Modal mineralogy of carbonaceous chondrites by X‐ray diffraction and Mössbauer spectroscopy

Abstract— Carbonaceous chondrites are among the most analyzed geological materials on Earth. However, despite this attention, and unlike most terrestrial rocks, little is known on the abundance of individual phases within them. Here, we show how a combination of several novel X‐ray diffraction (XRD) techniques (including a high‐brightness X‐ray MicroSource®), and Mössbauer spectroscopy, allows a complete modal mineralogy to be ascertained from even the most highly unequilibrated, fine‐grained chondrites for all minerals of abundance >1 wt%. Knowledge of the modal mineralogy of a sample also allows us to calculate grain density. We analyzed Allende, Murchison, Tagish Lake, and Orgueil. Based on our modal data, the grain density estimates for Allende, Murchison, and Orgueil are close to literature values. In the case of Tagish Lake, there is no published grain density, although a bulk density measurement does exist. Taking our estimate of grain density, and the measured bulk density, we calculate an exceptionally high porosity of 41% for this meteorite, similar to some chondritic IDPs and in line with a porosity calculated from an entry model for the Tagish Lake fireball. Although it is an oxidized CV, magnetite is present in Allende at a level of <0.5 wt% or <0.3 vol%, a result that is substantiated by several other instrumental studies. This may be an oxidized meteorite, but that oxidation is not manifested in abundant magnetite. In addition, we note appreciable fayalitic olivine in Orgueil, detected by both XRD and Mössbauer. We employed MicroSource® XRD to look at heterogeneity in mineral abundance in Orgueil and found substantial variation, with phyllosilicates varying inversely with olivine. The data suggest that Orgueil was initially composed primarily of anhydrous materials, which have been partially, but not completely, altered. Although the data are preliminary, comparison between our XRD modal assessment, bulk chemistry, grain density, and Mössbauer data, suggests that our estimates of mineral abundance are robust. The advent of MicroSource® XRD allows similar modal data to be acquired from samples as small as a few hundred micrograms.     

X-Ray Excitation of Molecular Hydrogen and [Fe II] Emission in NGC 1068

NGC 1068 is a source of luminous emission in the near-infrared lines of molecular hydrogen and [Fe II]. Although these emission lines are commonly attributed to shocks, I show that in NGC 1068 it is quite plausible that they arise in the X-Ray Dissociation Region (XDR) produced by X-ray irradiation of the gas in the disk by the powerful active nucleus. This mechanism naturally produces the observed size scale of the H2 emission. I will also briefly discuss the implications of the observations of the pure rotation lines of H2 with ISO (Lutz, this workshop).     

The frequency of wide binaries among the southern barium stars

Summary All of the barium and marginal barium stars in the 1972 MacConnell, Frey, and Upgren (1972: MFU) list of such objects which are located south of the celestial equator were examined for visual duplicity. Over 200 objects were observed, and a total of six possible candidates for wide pair visual binaries were found. Of these, four are most likely optical in nature. These data suggest that the incidence of wide binaries among barium stars is of the order of 1%.     

Recession of Martian north polar cap: 1979–1980 Viking observations

The 1979–1980 regression curve for the north polar cap of Mars, determined from Viking orbiter images, is compared to Viking observations of the same season 1 (Martin) year earlier and to telescopic observations. Differences between the two years cannot unambigously be attributed to dynamical effects because of uncertainties introduced by limited longitudinal coverage.     

Correction to: a thin viscous sheet model for continental deformation

Summary. The governing equation derived by England & M c Kenzie for the deformation of a thin viscous shell contains an error. We give the correct derivation here and correct those figures where the change makes a visible difference. The correct results differ quantitatively from those of England & M c Kenzie but their conclusions are not affected.     

Algebraic dispersion fields on ternary diagrams

Previously published dispersion fields on ternary diagrams have been constructed variously, and their derivations have not been well-specified. Here an explanation of their bases is provided through an algebraic method for calculating two related forms, designated thesilhouette dispersion field and thegirth dispersion field. Such dispersion estimates can be made more precise by specifying the percentage of samples that fall within the field. Because such fields represent a mechanistic rather than a probabilistic approach, their use in comparison of sample sets must be viewed with caution.     

Gamma-ray detectors (>10MeV)

Photons in the energy region above 10 MeV can provide unique information about the highest energy particles produced in solar flares. Measurements of the energy spectra, temporal behavior and anisotropies of the incident photons, can give valuable insights into the particle acceleration process. In this paper we review the detection techniques used at these energies, typical instruments which use these techniques, and future solar missions both actual and potential.