Geochemistry and magmatic properties of eruption episodes from Haroharo linear vent zone, Okataina Volcanic Centre, New Zealand during the last 10 kyr

Post-10 ka rhyolitic eruptions from the Haroharo linear vent zone, Okataina Volcanic Centre, have occurred from several simultaneously active vents spread over 12 km. Two of the three eruption episodes have tapped multiple compositionally distinct homogeneous magma batches. Three magmas totalling ~8 km³ were erupted during the 9.5 ka Rotoma episode. The most evolved Rotoma magma (SiO₂=76.5–77.9 wt%, Sr=96–112 ppm) erupted from a southeastern vent, and is characterised by a cummingtonite-dominant mineralogy, a temperature of 739±14°C, and fO₂ of NNO+0.52±0.11. The least evolved (SiO₂=75.0–76.4 wt%, Sr=128–138 ppm, orthopyroxene+ hornblende-dominant) Rotoma magma erupted from several vents, and was hotter (764±18°C) and more reduced (NNO+0.40±0.13). The ~11 km³ Whakatane episode occurred at 5.6 ka and also erupted three magmas, each from a separate vent. The most evolved (SiO₂=73.3–76.2 wt%, Sr=88–100 ppm) Whakatane magma erupted from the southwestern (Makatiti) vent and is cummingtonite-dominant, cool (745±11°C), and reduced (NNO+0.34±0.08). The least evolved (SiO₂=72.8–74.1 wt%, Sr=132–134 ppm) magma was erupted from the northeastern (Pararoa) vent and is characterised by an orthopyroxene+ hornblende-dominant mineralogy, temperature of 764±18°C, and fO₂ of NNO+0.40±0.13. Compositionally intermediate magmas were erupted during the Rotoma and Whakatane episodes are likely to be hybrids. A single ~13 km³ magma erupted during the intervening 8.1 ka Mamaku episode was relatively homogeneous in composition (SiO₂=76.1–76.8 wt%, Sr=104–112 ppm), temperature (736±18°C), and oxygen fugacity (NNO+0.19±0.12). Some of the vents tapped a single magma while others tapped several. Deposit stratigraphy suggests that the eruptions alternated between magmas, which were often simultaneously erupted from separate vents. Both effusive and explosive activity alternated, but was predominantly effusive (>75% erupted as lava domes and flows). The plumbing systems which fed the vents are inferred to be complex, with magma experiencing different conditions in the conduits. As the eruption of several magmas was essentially concurrent, the episodes were likely triggered by a common event such as magmatic intrusion or seismic disturbance.     

Assessing climate change impacts on hydrology from an ensemble of regional climate models,model scales and linking methods – a case study on the Lule River basin

This paper investigates how using different regional climate model (RCM) simulations affects climate change impacts on hydrology in northern Europe using an offline hydrological model. Climate change scenarios from an ensemble of seven RCMs, two global climate models (GCMs), two global emissions scenarios and two RCMs of varying resolution were used. A total of 15 climate change simulations were included in studies on the Lule River basin in Northern Sweden. Two different approaches to transfer climate change from the RCMs to hydrological models were tested. A rudimentary estimate of change in hydropower potential on the Lule River due to climate change was also made. The results indicate an overall increase in river flow, earlier spring peak flows and an increase in hydropower potential. The two approaches for transferring the signal of climate change to the hydrological impacts model gave similar mean results, but considerably different seasonal dynamics, a result that is highly relevant for other types of climate change impacts studies.     

Biodegradation of palmarosa oil (green oil) by Serratia marcescens

Biodegradation of oil depends on the nature of the oil, the type of microbial community and a variety of environmental factors. Green oils are being used as consumer goods and as raw materials in industries such as food processing, pharmaceutical and cosmetic. Microbial contaminations of green oils have been the cause of degradation problems. Serratia Marcessens produced cytochrome oxidase, catalase, Dextrose, Lactose, Manose and sorbitol enzymes were the main reason for the degradation af palmarosa oil. Changes of colour and turbidity was also the evidence for green oil degradation by bacteria. More oxygen included protons (0-CH²) group was produced in the presence of bacterial species and the addition of oxygen took place during bacterial degradation of palmarosa oil. The biodegradation of palmarosa oil by Serratia marcescens have been carried out using High Performance Liquid Chromatography, Fourier Transform Infrared Spectroscopy and Nuclear Magnetic spectroscopy analysis. Carboxyl group present in the palmorasa oil is utilised as a sole carbon sources for the Serratia marcescens.     

Identification of perylene in sediments: Occurrence and diagenetic evolution

Perylene and penta-aromatic hydrocarbons were determined in sediments as part of a study that was dedicated to the aquatic ecosystem of Elelenwo Creek (Southern Nigeria) in order to carry out a critical corroboration of occurrence and diagenetic evolution of perylene in the sediments of the creek. The results show that the annual mean levels of Benzo [g, h, i] Perylene ranged from 209.00–245.28 ?g/kg dry weight at the various stations sampled. Meanwhile, Station 3 recorded the highest mean level of 245.28 ?g/kg dry weight. The observed values for total penta-aromatic hydrocarbons were high (787.00–1154.36?g/kg dry weight) in all the stations sampled. In addition, the highest mean value of 1154.36?g/kg dry weight was again recorded at station 3 for the penta-aromatic hydrocarbons. One origin index or concentration ratio of Ip/Ip+BghiP was also used to evaluate the suitability of the penta-aromatic hydrocarbons as a tracer to distinguish between contaminations arising from different sources. The values for the sampling stations therefore ranged from 0.41 to 0.43. A critical appraisal of the PAH index, consequently, suggested that petroleum combustion is the major penta-aromatic hydrocarbon source in sediments of the creek. The PAH group profile shows that perylene was high in the sediments and would pose apparent effects in fauna. The high concentration of perylene in the sediments was also indicative of an in situ biogenic derivation. Furthermore, a concentration of perylene > 10 % of total penta-aromatic hydrocarbons established a credible diagenetic origin.     

The history of Jonsmod 1981–2006

This is a history of shallow sea modelling developments as viewed through the Jonsmod modelling conferences over the past 25 years. The conferences are reviewed, and what emerges is a coherent progression to present-day modelling. We also see advances in computing and oceanographic observation, although these are, of course, incidental to the modelling from the point of view of these conferences.     

The ortho- to para- ratio of H2 in the starburst of NGC 253

We present measurements of several near-infrared emission lines from the nearby galaxy NGC 253. We have been able to measure four H₂ lines across the circumnuclear starburst, from which we estimate the ortho- to para- ratio of excited H₂ to be ∼2. This indicates that the bulk of the H₂ emission arises from photodissociation regions (PDRs), rather than from shocks. This is the case across the entire region of active star formation.
As the H₂ emission arises from PDRs, it is likely that the ratio of H₂ to Brγ (the bright hydrogen recombination line) is a measure of the relative geometry of O and B stars and PDRs. Towards the nucleus of NGC 253 the geometry is deduced to be tightly clustered O and B stars in a few giant H  II regions that are encompassed by PDRs. Away from the nuclear region, the geometry becomes that of PDRs bathed in a relatively diffuse ultraviolet radiation field.
The rotation curves of 1–0 S(1) and Brγ suggest that the ionized gas is tracing a kinetic system different from that of the molecular gas in NGC 253, particularly away from the nucleus.     

A comparison of tropical oceanic heat fluxes determined by airborne eddy correlation and shipboard bulk aerodynamic techniques

Vertical turbulent transports of latent and sensible heat through the tropical marine boundary layer were measured with ship and airborne instruments in the GATE experimental area. The measurements from the two systems are compared for cases of simultaneous sampling in the same locations during undisturbed weather and during the wakes of convective disturbances. The paired average fluxes from the airborne eddy correlation measurements and the shipboard bulk aerodynamic measurements, for undisturbed weather, are related with correlation coefficients in the range of 0.6 to 0.9; the correlations depend primarily on stratifications of the aircraft data according to sampling altitude (15–153 m msl) and flight pattern relative to the mean wind. The agreement between the two types of measurements is best for ship data paired with aircraft samples from the lowest altitudes (15 and 30 m) and from alongwind rather than crosswind flights, as is appropriate since the stationary ships monitor the alongwind characteristics of the turbulence. The use of long (1–3 hr) versus short (10 min) ship samples did not significantly affect the comparability with the aircraft samples during undisturbed periods.The good baseline comparability demonstrated by the undisturbed-weather comparisons was applied to interpret the results from the wakes behind showers. Although these paired measurements were few, not only the sensible heat, but also the latent heat flux was shown to decrease substantially with altitude from 10 m to at least 150 m in the wakes, where the mixing was relatively intense. Variations in the fluxes were much greater at the higher level than nearer the sea surface.     

Die fazielle und paläogeographische Entwicklung der infrakambrischen bis ordovizischen Sedimente im Mittleren Antiatlas um Agdz (S-Marokko)

Zusammenfassung Die Entwicklung des Adoudounien (Infrakambrium) und Géorgien (Unterkambrium) ist im Mittleren Antiatlas durch einen Wechsel von marinen und kontinentalen Sedimenten gekennzeichnet. Wildbachablagerungen an der Basis und an den Beckenrändern werden von marin-marginalen stromatolithischen Karbonaten abgelöst. Ignimbrite belegen wiederholte terrestrische Sedimentation.Mit fluviatilen Sanden und wiederum Stromatolithen und lagunären Karbonaten (mit ersten Trilobiten!) setzt ein zweiter transgressiver Großzyklus ein, der an der Wende Infra-/Unter-Kambrium einen ersten Höhepunkt erreicht. Durch regressive Kleinzyklen charakterisierte Abfolgen leiten zu Sandsteinen über, die als Ablagerungen eines Deltas gedeutet werden.Vom Mittelkambrium bis Ordovizium dominiert marine Schelfsedimentation.

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The formations of Adoudounien (Infra Cambrian) and Géorgien (Lower Cambrian) of the middle Anti-Atlas are characterized by an alternation of marine and continental sediments. Torrent conglomerates at the base and the margins of the basin took turns to marine-marginal stromatolitic carbonates. Ignimbrites prove repeated terrestrial sedimentation.A second transgressiv megasequence begins with fluviatil sands and goes on with stromatolites and lagoon carbonates (first Trilobites). This transgression reachs his first culmination at the Infra-/Lower-Cambrian boundary. Typical regressiv cycles form a transition to sandstones, which are interpreted as sediments of a delta.Marine shelf environment dominates from Middle Cambrian to Ordovician beds.

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Résumé Dans le moyen Anti-Atlas, l'évolution de l'Adoudounien et du Géorgien est caractérisée par un changement des sédiments marins et continentaux. Les dépôts des torrents à la base et dans la bordure du bassin font place à des carbonates marins marginaux stromatolithiques. Les ignimbrites marquent le retour fréquent à la sédimentation terrestre.Une deuxième mégaséquence transgressive débute avec des sables fluviatiles, des stromatolithes et des carbonates lagunaires (premiers trilobites). La transgression atteint une première phase culminante à la transition de l'Adoudounien au Géorgien. Des séquences caractérisées par de petits cycles régressifs conduisent à des grès qui pourraient être interpré tés comme des sédiments deltaïques.A partir du Cambrien moyen jusqu'à l'Ordovicien prédomine un milieu de plate-forme externe.

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Adoudounien — — Géorgien — — . — — . , - , , . , , . .