Mineralogical and spectroscopic investigation of the Tagish Lake carbonaceous chondrite by X‐ray diffraction and infrared reflectance spectroscopy

Abstract– We have carried out a sample‐correlated spectroscopic and mineralogical investigation of samples from seven different collection sites of the Tagish Lake C2 chondrite. Rietveld refinement of high‐resolution powder X‐ray diffraction (XRD) data was used to determine quantitative major mineral abundances. Thermal infrared (400–4500 cm⁻¹, 2.2–25.0 μm) spectra of the same samples were obtained using diffuse (biconical) reflectance infrared Fourier transform spectroscopy (DRIFTS). Our results are in good agreement with previous studies of the mineralogy of the Tagish Lake meteorite; we find however that Tagish Lake is more varied in major mineralogy than has previously been reported. In particular, we observed two new distinct lithologies, an inclusion‐poor magnetite‐ and sulfide‐rich lithology, and a carbonate‐rich, siderite‐dominated lithology in addition to the previously documented carbonate‐rich and carbonate‐poor lithologies. Grain density for each Tagish Lake sample was calculated from the measured mineral modal abundances and known mineral densities. For powders from three originally intact inclusion‐rich samples, the calculated grain density is 2.77 ± 0.05 g cm⁻³, in excellent agreement with those reported in the literature for other intact inclusion‐rich Tagish Lake samples. Tagish Lake disaggregated samples have a significantly higher calculated grain density due to their lower saponite‐serpentine content, likely a result of mineral separation in the meltwater holes from which they were collected; the disaggregated samples may not therefore adequately represent bulk samples of the Tagish Lake meteorite. The predominance of very fine‐grained material in the Tagish Lake samples investigated in this study is expected to produce infrared spectra representative of asteroidal regolith. Gypsum and talc have been found by XRD in powders from the inclusion‐rich, intact Tagish Lake samples in this study, and may have been present in the parent body; if present, these hydrous sulfates would complicate the interpretation of possible hydrated mineral features in asteroid infrared spectra.     

Living the global social experiment: An analysis of public discourse on solar radiation management and its implications for governance

Solar radiation management techniques are a class of geoengineering methods designed to reflect some of the inbound sunlight back into space with the intended effect of arresting further warming of the planet and thus counteracting global warming. In this article we examine current debates on solar radiation management governance, clarifying a number of assumptions that persist and why these require further scrutiny. Building on existing research we articulate a more critical role that the social sciences should be playing in public engagement with solar radiation management. We develop a deliberative focus group methodology that aims to open up deliberation on the technology, focusing explicitly on the kinds of world that its deployment would bring into being. Our findings, based on an analysis of public discourse, suggest that solar radiation management would be publicly acceptable only under very specific, and highly contingent, conditions. Given the sensed implausibility of these conditions being realised in the real world, we set out the implications for solar radiation management governance. We explain why solar radiation management was perceived as likely to create a particular kind of world, one with an increased probability of geopolitical conflict, a new condition of global experimentality, and major threats to democratic governance. How to bring these issues into solar radiation management governance entails an important but challenging role for the social sciences.     

The Contribution of Variability of Lift-induced Upwash to the Uncertainty in Vertical Winds Determined from an Aircraft Platform

Aircraft-based vertical flux measurements fill a gap in the spatial domain for studies of biosphere–atmosphere exchange. To acquire valid flux data, a determination of the deviation from the mean vertical wind, w′, is essential. When using aircraft platforms, flux measurements are subject to systematic and random errors from airflow distortion caused by the lift-induced upwash ahead of the aircraft. Although upwash is typically considered to be a constant quantity over periods used for calculating fluxes, it can vary significantly over short (and longer) periods due to changes in aircraft lift. The characterization of such variations in upwash are of undeniable importance to flux measurements, especially when real-time computations of w′ are required. In this paper, the variability in upwash was compared to the calculated upwash from the model of Crawford et al. (Boundary-Layer Meteorol, 80:79–94, 1996) using data taken during a long-period (phugoid mode) free oscillation of the aircraft. The cyclic variation of lift during the free oscillation offers an ideal scenario in which to acquire in-flight data on the upwash that is present, as well as to test the capability of upwash correction models. Our results indicate that while this model corrects for much of the mean upwash, there can be significant variations in upwash on a time scale that is important to flux measurements. Our results suggest that use of the measured load factor could be an easily implemented operational constraint to minimize uncertainty in w′ due to changing upwash from changing aircraft lift. We estimate, using the phugoid data, and from variations in aircraft attitude and airspeed in flux-measurement configuration, that the uncertainty in w caused by variable upwash is approximately ± 0.05 m s⁻¹.     

Estimation of global temperature trends: what’s important and what isn’t

In this essay we discuss the development of and estimation of uncertainties in the global surface temperature record. We briefly discuss the similarities in and differences between the records from the institutions that produce such series. We then consider the numerous issues that must be addressed to enable accurate estimates to be derived. We consider these in their order of importance with respect to the record: biases in the sea surface temperature data, exposure of land-based thermometers before about 1900, urbanization effects in some series, and, finally, the homogeneity of individual land-based records.     

Simple derivation of Symplectic Integrators with First Order Correctors

In this paper we consider almost integrable systems for which we show that there is a direct connection between symplectic methods and conventional numerical integration schemes. This enables us to construct several symplectic schemes of varying order. We further show that the symplectic correctors, which formally remove all errors of first order in the perturbation, are directly related to the Euler—McLaurin summation formula. Thus we can construct correctors for these higher order symplectic schemes. Using this formalism we derive the Wisdom—Holman midpoint scheme with corrector and correctors for higher order schemes. We then show that for the same amount of computation we can devise a scheme which is of order O(h ⁶)+(² h ²), where is the order of perturbation and h the stepsize. Inclusion of a modified potential further reduces the error to O(h ⁶)+(² h ⁴).This revised version was published online in October 2005 with corrections to the Cover Date.     

Microbiologically influenced corrosion in dairy effluent

In the dairy industry mild steel is used as the construction material for the effluent treatment plants, pipelines, reinforcement in concrete structures etc. The steel exposed to the dairy effluent faces corrosion due to the microbes. In the present study the role of microbes in dairy effluent on the corrosion of mild steel has been investigated. Pseudomonas sp., Streptococcus sp., Micrococcus sp., Bacillus sp., Neisseria sp. and Lactobacillus sp. were identified in dairy effluent. Corrosion rate has been estimated by weight loss measurements and polarization technique. The Fourier transform infrared spectroscopy (FTIR) and X-ray diffractometer (XRD) studies were found helpful in investigating the chemical pathway leading to the formation of corrosion products on the mild steel during fermentation. Initiation of pitting corrosion was noticed on steel specimens by scanning electron microscope (SEM). A mechanism has been proposed for microbiologically influenced corrosion in dairy effluent.     

Effect of aluminum and chromium on the growth and germination of mesquite (Prosopis juliflora swartz.) DC.

Prosopis seeds were grown under controlled environment in solution of aluminum and chromium at different concentration alone as well as combined together. The effect of these metals was studied on seed germination, root length, shoot length, seedling length and dry biomass. Aluminum and chromium alone, and combined together showed no effects on germination and dry biomass. Chromium alone was found toxic to root, shoot and seedling length. However, application of different concentrations of aluminum increased the root, shoot and seedling growth. It may be concluded that aluminum is not as toxic as chromium, and their combined treatment showed the intermediate effect by ameliorating the impact of one another.     

Delving into Allende's dark secrets

What are the strange dark clasts within carbonaceous chondrites? How did they form? And what do they tell us about the early solar system? Mark Sephton, one of a team investigating the Allende meteorite, summarizes their findings.