Hydrological processes of a rainforest headwater swamp from natural chemical tracing in Nsimi watershed,Cameroon

The hydrological role of a headwater swamp in a tropical rainforest is studied using chloride mass balance (CMB) and end‐member mixing analysis. There are three main contributions to streamflow: (1) the hillside bedrock aquifer, (2) overland flow from the swamp during storm events and (3) groundwater flow from the swamp aquifer. Before rainfall events of the wet season, the pre‐event water comprises a mix of 80% of bedrock aquifer and 20% of swamp aquifer. During storms, the relative contribution of overland flow increases according to the rainfall intensity and the initial saturation rate of the pre‐event water reservoirs. The yearly contribution of overland flow from the swamp to the stream is about 31%. The relationship between the swamp and the stream fluctuates with space and time. Generally, the swamp is drained by the stream; however, at the end of long dry seasons, after the first rains, indirect recharge occurs from the stream to the swamp with a hydraulic gradient inversion in the swamp aquifer. The net contribution of the swamp aquifer to the stream is only 4%, which is much lower than the hillside aquifer contribution of about 65%. Recharge on the swamp being very low, these results suggest that, except for a few storms at the end of the dry season, the Nsimi swamp does not contribute to flood attenuation. Evapotranspiration is higher on the hillside than in the swamp. Nevertheless, depletion of water stored within the swamp is dominated by evaporation rather than by its contribution to streamflow. The export of solutes through swamp groundwater flow below the weir is low (<7%). Nevertheless, the swamp is the most active area of weathering in the watershed. Copyright © 2011 John Wiley & Sons, Ltd.     

Statistics of the variations of the high-energy electron population between 7 and 28 jovian radii as measured by the Galileo spacecraft

Recent measurements of the high-energy, omni-directional electron environment by the Galileo spacecraft Energetic Particle Detector (EPD) have been analyzed in the range from 7 to 28 Jupiter radii. 10-min averages of these data between Jupiter orbit insertion in 1995 to the end of the mission have been analyzed to provide estimates of the electron differential fluxes at 1.5, 2, and 11 MeV in the jovian equatorial plane as a function of radial distance. These data provide a long term picture of the variations in the high-energy electron environment over the ∼8 years of the Galileo mission. This paper reviews those measurements and the statistics associated with them for the 8 year period. In general, the data variations are well behaved with variations being within a factor of ∼2 of a median value at a given distance from Jupiter. These results are analyzed in detail and the orbit variations discussed in the context of the overall data set. The results of this analysis of the long-term statistical variations in high-energy electron fluxes are directly applicable to models that estimate the effects of the radiation environment on Jupiter's moons and their atmospheres as they permit estimates of the possible range of radiation effects that might be expected.     

Pesticide residues in South African marine animals

Analyses of organochlorine pesticides in South African marine animals living far from any obvious source of contamination reveal surprisingly high values.     

A soil‐water‐balance approach to quantify groundwater recharge from irrigated cropland in the North China Plain

Rapidly depleting unconfined aquifers are the primary source of water for irrigation on the North China Plain. Yet, despite its critical importance, groundwater recharge to the Plain remains an enigma. We introduce a one‐dimensional soil‐water‐balance model to estimate precipitation‐ and irrigation‐generated areal recharge from commonly available crop and soil characteristics and climate data. To limit input data needs and to simplify calculations, the model assumes that water flows vertically downward under a unit gradient; infiltration and evapotranspiration are separate, sequential processes; evapotranspiration is allocated to evaporation and transpiration as a function of leaf‐area index and is limited by soil‐moisture content; and evaporation and transpiration are distributed through the soil profile as exponential functions of soil and root depth, respectively. For calibration, model‐calculated water contents of 11 soil‐depth intervals from 0 to 200 cm were compared with measured water contents of loam soil at four sites in Luancheng County, Hebei Province, over 3 years (1998–2001). Each 50‐m² site was identically cropped with winter wheat and summer maize, but received a different irrigation treatment. Average root mean‐squared error between measured and model‐calculated water content of the top 180 cm was 4·2 cm, or 9·3% of average total water content. In addition, model‐calculated evapotranspiration compared well with that measured by a large‐scale lysimeter. To test the model, 12 additional sites were simulated successfully. Model results demonstrate that drainage from the soil profile is not a constant fraction of precipitation and irrigation inputs, but rather the fraction increases as the inputs increase. Because this drainage recharges the underlying aquifer, improving irrigation efficiency by reducing seepage will not reverse water‐table declines. Copyright © 2003 John Wiley & Sons, Ltd.     

Metamorphic grade of organic matter in six unequilibrated ordinary chondrites

Abstract— The thermal metamorphism grade of organic matter (OM) trapped in 6 unequilibrated ordinary chondrites (UOCs) (Semarkona [LL 3.0], Bishunpur [L/LL 3.1], Krymka [LL 3.1], Chainpur [LL 3.4], Inman [L/LL 3.4], and Tieschitz [H/L 3.6]) has been investigated with Raman spectroscopy in the region of the first‐order carbon bands. The carbonaceous chondrite Renazzo (CR2) was also investigated and used as a reference object for comparison, owing to the fact that previous studies pointed to the OM in this meteorite as being the most pristine among all chondrites. The results show that the OM thermal metamorphic grade: 1) follows the hierarchy Renazzo << Semarkona << other UOCs; 2) is well correlated to the petrographic type of the studied objects; and 3) is also well correlated with the isotopic enrichment δ¹⁵N. These results are strikingly consistent with earlier cosmochemical studies, in particular, the scenario proposed by Alexander et al. (1998). Thermal metamorphism in the parent body appears as the main evolution process of OM in UOCs, demonstrating that nebular heating was extremely weak and that OM burial results in the destabilization of an initial isotopic composition with high δD and δ¹⁵N. Furthermore, the clear discrimination between Renazzo, Semarkona, and other UOCs shows: 1) Semarkona is a very peculiar UOC—by far the most pristine; and 2) Raman spectroscopy is a valid and valuable tool for deriving petrographic sub‐types (especially the low ones) that should be used in the future to complement current techniques. We compare our results with other current techniques, namely, induced thermo‐luminescence and opaques petrography. Other results have been obtained. First, humic coals are not strictly valid standard materials for meteoritic OM but are helpful in the study of evolutionary trends due to thermal metamorphism. Second, terrestrial weathering has a huge effect on OM structure, particularly in Inman, which is a find. Finally, the earlier statement that fine‐grained chondrule rims and matrix in Semarkona could be the source of smectite‐rich IDPs is not valid, given the different degree of structural order of their OM.