zone shows alteration features typical of a closed system interaction between the basaltic rock and a magmatic fluid in which seawater did not take part.     

Eruptive history of the Colima volcanic complex (Mexico)

The evolution of the Colima volcanic complex can be divided into successive periods characterized by different dynamic and magmatic processes: emission of andesitic to dacitic lava flows, acid-ash and pumice-flow deposits, fallback nuées ardentes leading to pyroclastic flows with heterogeneous magma, plinian air-fall deposits, scoriae cones of alkaline and calc-alkaline nature. Four caldera-forming events, resulting either from major ignimbrite outbursts or Mount St. Helens-type eruptions, separate the main stages of development of the complex from the building of an ancient shield volcano (25 × 30 km wide) up to two summit cones, Nevado and Fuego.The oldest caldera, C1 (7–8 km wide), related to the pouring out of dacitic ash flows, marks the transition between two periods of activity in the primitive edifice called Nevado I: the first one, which is at least 0.6 m.y. old, was mainly andesitic and effusive, whereas the second one was characterized by extrusion of domes and related pyroclastic products. A small summit caldera, C2 (3–3.5 km wide), ended the evolution of Nevado I.Two modern volcanoes then began to grow. The building of the Nevado II started about 200,000 y. ago. It settled into the C2 caldera and partially overflowed it. The other volcano, here called Paleofuego, was progressively built on the southern side of the former Nevado I. Some of its flows are 50,000 y. old, but the age of its first outbursts is not known. However, it is younger than Nevado II. These two modern volcanoes had similar evolutions. Each of them was affected by a huge Mount St. Helens-type (or Bezymianny-type) event, 10,000 y. ago for the Paleofuego, and hardly older for the Nevado II. The landslides were responsible for two horseshoe-shaped avalanche calderas, C3 (Nevado) and C4 (Paleofuego), each 4–5 km wide, opening towards the east and the south. In both cases, the activity following these events was highly explosive and produced thick air-fall deposits around the summit craters.The Nevado III, formed by thick andesitic flows, is located close to the southwestern rim of the C3 caldera. It was a small and short-lived cone. Volcan de Fuego, located at the center of the C4 caldera, is nearly 1500 m high. Its activity is characterized by an alternation of long stages of growth by flows and short destructive episodes related to violent outbursts producing pyroclastic flows with heterogeneous magma and plinian air falls.The evolution of the primitive volcano followed a similar pattern leading to formation of C1 and then C2. The analogy between the evolutions of the two modern volcanoes (Nevado II–III; Paleofuego-Fuego) is described. Their vicinity and their contemporaneous growth pose the problem of the existence of a single reservoir, or two independent magmatic chambers, after the evolution of a common structure represented by the primitive volcano.