The impact of atmospheric sodium on erodibility of clay in a coastal Mediterranean region

 Heavy rainfalls, between 25 and 100 mm·h–1, were simulated on Pliocene/Quaternary sediments. To reproduce the heterogeneity of natural environments, 231 small plots of various sizes (between 2.5 and 3.5 m²; mean: about 3 m²) were used. The duration of all simulations was 1 h. We used water that had been collected during natural rainfall. The concentration of clay particles in the sheet wash depended upon the concentration of dissolved sodium in the wash (for about 42%) and of the sheet wash quantity (for about 37%). Under natural water conditions colloidal matter, like clay minerals, is charged negatively and therefore is destabilized by metal cations such as in the case of Na⁺. Results suggest that relatively higher concentrations of montmorrillonite were related to higher concentrations of sodium as opposed to illite and kaolinite. Microflakes of up to 25 μ were observed to vary between face-to-edge and face-to-face modes (competition between protons and other cations). The concentration of dissolved sodium (Na⁺) in the runoff water depends on water and sodium balances such as atmospheric input, infiltration, evaporation and surface water runoff. The reduction of vegetation cover increases the amount of salt and amorphous matter in/on the topsoil between heavy rainfall generations. The best predictor to explain montmorillonite, illite and kaolinite in % of mineral clay-sized matter in the surface water runoff (sheet wash) is the percentage of each clay mineral in the topsoil. As opposed to illite and kaolinite, more sheet wash indicate for montmorillonite relatively higher concentrations in the wash. The results of model simulations were confirmed on different field plots of about 1 ha and small catchments during natural heavy rainfall events. Models can also be used to understand and to better simulate sheet, rill and gully erosion, micropedimentation; and pedimentation.     

Investigating strong ground-motion variability using analysis of variance and two-way-fit plots

A statistical method to quantitatively assess the relative importance of unmodelled site and source effects on the observed variability (σ) in ground motions is presented. The method consists of analysis of variance (ANOVA) using the computed residuals with respect to an empirical ground-motion model for strong-motion records of various earthquakes recorded at a common set of stations. ANOVA divides the overall variance (σ ²) into the components due to site and source effects (respectively σ _S ² and σ _E ²) not modelled by the ground-motion model plus the residual variance not explained by these effects (σ _R ²). To test this procedure, four sets of observed strong-motion records: two from Italy (Umbria-Marche and Molise), one from the French Antilles and one from Turkey, are used. It is found that for the data from Italy, the vast majority of the observed variance is attributable to unmodelled site effects. In contrast, the variation in ground motions in the French Antilles and Turkey data is largely attributable, especially at short periods, to source effects not modelled by the ground-motion estimation equations used.     

Influence of landscape and hydrological factors on stream–air temperature relationships at regional scale

Identifying the main controlling factors of the stream temperature (Tw) variability is important to target streams sensitive to climate and other drivers of change. The thermal sensitivity (TS), based on relationship between air temperature (Ta) and Tw, of a given stream can be used for quantifying the streams sensitivity to future climate change. This study aims to compare TS for a wide range of temperate streams located within a large French catchment (110,000 km²) using 4 years of hourly data (2008–2012) and to cluster stations sharing similar thermal variabilities and thereby identify environmental key drivers that modify TS at the regional scale. Two successive classifications were carried out: (a) first based on Ta–Tw relationship metrics including TS and (b) second to establish a link between a selection of environmental variables and clusters of stations. Based on weekly Ta–Tw relationships, the first classification identified four thermal regimes with differing annual Tw in terms of magnitude and amplitudes in comparison with Ta. The second classification, based on classification and regression tree method, succeeded to link each thermal regime to different environmental controlling factors. Streams influenced by both groundwater inflows and shading are the most moderated with the lowest TS and an annual amplitude of Tw around half of the annual amplitude of Ta. Inversely, stations located on large streams with a high distance from source and not (or slightly) influenced by groundwater inflows nor shading showed the highest TS, and so, they are very climate sensitive. These findings have implications for guiding river basin managers and other stakeholders in implementing thermal moderation measures in the context of a warming climate and global change.     

Innovative Contaminant Mass Flux Monitoring in an Aquifer Subject to Tidal Effects

Exposure from groundwater contamination to aquatic receptors residing in receiving surface water is dependent upon the rate of contaminated groundwater discharge. Characterization of groundwater fluxes is challenging, especially in coastal environments where tidal fluctuations result in transient groundwater flows towards these receptors. This can also be further complicated by the high spatial heterogeneity of subsurface deposits enhanced by anthropogenic influences such as the mixing of natural sediments and backfill materials, the presence of subsurface built structures such as sheet pile walls or even occurrence of other sources of contaminant discharge. In this study, the finite volume point dilution method (FVPDM) was successfully used to characterize highly transient groundwater flows and contaminant mass fluxes within a coastal groundwater flow system influenced by marked tides. FVPDM tests were undertaken continuously for more than 48 h at six groundwater monitoring wells, in order to evaluate groundwater flow dynamics during several tide cycles. Contaminant concentrations were measured simultaneously which allowed calculating contaminant mass fluxes. The study highlighted the importance of the aquifer heterogeneity, with groundwater fluxes ranging from 10⁻⁷ to 10⁻³ m/s. Groundwater flux monitoring enabled a significant refinement of the conceptual site model, including the fact that inversion of groundwater fluxes was not observed at high tide. Results indicated that contaminant mass fluxes were particularly higher at a specific monitoring well, by more than three orders of magnitude, than at other wells of the investigated aquifer. This study provided crucial information for optimizing further field investigations and risk mitigation measures.     

Influence of morphological changes on suspended sediment dynamics in a macrotidal estuary: diachronic analysis in the Seine Estuary (France) from 1960 to 2010

Ocean Dynamics - Estuaries are subject to extensive morphological changes through human activities, such as deepening and narrowing via dredging and channelization. The estuary sediment load,...     

Monitoring Sea Level in the Coastal Zone with Satellite Altimetry and Tide Gauges

We examine the issue of sustained measurements of sea level in the coastal zone, first by summarizing the long-term observations from tide gauges, then showing how those are now complemented by improved satellite altimetry products in the coastal ocean. We present some of the progresses in coastal altimetry, both from dedicated reprocessing of the radar waveforms and from the development of improved corrections for the atmospheric effects. This trend towards better altimetric data at the coast comes also from technological innovations such as Ka-band altimetry and SAR altimetry, and we discuss the advantages deriving from the AltiKa Ka-band altimeter and the SIRAL altimeter on CryoSat-2 that can be operated in SAR mode. A case study along the UK coast demonstrates the good agreement between coastal altimetry and tide gauge observations, with root mean square differences as low as 4 cm at many stations, allowing the characterization of the annual cycle of sea level along the UK coasts. Finally, we examine the evolution of the sea level trend from the open to the coastal ocean along the western coast of Africa, comparing standard and coastally improved products. Different products give different sea level trend profiles, so the recommendation is that additional efforts are needed to study sea level trends in the coastal zone from past and present satellite altimeters. Further improvements are expected from more refined processing and screening of data, but in particular from the constant improvements in the geophysical corrections.     

An information-based criterion to measure pixel-level thematic uncertainty in land cover classifications

Traditional accuracy assessment of satellite-derived maps relies on a confusion matrix and its associated indices built by comparing ground truth observations and classification outputs at specific locations. These indices may be applied at the map-level or at the class level. However, the spatial variation of the accuracy is not captured by those statistics. Pixel-level thematic uncertainty measures derived from class membership probability vectors can provide such spatially explicit information. In this paper, a new information-based criterion—the equivalent reference probability—is introduced to provide a synoptic thematic uncertainty measure that has the advantage of taking the maximum probability value into account while committing for the full set of probabilities. The fundamental theoretical properties of this indicator was first highlighted and its use was afterwards demonstrated on a real case study in Belgium. Results showed that the proposed approach positively correlates with the quality of the classification and is more sensitive than the classical maximum probability criterion. As this information-based criterion can be used for providing spatially explicit maps of thematic uncertainty quality, it provides substantial additional information regarding classification quality compared to conventional quality measures. Accordingly, it proved to be useful both for end-users and map producers as a way to better understand the nature of the errors and to subsequently improve the map quality.     

Effects of persistent organic pollutants on the thyroid function of the European sea bass (Dicentrarchus labrax) from the Aegean sea, is it an endocrine disruption?

We evaluated the alterations of organochlorinated compounds such as polychlorobiphenyls (PCB), dichloro-diphenyl-dichloroethylene (DDE) and dichloro-diphenyl-trichloroethane (DDT) on the thyroid in wild and cultured sea bass (Dicentrarchus labrax) at environmental concentrations. These compounds influence the endocrine system of many fish species and are qualified as endocrine disruptors. The thyroid seems to be a target organ. Two alteration endpoints: the thyroid histology and the muscular thyroid hormone concentrations, were used simultaneously.High concentrations in PCBs and DDT were detected in muscles, supporting the idea that the Mediterranean fauna could be more polluted than the Atlantic fauna. The high abundance of DDE indicates a progressive degradation of remnant DDT load and the absence of new inputs in this area. Aquaculture sea bass shows a significant higher amount of pollutants on fresh weight basis (especially PCBs) in their muscles compared to the wild sea bass. Those differences may be related mainly to the contaminations of diet.Thyroid parameters vary between wild and aquaculture sea bass, wild sea bass were characterized by higher follicle diameters, epithelial cell heights and muscular T₄ concentrations. A significant relationship between persistent organic pollutants (muscular PCBs and DDT concentration) and the different thyroid parameters (diameters of follicles, epithelial cell heights and muscular T₄ levels) could be observed, which support the hypothesis that these compounds have an adverse impact on thyroid morphometry and function.     

Simulated asteroid materials based on carbonaceous chondrite mineralogies

A set of high‐fidelity simulated asteroid materials, or simulants, was developed based on the mineralogy of carbonaceous chondrite meteorites. Three varieties of simulant were developed based on CI1 chondrites (typified by Orgueil), CM2 chondrites (typified by Murchison), and CR2/3 chondrites (multiple samples). The simulants were designed to replicate the mineralogy and physical properties of the corresponding meteorites and anticipated asteroid surface materials as closely as is reasonably possible for bulk amounts. The simulants can be made in different physical forms ranging from larger cobbles to fine‐grained regolith. We analyzed simulant prototypes using scanning electron microscopy, X‐ray fluorescence, reflectance spectroscopy at ambient conditions and in vacuum, thermal emission spectroscopy in a simulated asteroid environment chamber, and combined thermogravimetry and evolved gas analysis. Most measured properties compare favorably to the reference meteorites and therefore to predicted volatile‐rich asteroid surface materials, including boulders, cobbles, and fine‐grained soils. However, there were also discrepancies, and mistakes were made in the original mineral formulations that will be updated in the future. The asteroid simulants are available to the community from the nonprofit Exolith Lab at UCF, and the mineral recipes are freely published for other groups to reproduce and modify as they see fit.     

Water abundance in the Tagish Lake meteorite from TGA and IR spectroscopy: Evaluation of aqueous alteration

Here, we evaluate the extent of aqueous alteration among five pristine specimens of the ungrouped Tagish Lake carbonaceous chondrite (TL5b, TL11h, TL11i, TL4, and TL10a) using thermogravimetric analysis (TGA) and infrared (IR) transmission spectroscopy. Both TGA and IR spectroscopy have proven to be reliable methods for determining the extent of aqueous alteration among different carbonaceous chondrites, in particular the CM chondrites (e.g., Garenne et al. 2014), with which Tagish Lake shares some affinities. Using these two methods, our goal is to incorporate TL4 and TL10a into the known alteration sequence of TL5b < TL11h < TL11i (Herd et al. 2011; Blinova et al. 2014a). This study highlights the compositional variability of the Tagish Lake specimens, which we ascribe to its brecciated nature. Our TGA and IR spectroscopy results are congruent with the reported alteration sequence, allowing us to introduce the TL4 and TL10a specimens in the following order: TL4 < TL5b ≤ TL10a < TL 11h < TL11i. Notably, these two specimens appear to be similar to the least altered lithologies previously reported, and the alteration of Tagish Lake is similar to that experienced by lesser altered members of the CM chondrites (>CM1.6). Based on these findings, Tagish Lake could be considered a 1.6–2.0 ungrouped carbonaceous chondrite. Visible and near‐IR reflectance measurements of Tagish Lake were also acquired in this study to revisit the Tagish Lake parent body connection. While other studies have paired Tagish Lake with D‐ and T‐type asteroid parent bodies, the reflectance spectra acquired in this study are variable among the different Tagish Lake specimens in relation to their alteration sequences; results match with spectra characteristic of C‐, X‐, Xc‐, and D‐type asteroids. The heterogeneity of Tagish Lake coupled with its low albedo makes the parent body connection a challenge.