The orbital period distribution of subdwarf-B binaries

We present the results of a 3.5 year long campaign to measure orbital periods of subdwarf-B (sdB) star binaries. We directly compare our observed orbital period distribution with that predicted by using binary population synthesis. Up to now, most of our systems seem to have been formed through two of the formation channels discussed by Han et al. (2003, MNRAS 341, p. 669), i.e. the first and the second common envelope ejection (CE) channels. At this point, thanks to the long baseline of our observations, we are starting to detect also very long orbital period systems. These have probably come from a complete different formation path, the first stable Roche Lobe overflow (RLOF) channel in which the first mass transfer phase is stable. This channel is expected to lead to the formation of very wide binaries with typical orbital periods ranging from 1 month to 1 year.     

The extent of chronic marine oil pollution in southeastern Newfoundland waters assessed through beached bird surveys 1984-1999

The Grand Banks south of Newfoundland provide year-round feeding habitat for tens of millions of seabirds of numerous species, an abundance and diversity unparalleled in the North Atlantic. Dense ship traffic routes traverse this productive environment as vessels travel the Great Circle Route between Europe and North America. Oiled seabirds have washed up on beaches in Newfoundland for many decades. Most oil on their feathers is heavy fuel oil mixed with lubricants, the mixture found in bilges of large vessels. Beached bird surveys conducted between 1984 and 1999 indicate that chronic oil pollution along the southeast coast of Newfoundland is among the highest in world. Sixty two percent of all dead birds found over the 16-year period had oil on their feathers; 74% during the last five years. Auks, especially Thick-billed Murres (Uria lomvia), are the most affected. The mean number of oiled birds per kilometer was 0.77 and thus higher than in other regions of the world during a comparable time period (0.02-0.33). Oiling rates correlated with weather patterns and degree of the regional murre hunt, indicate that illegal dumping of oil may occur year round, and point out that it is critical to assess all possible environmental and anthropogenic factors influencing the number of clean and oiled dead birds found on beaches before inferring trends in oiling rates over time.     

Sliding response of gravity dams including vertical seismic accelerations

Seismic safety assessment of gravity dams has become a major concern in many regions of the world while the effects of vertical seismic accelerations on the response of structures remain poorly understood. This paper first investigates the effect of including vertical accelerations in the sliding response analysis of gravity dams subjected to a range of historical ground motion records separated in two groups according to their source-to-site distance. Analyses showed that the incidence of vertical accelerations on the sliding response of gravity dams is significantly higher for near-source records than for farsource records. The pseudo-static 30% load combination rule, commonly used in practice to account for the non-simultaneous occurrence of the peak horizontal and vertical accelerations, yielded good approximations of the minimum safety factors against sliding computed from time-history analyses. A method for empirically estimating the vertical response spectra based on horizontal spectra, accounting for the difference in frequency content and amplitudes between the two components is investigated. Results from analyses using spectrum compatible horizontal and vertical synthetic records also approximated well the sliding response of a gravity dam subjected to series of simultaneous horizontal and vertical historical earthquake records.     

Structure, age and mode of emplacement of the Hercynian Bordères-Louron pluton (Central Pyrenees, France)

The Hercynian Bordères-Louron pluton (20 km²) in the Central Pyrenees intrudes Devonian and Carboniferous metasediments. It shows a concentric zoning and consists of a significant proportion of (quartz) gabbros in its periphery, and of granodiorites, biotite monzogranites and biotite-muscovite monzogranites in its core. AMS study shows that the pluton corresponds to an elongated dome with a N100°E-trending axis. The anisotropy intensity Ppara% is high in the south and in the core of the pluton, whereas it is low in the north. The shape parameter T indicates that the fabric is strongly planar in a large central band oriented NW-SE, whereas it is strongly linear in the western and eastern tips of the pluton. These characteristics suggest that the Bordères-Louron pluton emplaced in two episodes: (1) intrusion of mafic magmas along a N100°E sill parallel to the regional foliation of the host metasediments; and (2) injection of three successive silicic batches (granodiorite, biotite monzogranite, two-micas monzogranite) which pushed aside the early mafic injections. In situ U-Pb dating of zircon grains indicates that the emplacement age of the biotite monzogranite is 309 ± 4 Ma, synchronous with the D ₂ dextral transpressive event and close to the ages of the eastern Pyrenean plutons, may be slightly older.     

Seismic properties of the upper mantle beneath Lanzarote (Canary Islands): Model predictions based on texture measurements by EBSD

We present a petrophysical analysis of upper mantle xenoliths, collected in the Quaternary alkali basalt fields (Series III and IV) from the island of Lanzarote. The samples consist of eight harzburgite and four dunite nodules, 5 to 15 cm in size, and exhibit a typical protogranular to porphyroclastic texture. An anomalous foliation resulting from strong recovery processes is observed in half of the specimens. The lattice preferred orientations (LPO) of olivine, orthopyroxene and clinopyroxene were measured using electron backscatter diffraction (EBSD). In most samples, olivine exhibits LPOs intermediate between the typical single crystal texture and the [100] fiber texture. Occasionally, the [010] fiber texture was also observed. Simultaneous occurrence of both types of fiber textures suggests the existence of more than one deformation regime, probably dominated by a simple shear component under low strain rate and moderate to high temperature. Orthopyroxene and clinopyroxene display a weaker but significant texture. The LPO data were used to calculate the seismic properties of the xenoliths at PT conditions obtained from geothermobarometry, and were compared to field geophysical data reported from the literature. The velocity of P-waves (7.9 km/s) obtained for a direction corresponding to the existing seismic transect is in good agreement with the most recent geophysical interpretation. Our results are consistent with a roughly W–E oriented fastest P-wave propagation direction in the uppermost mantle beneath the Canary Islands, and with the lithosphere structure proposed by previous authors involving a crust–mantle boundary at around 18 km in depth, overlaid by intermediate material between 11 and 18 km.     

Analysis of organic matter by flash pyrolysis-gas chromatography–mass spectrometry in the presence of Na-smectite: When clay minerals lead to identical molecular signature

Different studies have already pointed out the influence of clays during the analysis of pure organic compounds (especially alkanols, alkanoic acids) as well as macromolecules (humic acids) by flash pyrolysis-gas chromatography–mass spectrometry (PyGC–MS). Especially, the occurrence of clay minerals favors the generation of aromatic units such as alkylbenzenes and polycyclic aromatic hydrocarbons. So as to better identify the nature of the organic compounds which are sensitive to the presence of clays during flash pyrolysis, a humic acid mixed in variable proportions of a Na-homoionic clay was tested. The smectite/humic acid mixtures containing from 10% to 100% humic acid allowed us to identify the progressive disappearance or appearance of specific compounds after PyGC–MS.n-Alk-1-enes disappear when the clay proportion is higher than 67%. For higher contents of Na-smectite, n-alkanes become less and less abundant with a preferential consumption of high molecular weight n-alkanes, whereas the aromatic hydrocarbon proportion increases. Moreover, the distribution of each aromatic hydrocarbon family (alkylbenzenes and alkylnaphthalenes) has been investigated. The pyrogram of pure humic acid exhibits a specific distribution of alkylbenzenes and alkylnaphthalenes reflecting the structure of the organic macromolecule. With the increase in clay proportion, these distributions are modified and lead to other distributions with a preferential predominance of thermally stable isomers.Pyrograms of humic acid and undecanoic acid in the presence of 90% of Na-smectite are similar, especially concerning alkylbenzene and alkylnaphthalene distributions. Therefore, clays (Na-smectite in our experiments) in high proportion modify initial organic products by recombination reactions and lead to the generation of new compounds of very similar distribution, whatever the nature of the initial organic matter. Such results underline the very important catalytic properties of clay minerals on functionalized organic matter during flash pyrolysis.     

Laboratory P-wave measurements in dry and saturated sand

We measure the P-wave velocity in a clean medium sand subject to very low stress in a large-scale laboratory cross-hole experiment for frequencies less than 10 kHz. In dry sand the velocity is depth-, and therefore, stress-dependent according to a power law. The velocity in partially saturated sand is essentially the same as in dry sand, which confirms the analytical result of the Biot–Gassmann theory. At 100% saturation, the velocity largely exceeds that in dry and partially saturated sand, once again in accordance with the Biot–Gassmann theory. However, the theory under-predicts velocities by up to 12% in some cases at full saturation. The maximum attenuation determined from spectral analysis of the measured signals closely matches the characteristic frequency predicted by the Biot model.     

Comparison of methods for the estimation of pyrite oxidation rate in a waste rock pile at Mine Doyon site, Quebec, Canada

Several methods were evaluated and compared for the estimation of pyrite oxidation rates (POR) in waste rock at Mine Doyon, Quebec, Canada. Methods based on data collected in situ, such as the interpretation of temperature and oxygen concentration profiles (TOP) measured in the waste rock pile and pyrite mass balance (PMB) on solid phase samples were compared with the oxygen consumption measurements (OCM) in closed chamber in the laboratory. A 1-D analytical solution to a gas and heat transport equation used temperature and oxygen profiles (TOP) measured in the pile for the preliminary POR estimates at a site close to the slope of the pile (Site 6) and in the core of the pile (Site 7). Resulting POR values were 1.1 × 10^− 9 mol(O₂) kg^− 1 s^− 1 and 1.0 × 10^− 10 mol(O₂) kg^− 1 s^− 1 for the slope site and the core site, respectively. Oxidation rates based on pyrite mass balance (PMB) calculations for solid samples were 2.21 × 10^− 9 mol(O₂) kg^− 1 s^− 1 and 2.03 × 10^− 9 mol(O₂) kg^− 1 s^− 1, respectively, for the same slope and core sites, but the difference between sites was within the error margin. The OCM measurements in the laboratory on fresh waste rock samples yielded higher POR values than field methods, with average oxidation rate of 6.7 × 10^− 8 mol(O₂) kg^− 1 s^− 1. However, the OCM results on weathered and decomposed material from the rock stockpile (average oxidation rate 3.4 × 10^− 9 mol(O₂) kg^− 1 s^− 1) were consistent with results from the field-based estimates. When POR values based on fresh material are excluded, the remaining POR values for all methods range from 1.0 × 10^− 10 to 3.4 × 10^− 9 mol(O₂) kg^− 1 s^− 1. The lowest estimated value (1.0 × 10^− 10 mol(O₂) kg^− 1 s^− 1) was based on TOP estimates in the interior of the pile where oxygen transport was limited by diffusion from the surface. These results suggest that small-scale OCM laboratory experiments may provide relatively representative values of POR in the zones of waste rock piles in which oxygen transport is not dominated by diffusion.     

Relative performance of future altimeter systems and tide gauges in constraining a model of North Sea high-frequency barotropic dynamics

We evaluate in this paper the ability of several altimeter systems, considered separately as well as together with tide gauges, to control the time evolution of a barotropic model of the North Sea shelf. This evaluation is performed in the framework of the particular model errors due to uncertainties in bathymetry. An Ensemble Kalman Filter (EnKF) data assimilation approach is adopted, and observing-systems simulation experiments (OSSEs) are carried out using ensemble spread statistics. The skill criterion for the comparison of observing networks is, therefore, not based on the misfit between two simulations, as done in classic twin experiments, but on the reduction of ensemble variance occurring as a consequence of the assimilation. Future altimeter systems, such as the Wide Swath Ocean Altimeter (WSOA) and satellite constellations, are considered in this work. A single WSOA exhibits, for instance, similar performance as two-nadir satellites in terms of sea-level correction, and is better than three satellites in terms of model velocity control. Generally speaking, the temporal resolution of observations is shown to be of major importance for controlling the model error in these experiments. This result is clearly related to the focus adopted in this study on the specific high-frequency response of the ocean to meteorological forcing. Altimeter systems lack adequate temporal sampling for properly correcting the major part of model error in this context, whereas tide gauges, which provide a much finer time resolution, lead to better global statistical performance. When looking into further detail, tide gauges and altimetry are demonstrated to exhibit an interesting complementary character over the whole shelf, as tide gauge networks make it possible to properly control model error in a ∼100-km coastal band, while high-resolution altimeter systems are more efficient farther from the coast.     

The role of groundwater in cliff instability: an example at Cape Blanc‐Nez (Pas‐de‐Calais,France)

Cliff retreat in northern Boulonnais is described. The distribution of the amount of retreat is related to structural and topographic factors. Both control the runoff–infiltration balance and therefore the mechanical behaviour of the rocks, which determines the modes of failure. The spatial variability of the retreat rate is explained, but predicting the temporal variability of the retreat rate, which is central to risk management, is much more difficult. Rainfall and piezometric surface data enhanced a ‘piston flow’ mechanism during November 2000. The result of its occurrence on the stability of the cliff and conditions of its recurrence are examined with a view to better understanding the rate of recession of coastal cliffs and wiser management of risk. Copyright © 2005 John Wiley & Sons, Ltd.