Carbon dioxide on the satellites of Saturn: Results from the Cassini VIMS investigation and revisions to the VIMS wavelength scale

Several of the icy satellites of Saturn show the spectroscopic signature of the asymmetric stretching mode of C-O in carbon dioxide (CO₂) at or near the nominal solid-phase laboratory wavelength of 4.2675 μm (2343.3 cm⁻¹), discovered with the Visible-Infrared Mapping Spectrometer (VIMS) on the Cassini spacecraft. We report here on an analysis of the variation in wavelength and width of the CO₂ absorption band in the spectra of Phoebe, Iapetus, Hyperion, and Dione. Comparisons are made to laboratory spectra of pure CO₂, CO₂ clathrates, ternary mixtures of CO₂ with other volatiles, implanted and adsorbed CO₂ in non-volatile materials, and ab initio theoretical calculations of CO₂ * nH₂O. At the wavelength resolution of VIMS, the CO₂ on Phoebe is indistinguishable from pure CO₂ ice (each molecule’s nearby neighbors are also CO₂) or type II clathrate of CO₂ in H₂O. In contrast, the CO₂ band on Iapetus, Hyperion, and Dione is shifted to shorter wavelengths (typically ∼4.255 μm (∼2350.2 cm⁻¹)) and broadened. These wavelengths are characteristic of complexes of CO₂ with different near-neighbor molecules that are encountered in other volatile mixtures such as with H₂O and CH₃OH, and non-volatile host materials like silicates, some clays, and zeolites. We suggest that Phoebe’s CO₂ is native to the body as part of the initial inventory of condensates and now exposed on the surface, while CO₂ on the other three satellites results at least in part from particle or UV irradiation of native H₂O plus a source of C, implantation or accretion from external sources, or redistribution of native CO₂ from the interior.The analysis presented here depends on an accurate VIMS wavelength scale. In preparation for this work, the baseline wavelength calibration for the Cassini VIMS was found to be distorted around 4.3 μm, apparently as a consequence of telluric CO₂ gas absorption in the pre-launch calibration. The effect can be reproduced by convolving a sequence of model detector response profiles with a deep atmospheric CO₂ absorption profile, producing distorted detector profile shapes and shifted central positions. In a laboratory blackbody spectrum used for radiance calibration, close examination of the CO₂ absorption profile shows a similar deviation from that expected from a model. These modeled effects appear to be sufficient to explain the distortion in the existing wavelength calibration now in use. A modification to the wavelength calibration for 13 adjacent bands is provided. The affected channels span about 0.2 μm centered on 4.28 μm. The maximum wavelength change is about 10 nm toward longer wavelength. This adjustment has implications for interpretation of some of the spectral features observed in the affected wavelength interval, such as from CO₂, as discussed in this paper.     

TitaniQ under pressure: the effect of pressure and temperature on the solubility of Ti in quartz

Quartz and rutile were synthesized from silica-saturated aqueous fluids between 5 and 20 kbar and from 700 to 940°C in a piston-cylinder apparatus to explore the potential pressure effect on Ti solubility in quartz. A systematic decrease in Ti-in-quartz solubility occurs between 5 and 20 kbar. Titanium K-edge X-ray absorption near-edge structure (XANES) measurements demonstrate that Ti⁴⁺ substitutes for Si⁴⁺ on fourfold tetrahedral sites in quartz at all conditions studied. Molecular dynamic simulations support XANES measurements and demonstrate that Ti incorporation onto fourfold sites is favored over interstitial solubility mechanisms. To account for the P–T dependence of Ti-in-quartz solubility, a least-squares method was used to fit Ti concentrations in quartz from all experiments to the simple expression

加拿大不列颠哥伦比亚省温哥华岛纳奈莫群的帆翼龙类化石

An unusual jaw found in a calcite nodule from Collishaw Point, Hornby Island, British Columbia (off the east coast of Vancouver Island) represents the first definitive pterosaur found in British Columbia, and the first istiodactylid from Canada.     

Variations in long term wind speed during different decades in Arabian Sea and Bay of Bengal

A study has been carried out by comparing the extreme wind speeds estimated based on NCEP/NCAR reanalysis data for 100 years return period using Fischer Tippet-1 (commonly known as Gumbel) and Weibull distributions for three locations (off Goa, Visakhapatnam and Machilipatnam) in the north Indian Ocean. The wind dataset for Goa is compared with that from ERA-40 data. For higher wind speeds (12–20m s⁻¹), NCEP wind speed has higher percentage of occurrence than that of ERA-40. Analysis has shown slight upward trend in the annual maximum wind for location off Machilipatnam with an increase of 1.2 cm s⁻¹ per year and a decreasing trend of −1.3 cm s⁻¹ per year in the case of Goa. The Weibull distribution with shape parameter 2 fits the annual maximum wind data better than FT-1 distribution.     

New Urbanist developments in flood-prone areas: safe development,or safe development paradox?

Government policies intended to reduce flood losses can increase the potential for catastrophe by stimulating development inside the floodplain, a phenomenon referred to as the “safe development paradox.” New Urbanist design has the potential to both exacerbate and alleviate flood risks. Because they are built at relatively high densities, New Urbanist developments can exacerbate risk by placing more people and property in harm’s way. Conversely, New Urbanist design features theoretically better enable designers of New Urbanist developments to avoid floodplain portions of project sites than designers of conventional subdivisions. Using a sample of New Urbanist developments in the US that contain floodplain portions within their boundaries, this paper focuses on whether and why these developments locate built structures inside the floodplain. The authors find that roughly 30% of the developments locate structures inside the floodplain, and that the odds of locating structures inside the floodplain increase with the proportion of the project site located inside the floodplain and decrease with the presence of government policies that prohibit residential development in the floodplain. The authors also identify confusion among government planners regarding the distinction between pre and postconstruction floodplain boundaries. A subset of New Urbanist developments is found to have built structures located outside the postconstruction floodplain boundary, but inside the preconstruction floodplain boundary. This finding is cited as an example of the “safe development paradox” in action. The authors recommend changes in New Urbanist design codes and local government floodplain management to increasingly direct new development away from the floodplain.     

The water impacts of climate change mitigation measures

A variety of proposed activities to mitigate greenhouse gas emissions will impact on scarce water resources, which are coming under increasing pressure in many countries due to population growth and shifting weather patterns. However, the integrated analysis of water and carbon impacts has been given limited attention in greenhouse mitigation planning. In this Australian case study, we analyse a suite of 74 mitigation measures ranked as highest priority by one influential analysis, and we find that they have highly variable consequences for water quantity. We find: (1) The largest impacts result from land-based sequestration, which has the potential to intercept large quantities of water and reduce catchment yields, estimated to exceed 100 Mm³/MtCO₂-e of carbon mitigated (100,000 l per tonne CO₂-e). (2) Moderate impacts result from some renewable power options, including solar thermal power with a water cost estimated at nearly 4 Mm³/MtCO₂-e. However, the water impacts of solar thermal power facilities could be reduced by designing them to use existing power-related water supplies or to use air or salt-water cooling. (3) Wind power, biogas, solar photovoltaics, energy efficiency and operational improvements to existing power sources can reduce water demand through offsetting the water used to cool thermal power generation, with minor savings estimated at 2 Mm³/MtCO₂-e and amounting to nearly 100 Mm³ of water saved in Australia per annum in 2020. This integrated analysis significantly changes the attractiveness of some mitigation options, compared to the case where water impacts are not considered.     

Wind-Tunnel Simulation of the Wake of a Large Wind Turbine in a Stable Boundary Layer. Part 1: The Boundary-Layer Simulation

Measurements have been made in both a neutral and a stable boundary layer as part of an investigation of the wakes of wind turbines in an offshore environment, in the EnFlo stratified flow wind tunnel. The working section is long enough for the flow to have become very nearly invariant with streamwise distance. In order to be systematic, the flow profile generators of Irwin-type spires and surface roughness were the same for both neutral and stable conditions. Achieving the required profiles by adjusting the flow generators, even for neutral flow, is a highly iterative art, and the present results indicate that it will be no less iterative for a stable flow (as well as there being more conditions to meet), so this was not attempted in the present investigation. The stable-case flow conformed in most respects to Monin–Obukhov similarity in the surface layer. A linear temperature profile was applied at the working section inlet, resulting in a near-linear profile in the developed flow above the boundary layer and ‘strong’ imposed stability, while the condition at the surface was ‘weak’. Aerodynamic roughness length (mean velocity) was not affected by stability even though the roughness Reynolds number ${<}1$ , while the thermal roughness length was much smaller, as is to be expected. The neutral case was Reynolds-number independent, and by inference, the stable case was also Reynolds-number independent.     

Scales and causes of heterogeneity in bars in a large multi‐channel river: Río Paraná, Argentina

To date, published studies of alluvial bar architecture in large rivers have been restricted mostly to case studies of individual bars and single locations. Relatively little is known about how the depositional processes and sedimentary architecture of kilometre‐scale bars vary within a multi‐kilometre reach or over several hundreds of kilometres downstream. This study presents Ground Penetrating Radar and core data from 11, kilometre‐scale bars from the Río Paraná, Argentina. The investigated bars are located between 30 km upstream and 540 km downstream of the Río Paraná – Río Paraguay confluence, where a significant volume of fine‐grained suspended sediment is introduced into the network. Bar‐scale cross‐stratified sets, with lengths and widths up to 600 m and thicknesses up to 12 m, enable the distinction of large river deposits from stacked deposits of smaller rivers, but are only present in half the surface area of the bars. Up to 90% of bar‐scale sets are found on top of finer‐grained ripple‐laminated bar‐trough deposits. Bar‐scale sets make up as much as 58% of the volume of the deposits in small, incipient mid‐channel bars, but this proportion decreases significantly with increasing age and size of the bars. Contrary to what might be expected, a significant proportion of the sedimentary structures found in the Río Paraná is similar in scale to those found in much smaller rivers. In other words, large river deposits are not always characterized by big structures that allow a simple interpretation of river scale. However, the large scale of the depositional units in big rivers causes small‐scale structures, such as ripple sets, to be grouped into thicker cosets, which indicate river scale even when no obvious large‐scale sets are present. The results also show that the composition of bars differs between the studied reaches upstream and downstream of the confluence with the Río Paraguay. Relative to other controls on downstream fining, the tributary input of fine‐grained suspended material from the Río Paraguay causes a marked change in the composition of the bar deposits. Compared to the upstream reaches, the sedimentary architecture of the downstream reaches in the top ca 5 m of mid‐channel bars shows: (i) an increase in the abundance and thickness (up to metre‐scale) of laterally extensive (hundreds of metres) fine‐grained layers; (ii) an increase in the percentage of deposits comprised of ripple sets (to >40% in the upper bar deposits); and (iii) an increase in bar‐trough deposits and a corresponding decrease in bar‐scale cross‐strata (<10%). The thalweg deposits of the Río Paraná are composed of dune sets, even directly downstream from the Río Paraguay where the upper channel deposits are dominantly fine‐grained. Thus, the change in sedimentary facies due to a tributary point‐source of fine‐grained sediment is primarily expressed in the composition of the upper bar deposits.     

Assessment of the effects of climate and land cover changes on river discharge and sediment yield,and an adaptive spatial planning in the Jakarta region

In Jakarta, climate change has been detected through rising air temperatures, increased intensity of rainfall in the wet season, and sea level rise. The coupling of such changes with local anthropogenic driven modifications in the environmental setting could contribute to an increased probability of flooding, due to increase in both extreme river discharge and sedimentation (as a result of erosion in the watersheds above Jakarta and as indicated by sediment yield in the downstream area). In order to respond to the observed and projected changes in river discharge and sediment yield, and their secondary impacts, adaptation strategies are required. A possible adaptation strategy is through policy making in the field of spatial planning. For example, in Indonesia, presidential regulation number 54 year 2008 (Peraturan Presiden Nomor 54 Tahun 2008—Perpres 54/2008) was issued as a reference for the implementation of water and soil conservation. This paper assesses the impact of climate and land cover change on river discharge and sediment yield, as well as the effects of Perpres 54/2008 on that river discharge and sediment yield. The spatial water balance model Spatial Tools for River Basins and Environmental and Analysis of Management Option was used for the runoff computations, whilst the Spatial Decision Assistance of Watershed Sedimentation model was used to simulate erosion, Sediment Delivery Ratio, and sediment yield. The computation period is from January 1901 to December 2005, at the scale of the following watersheds: Ciujung, Cisadane, Ciliwung, and Citarum. During the twentieth century, computed average discharge in the downstream area (near Jakarta) increased between 2.5 and 35 m³/s/month, and sediment yield increased between 1 × 10³ and 42 × 10³ tons/year. These changes were caused by changes in both land cover and climate, with the former playing a stronger role. Based on a computation under a theoretical full implementation of the spatial plan proposed by Perpres 54/2008, river discharge would decrease by up to 5 % in the Ciliwung watershed and 26 % in the Cisadane watershed. The implementation of Perpres 54/2008 could also decrease the sediment yield, by up to 61 and 22 % in the Ciliwung and Cisadane watersheds, respectively. These findings show that the implementation of the spatial plan of Perpres 54/2008 could significantly improve watershed response to runoff and erosion. This study may serve as a tool for assessing the reduction in climate change impacts and evaluating the role of spatial planning for adaptation strategies.