XUV Photometer System (XPS): Improved Solar Irradiance Algorithm Using CHIANTI Spectral Models

Solar soft X-ray (XUV) radiation is highly variable on all time scales and strongly affects Earth’s ionosphere and upper atmosphere; consequently, the solar XUV irradiance is important for atmospheric studies and for space weather applications. Although there have been several recent measurements of the solar XUV irradiance, detailed understanding of the solar XUV irradiance, especially its variability during flares, has been hampered by the broad bands measured in the XUV range. In particular, the simple conversion of the XUV photometer signal into irradiance, in which a static solar spectrum is assumed, overestimates the flare variations by more than a factor of two as compared to the atmospheric response to the flares. To address this deficiency in the simple conversion, an improved algorithm using CHIANTI spectral models has been developed to process the XUV Photometer System (XPS) measurements with its broadband photometers. Model spectra representative of quiet Sun, active region, and flares are combined to match the signals from the XPS and produce spectra from 0.1 to 40 nm in 0.1-nm intervals for the XPS Level 4 data product. The two XPS instruments are aboard NASA’s Solar Radiation and Climate Experiment (SORCE) and Thermosphere, Ionosphere, Mesosphere, Energetics, and Dynamics (TIMED) satellites. In addition, the XPS responsivities have been updated for the latest XPS data processing version. The new XPS results are consistent with daily variations from the previous simple conversion technique used for XPS and are also consistent with spectral measurements made at wavelengths longer than 27 nm. Most importantly, the XPS flare variations are reduced by factors of 2 – 4 at wavelengths shorter than 14 nm and are more consistent, for the first time, with atmospheric response to solar flares. Along with the details of the new XPS algorithm, several comparisons to dayglow and photoelectron measurements and model results are also presented to help verify the accuracy of the new XUV irradiance spectra.     

Identification of perylene in sediments: Occurrence and diagenetic evolution

Perylene and penta-aromatic hydrocarbons were determined in sediments as part of a study that was dedicated to the aquatic ecosystem of Elelenwo Creek (Southern Nigeria) in order to carry out a critical corroboration of occurrence and diagenetic evolution of perylene in the sediments of the creek. The results show that the annual mean levels of Benzo [g, h, i] Perylene ranged from 209.00–245.28 ?g/kg dry weight at the various stations sampled. Meanwhile, Station 3 recorded the highest mean level of 245.28 ?g/kg dry weight. The observed values for total penta-aromatic hydrocarbons were high (787.00–1154.36?g/kg dry weight) in all the stations sampled. In addition, the highest mean value of 1154.36?g/kg dry weight was again recorded at station 3 for the penta-aromatic hydrocarbons. One origin index or concentration ratio of Ip/Ip+BghiP was also used to evaluate the suitability of the penta-aromatic hydrocarbons as a tracer to distinguish between contaminations arising from different sources. The values for the sampling stations therefore ranged from 0.41 to 0.43. A critical appraisal of the PAH index, consequently, suggested that petroleum combustion is the major penta-aromatic hydrocarbon source in sediments of the creek. The PAH group profile shows that perylene was high in the sediments and would pose apparent effects in fauna. The high concentration of perylene in the sediments was also indicative of an in situ biogenic derivation. Furthermore, a concentration of perylene > 10 % of total penta-aromatic hydrocarbons established a credible diagenetic origin.     

Late Quaternary tephra layers around Raoul and Macauley Islands,Kermadec Arc: implications for volcanic sources,explosive volcanism and tephrochronology

A suite of deep‐sea cores were collected along transects up to 100 km across the fore‐arc and back‐arc regions of the predominantly submarine Kermadec arc near Raoul and Macauley islands, southwest Pacific. The cores reveal a macroscopic tephra record extending back >50 ka. This is a significant addition to the dated record of volcanism, previously restricted to fragmented late Holocene records exposed on the two islands. The 27 macroscopic tephra layers display a wide compositional diversity in glass (～50–78 wt% SiO₂). Many tephra layers comprise silicic shards with a subordinate mafic shard population. This could arise from magma mingling and may reflect mafic triggering of the silicic eruptions. Broadly, the glass compositions can be distinguished on diverging high‐K and low‐K trends, most likely arising from different source volcanoes. This distinction is also reflected in the tephra records exposed on Raoul (low‐K) and Macauley (high‐K) islands, the likely source areas. Heterogeneous tephra comprising shards of both high‐ and low‐K affinity, silicic and mafic compositions, and more homogeneous tephra with subordinate outlier shard compositions, are best explained by post‐depositional mixing of separate eruption deposits or contemporaneous eruptions. Evidently, the slow sedimentation rates of the calcareous oozes (～10¹–10² mm ka^?1) were insufficient to adequately separate and preserve closely spaced eruption deposits. This exemplifies the difficulty in assessing eruption frequencies and magmatic trends, and erecting a tephrostratigraphy, using geochemical fingerprinting in such environments. Despite these difficulties, the ca. 5.7 ka Sandy Bay Tephra erupted from Macauley Island can be correlated over a distance of >100 km, extending east and west of the island, showing that the mostly submerged volcanoes are capable of wide tephra dispersal. Hence there is potential for developing chronostratigraphies for the southwest Pacific beyond the region covered by the extensive rhyolite marker beds from the Taupo Volcanic Zone. Copyright © 2011 John Wiley & Sons, Ltd.     

Assessment of surface air warming in northeast China, with emphasis on the impacts of urbanization

Based on homogenized land surface air temperature (SAT) data (derived from China Homogenized Historical Temperature (CHHT) 1.0), the warming trends over Northeast China are detected in this paper, and the impacts of urban heat islands (UHIs) evaluated. Results show that this region is undergoing rapid warming: the trends of annual mean minimum temperature (MMIT), mean temperature (MT), and mean maximum temperature (MMAT) are 0.40 C decade^?1, 0.32 C decade^?1, and 0.23 C decade^?1, respectively. Regional average temperature series built with these networks including and excluding “typical urban stations” are compared for the periods of 1954–2005. Although impacts of UHIs on the absolute annual and seasonal temperature are identified, UHI contributions to the long-term trends are less than 10% of the regional total warming during the period. The large warming trend during the period is due to a regime shift in around 1988, which accounted for about 51% of the regional warming.     

A REVIEW OF PHYSICAL GEOGRAPHY IN SOUTH ASIA

The development of physical geography in South Asia has generally followed the British and European trends. Diverse themes from denudational chronology to palaeoflood geomorphology have attracted the attention of geomorphologists, particularly in the last 25 years. In addition, geographers’ interest in climatology and biogeography became pronounced during the 1980s. Major methodological shifts in the late 1960s in the west have affected geographical studies in South Asia. These shifts include the use of methods of quantification, remote sensing data, and the increased importance of field and laboratory studies. The second notable aspect in recent times is the accelerating interest amongst physical geographers in environmental studies and the applied aspects of the discipline as well as an increased interaction with scientists in cognate fields. An attempt is also made to identify the key research themes that will interest physical geographers in the near future.     

Testing variograms for positive-definiteness

A method based on Bochner's theorem is described for demonstrating the positive-definiteness of variogram models and for generating classes of valid variogram functions.Work performed while on leave at the Centre de Géostatistique et de Morphologie Mathématique.