The role of groundwater in cliff instability: an example at Cape Blanc‐Nez (Pas‐de‐Calais,France)

Cliff retreat in northern Boulonnais is described. The distribution of the amount of retreat is related to structural and topographic factors. Both control the runoff–infiltration balance and therefore the mechanical behaviour of the rocks, which determines the modes of failure. The spatial variability of the retreat rate is explained, but predicting the temporal variability of the retreat rate, which is central to risk management, is much more difficult. Rainfall and piezometric surface data enhanced a ‘piston flow’ mechanism during November 2000. The result of its occurrence on the stability of the cliff and conditions of its recurrence are examined with a view to better understanding the rate of recession of coastal cliffs and wiser management of risk. Copyright © 2005 John Wiley & Sons, Ltd.     

Laboratory P-wave measurements in dry and saturated sand

We measure the P-wave velocity in a clean medium sand subject to very low stress in a large-scale laboratory cross-hole experiment for frequencies less than 10 kHz. In dry sand the velocity is depth-, and therefore, stress-dependent according to a power law. The velocity in partially saturated sand is essentially the same as in dry sand, which confirms the analytical result of the Biot–Gassmann theory. At 100% saturation, the velocity largely exceeds that in dry and partially saturated sand, once again in accordance with the Biot–Gassmann theory. However, the theory under-predicts velocities by up to 12% in some cases at full saturation. The maximum attenuation determined from spectral analysis of the measured signals closely matches the characteristic frequency predicted by the Biot model.     

Seismic properties of the upper mantle beneath Lanzarote (Canary Islands): Model predictions based on texture measurements by EBSD

We present a petrophysical analysis of upper mantle xenoliths, collected in the Quaternary alkali basalt fields (Series III and IV) from the island of Lanzarote. The samples consist of eight harzburgite and four dunite nodules, 5 to 15 cm in size, and exhibit a typical protogranular to porphyroclastic texture. An anomalous foliation resulting from strong recovery processes is observed in half of the specimens. The lattice preferred orientations (LPO) of olivine, orthopyroxene and clinopyroxene were measured using electron backscatter diffraction (EBSD). In most samples, olivine exhibits LPOs intermediate between the typical single crystal texture and the [100] fiber texture. Occasionally, the [010] fiber texture was also observed. Simultaneous occurrence of both types of fiber textures suggests the existence of more than one deformation regime, probably dominated by a simple shear component under low strain rate and moderate to high temperature. Orthopyroxene and clinopyroxene display a weaker but significant texture. The LPO data were used to calculate the seismic properties of the xenoliths at PT conditions obtained from geothermobarometry, and were compared to field geophysical data reported from the literature. The velocity of P-waves (7.9 km/s) obtained for a direction corresponding to the existing seismic transect is in good agreement with the most recent geophysical interpretation. Our results are consistent with a roughly W–E oriented fastest P-wave propagation direction in the uppermost mantle beneath the Canary Islands, and with the lithosphere structure proposed by previous authors involving a crust–mantle boundary at around 18 km in depth, overlaid by intermediate material between 11 and 18 km.     

Analysis of organic matter by flash pyrolysis-gas chromatography–mass spectrometry in the presence of Na-smectite: When clay minerals lead to identical molecular signature

Different studies have already pointed out the influence of clays during the analysis of pure organic compounds (especially alkanols, alkanoic acids) as well as macromolecules (humic acids) by flash pyrolysis-gas chromatography–mass spectrometry (PyGC–MS). Especially, the occurrence of clay minerals favors the generation of aromatic units such as alkylbenzenes and polycyclic aromatic hydrocarbons. So as to better identify the nature of the organic compounds which are sensitive to the presence of clays during flash pyrolysis, a humic acid mixed in variable proportions of a Na-homoionic clay was tested. The smectite/humic acid mixtures containing from 10% to 100% humic acid allowed us to identify the progressive disappearance or appearance of specific compounds after PyGC–MS.n-Alk-1-enes disappear when the clay proportion is higher than 67%. For higher contents of Na-smectite, n-alkanes become less and less abundant with a preferential consumption of high molecular weight n-alkanes, whereas the aromatic hydrocarbon proportion increases. Moreover, the distribution of each aromatic hydrocarbon family (alkylbenzenes and alkylnaphthalenes) has been investigated. The pyrogram of pure humic acid exhibits a specific distribution of alkylbenzenes and alkylnaphthalenes reflecting the structure of the organic macromolecule. With the increase in clay proportion, these distributions are modified and lead to other distributions with a preferential predominance of thermally stable isomers.Pyrograms of humic acid and undecanoic acid in the presence of 90% of Na-smectite are similar, especially concerning alkylbenzene and alkylnaphthalene distributions. Therefore, clays (Na-smectite in our experiments) in high proportion modify initial organic products by recombination reactions and lead to the generation of new compounds of very similar distribution, whatever the nature of the initial organic matter. Such results underline the very important catalytic properties of clay minerals on functionalized organic matter during flash pyrolysis.     

Comparison of methods for the estimation of pyrite oxidation rate in a waste rock pile at Mine Doyon site, Quebec, Canada

Several methods were evaluated and compared for the estimation of pyrite oxidation rates (POR) in waste rock at Mine Doyon, Quebec, Canada. Methods based on data collected in situ, such as the interpretation of temperature and oxygen concentration profiles (TOP) measured in the waste rock pile and pyrite mass balance (PMB) on solid phase samples were compared with the oxygen consumption measurements (OCM) in closed chamber in the laboratory. A 1-D analytical solution to a gas and heat transport equation used temperature and oxygen profiles (TOP) measured in the pile for the preliminary POR estimates at a site close to the slope of the pile (Site 6) and in the core of the pile (Site 7). Resulting POR values were 1.1 × 10^− 9 mol(O₂) kg^− 1 s^− 1 and 1.0 × 10^− 10 mol(O₂) kg^− 1 s^− 1 for the slope site and the core site, respectively. Oxidation rates based on pyrite mass balance (PMB) calculations for solid samples were 2.21 × 10^− 9 mol(O₂) kg^− 1 s^− 1 and 2.03 × 10^− 9 mol(O₂) kg^− 1 s^− 1, respectively, for the same slope and core sites, but the difference between sites was within the error margin. The OCM measurements in the laboratory on fresh waste rock samples yielded higher POR values than field methods, with average oxidation rate of 6.7 × 10^− 8 mol(O₂) kg^− 1 s^− 1. However, the OCM results on weathered and decomposed material from the rock stockpile (average oxidation rate 3.4 × 10^− 9 mol(O₂) kg^− 1 s^− 1) were consistent with results from the field-based estimates. When POR values based on fresh material are excluded, the remaining POR values for all methods range from 1.0 × 10^− 10 to 3.4 × 10^− 9 mol(O₂) kg^− 1 s^− 1. The lowest estimated value (1.0 × 10^− 10 mol(O₂) kg^− 1 s^− 1) was based on TOP estimates in the interior of the pile where oxygen transport was limited by diffusion from the surface. These results suggest that small-scale OCM laboratory experiments may provide relatively representative values of POR in the zones of waste rock piles in which oxygen transport is not dominated by diffusion.     

Seismic stability of concrete gravity dams strengthened by rockfill buttressing

Rockfill buttressing resting on the downstream face of masonry or concrete gravity dam is often considered as a strengthening method to improve the stability of existing dam for hydrostatic and seismic loads. Simplified methods for seismic stability analysis of composite concrete-rockfill dams are discussed. Numerical analyses are performed using a nonlinear rockfill model and nonlinear dam-rockfill interface behavior to investigate the effects of backfill on dynamic response of composite dams. A typical 35 m concrete gravity dam, strengthened by rockfill buttressing is considered. The results of analyses confirm that backfill can improve the seismic stability of gravity dams by exerting pressure on the dam in opposition to hydrostatic loads. According to numerical analyses results, the backfill pressures vary during earthquake base excitations and the inertia forces of the backfill are the main source for those variations. It is also shown that significant passive (or active) pressure cannot develop in composite dams with a finite backfill width. A simplified model is also proposed for dynamic analysis of composite dam by replacing the backfill with by a series of vertical cantilever shear beams connected to each other and to the dam by flexible links.     

Contrôle karstique de minéralisations nickélifères de Nouvelle-Calédonie

Fracturing associated with the nickeliferous mineralisations of New Caledonia has been successively considered as pre-dating and then post-dating the metallogenic processes. On the basis of a study of the dynamics of karst contemporaneous with lateritisation, a new emplacement model is proposed for the mineralisation: a network of hydraulic fractures of the crack-seal type governs the emplacement of mineralisation, associated with a network of normal faults that controls the sinking and evacuation of the karst products. To cite this article: A. Genna et al., C. R. Geoscience 337 (2005).     

Studying the migration behaviour of selenate in Boom Clay by electromigration

For the disposal of high-level waste (HLW) in a deep geological formation as Boom Clay, safety assessment studies have shown that long lived ⁷⁹Se is one of the more critical fission products. Therefore, the knowledge of its migration properties (diffusion, retention) through the geological barrier (Boom Clay) is of paramount importance. The migration behaviour of selenium strongly depends on its speciation. Under reducing conditions, selenide would be the dominant species and selenium migration would mainly be controlled by the low solubility of Se(−II)-bearing minerals. However Se species are often found in redox disequilibrium and more oxidized species might also coexist. Therefore, the study of selenate migration requires attention, as it might be the most mobile selenium species in the host rock. Electromigration experiments performed with a ⁷⁵Se-labeled selenate in Boom Clay indicate a high mobility for this species. The apparent diffusion coefficient (D_app) of selenate in Boom Clay is estimated from electromigration experiments performed under different electric fields. Using two independent approaches, the value of D_app for selenate is shown to fall in the range from 1.7×10⁻¹¹ to 6.2×10⁻¹¹ m² s⁻¹. Moreover, no reduction of selenate in Boom Clay was observed.