海南博螯沿岸地貌与人类活动的潜在影响

The Boao coastal system along the eastern coast of Hainan Island is a dynamic delta-tidal inlet-barrier formed during the late Holocene. The delta developed inside a shallow lagoon barred by a sandy barrier with a narrow, shallow tidal inlet opening. Two major distributary channels separated by small islands characterize the delta. The lagoon is silting up receiving and trapping sediments from both the river and, in minor measure during storms, through the tidal inlet opening and barrier washovers. The barrier at the tidal inlet is highly dynamic and changes its form, accreting (migrating spit) against the inlet during fair-weather conditions and being eroded during storms and river floods.The delta has almost completely filled the lagoon and major concerns exist on the effect that ongoing large development plans may have on the environment. These concerns include the effect on floods and rate of siltation once banks of the islands have been stabilized and floodwater and sediment load are impeded from spreading over the lowlands, and the effect of increasing pollutant loads from the new facilities on the ecosystems of the increasingly restricting lagoon water and on the seashores.     

Internet‐Based GIS Mapping in Support of K‐12 Education

Internet‐based mapping provides a powerful alternative for successfully establishing GIS technology in the K‐12 education community, while simultaneously avoiding the traditional barriers associated with desktop GIS. Internet‐based GIS can support standards‐based inquiry methods of teaching and learning while providing basic analysis tools for studying and exploring geographic or scientific data in the classroom.     

Creation of the Cocos and Nazca plates by fission of the Farallon plate

Throughout the Early Tertiary the area of the Farallon oceanic plate was episodically diminished by detachment of large and small northern regions, which became independently moving plates and microplates. The nature and history of Farallon plate fragmentation has been inferred mainly from structural patterns on the western, Pacific-plate flank of the East Pacific Rise, because the fragmented eastern flank has been subducted. The final episode of plate fragmentation occurred at the beginning of the Miocene, when the Cocos plate was split off, leaving the much reduced Farallon plate to be renamed the Nazca plate, and initiating Cocos–Nazca spreading. Some Oligocene Farallon plate with rifted margins that are a direct record of this plate-splitting event has survived in the eastern tropical Pacific, most extensively off northern Peru and Ecuador. Small remnants of the conjugate northern rifted margin are exposed off Costa Rica, and perhaps south of Panama. Marine geophysical profiles (bathymetric, magnetic and seismic reflection) and multibeam sonar swaths across these rifted oceanic margins, combined with surveys of 30–20 Ma crust on the western rise-flank, indicate that (i) Localized lithospheric rupture to create a new plate boundary was preceded by plate stretching and fracturing in a belt several hundred km wide. Fissural volcanism along some of these fractures built volcanic ridges (e.g., Alvarado and Sarmiento Ridges) that are 1–2 km high and parallel to “absolute” Farallon plate motion; they closely resemble fissural ridges described from the young western flank of the present Pacific–Nazca rise. (ii) For 1–2 m.y. prior to final rupture of the Farallon plate, perhaps coinciding with the period of lithospheric stretching, the entire plate changed direction to a more easterly (“Nazca-like”) course; after the split the northern (Cocos) part reverted to a northeasterly absolute motion. (iii) The plate-splitting fracture that became the site of initial Cocos–Nazca spreading was a linear feature that, at least through the 680 km of ruptured Oligocene lithosphere known to have avoided subduction, did not follow any pre-existing feature on the Farallon plate, e.g., a “fracture zone” trail of a transform fault. (iv) The margins of surviving parts of the plate-splitting fracture have narrow shoulders raised by uplift of unloaded footwalls, and partially buried by fissural volcanism. (v) Cocos–Nazca spreading began at 23 Ma; reports of older Cocos–Nazca crust in the eastern Panama Basin were based on misidentified magnetic anomalies.There is increased evidence that the driving force for the 23 Ma fission of the Farallon plate was the divergence of slab-pull stresses at the Middle America and South America subduction zones. The timing and location of the split may have been influenced by (i) the increasingly divergent northeast slab pull at the Middle America subduction zone, which lengthened and reoriented because of motion between the North America and Caribbean plates; (ii) the slightly earlier detachment of a northern part of the plate that had been entering the California subduction zone, contributing a less divergent plate-driving stress; and (iii) weakening of older parts of the plate by the Galapagos hotspot, which had come to underlie the equatorial region, midway between the risecrest and the two subduction zones, by the Late Oligocene.     

Mise au point d'un milieu de culture pour l'étude de l'altération de silicates en présence de Pseudomonas aeruginosa

The influence of microorganisms on mineral alteration is not easy to determine in environmental conditions, because of the difficulty to raise for comparison purposes an identical but abiotic system. Another problem in this context is the choice of reliable tracers to evaluate the alteration rate of materials during in vitro experiments. To face such difficulties, we elaborated a defined medium allowing both the growth of Pseudomonas aeruginosa and a precise measurement of the elements solubilized from the minerals. Thanks to this medium, we were able to quantitatively determine the amounts of major elements solubilized from the materials in the presence of bacterial growth, compared to a sterile system. Moreover, the analysis by ICP-MS of trace elements was possible after a chromatographic treatment, which selectively eliminated 99% of the sodium content of the medium. To cite this article: G. Aouad et al., C. R. Geoscience 337 (2005).     

The geological significance of a negative gravity anomaly in the South Wales Coalfield

Three gravity traverses across the eastern half of the South Wales Coalfield indicate a local, elongate, negative Bouguer anomaly of a few milligals amplitude bordering the southern rim. The anomaly has a maximum amplitude of 4 mgal near Maesteg and attenuates eastward, dying out in the vicinity of the East Crop. Two possible geological causes of the anomaly are examined, namely a local thick sequence of normal Upper Carboniferous strata and a discrete, low-density body of Carboniferous age with no apparent surface expression. The former, uncontroversial explanation requires rock densities at variance with measured values. In the case of the hypothetical low density body which can explain the anomaly, a variety of possible ages and configurations are discussed.     

Alkylation of polycyclic aromatic hydrocarbons in carbonaceous chondrites

Using microprobe laser-desorption, laser-ionization mass spectrometry (μL²MS), we measured the distributions of alkylated and unalkylated polycyclic aromatic hydrocarbons (PAHs) in the free organic material of 20 carbonaceous chondrites. These meteorites represent a variety of meteorite classes and alteration histories, including CI, CK, CM, CO, CR, CV, and Tagish Lake. This work provides information on free organic compounds that is complementary to studies of the structure and composition of meteoritic macromolecular content.For the nine CM2 meteorites analyzed, we observe that higher relative abundances of alkylated PAHs correlate with more intense aqueous activity. We attribute this correlation to the differences in solubility and volatility between unalkylated and alkylated PAHs. Naphthalene and its alkylation series are more susceptible to the effects of aqueous exposure than the less-soluble PAH phenanthrene and its alkylated derivatives. These observations are consistent with the possibility of chromatographic separations on the meteorite parent bodies. We identify six CM2 meteorites with similar PAH distributions that may represent the original, unaltered organic composition of the parent body.Increased metamorphic intensity reduces the abundance of all PAHs. The thermally metamorphosed CK chondrites had no detectable levels of typical meteoritic PAHs. This observation might be explained either by a loss of PAHs caused by volatilization or by a significantly different organic content of the CK parent body.     

Effects of natural attenuation processes on groundwater contamination caused by abandoned waste sites in Berlin

The aim of this research project is to identify, characterize and quantify natural attenuation (NA) processes in groundwater affected by emissions of abandoned waste disposal sites in Berlin-Kladow/Gatow, Germany. It is part of the funding priority called KORA established by the Federal Ministry for Education and Research (BMBF) to explore the extent to which NA can be used for remedial purposes for varied forms of soil and groundwater contamination. Information on the emission behaviour of individual parameters is generated on the basis of hydrogeochemical comparison of 20 years old and new data. Using groundwater-modelling and CFC-analysis, information on the transport and retention of pollutants in groundwater is compiled. The microbial colonization of contaminated aquifers is characterized by molecular biological methods [polymerase chain reaction (PCR) and denaturing gradient gel electrophoresis (DGGE)] to differentiate between contaminated and not contaminated zones.     

Redistribution of HFSE elements during rutile replacement by titanite

Titanite growth at the expense of rutile during retrograde hydration of eclogite into amphibolite is a common phenomenon. We investigated an amphibolite sample from the Tromsø eclogite facies terrain in Northern Norway to gain insight into the trace element distribution between rutile and titanite during incomplete resorption of the rutile by titanite. Patchy compositional zoning of Al, Ti, and F in titanite relates to the presence of a fluid with variable Ti/Al and/or F during its growth. Laser ablation ICP–MS and electron microprobe data for high field strength elements (HFSE: Nb, Zr, Ta, and Hf) of rutile resorbed by titanite indicate a pronounced enrichment of these elements in the rim of a large single rutile crystal (~8 mm) and a systematic decrease towards uniform HFSE contents in the large core. HFSE contents of smaller rutile grains (~0.5 mm) and rutile inclusions (<100 μm) in the titanite overgrowth are similar or higher than in the rims of large rutile crystals. Element profiles from the rim inward demonstrate that HFSE enrichment in rutile is controlled by diffusion. HFSE ratios in diffusion-altered rutile show systematic variations compared with the uniform core composition of the large rutile. Modelling of Zr and Nb diffusion in rutile indicates that diffusion coefficients in rutile in fluid-dominated natural systems must be considerably higher than those determined experimentally at 1 bar in dry systems. Variations of HFSE contents in the newly formed titanite show no systematic spatial distribution. HFSE ratios in titanite and the rims of rutile are different, indicating different solid/fluid distribution coefficients in these minerals. Element fractionation by diffusion into the relict rutile and during fluid-mediated growth of new titanite could substantially change the HFSE budget of these minerals and could affect their use for geochemical tracing and other applications, such as Zr-based geothermobarometry.     

Comparison of isotope pairing and N2:Ar methods for measuring sediment denitrification—Assumption, modifications, and implications

Denitrification has been measured during the last few years using two different methods in particular: isotope pairing measured on a triple-collector isotopic ratio mass spectrometer and N₂:Ar ratios measured on a membrane inlet mass spectrometer (MIMS). This study compares these two techniques in short-term batch experiments. Rates obtained using the original N₂∶Ar method were up to 3 to 4 times higher than rates obtained using the isotope pairing technique due to O₂ reacting with the N₂ during MIMS analysis. Oxygen combines with N₂ within the mass spectrometer ion source forming NO⁺ which reduces the N₂ concentration. The decrease in N₂ is least at lower O₂ concentrations and since oxygen is typically consumed during incubations of sediment cores, the result is often a pseudo-increase in N₂ concentration being interpreted as denitrification activity. The magnitude of this ocygen effect may be instrument specific. The reaction of O₂ with N₂ and the subsequent decrease in N₂ was only partly correctly using an O₂ correction curve for the relationship between N₂ and O₂ concentrations. The O₂ corrected N₂∶Ar denitrification rates were lower, but still did not match the isotope pairing rates and the variability between replicates was much higher. Using a copper reduction column heated to 600°C to remove all of the O₂ from the sample before MIMS analysis resulted in comparable rates (slightly lower), and comparable variability between replicates, to the isotope pairing technique. The N₂:Ar technique determines the net N₂ production as the difference between N₂ production by denitrification and N₂ consumption by N-fixation, while N-fixation has little effect on the isotope pairing technique which determines a rate very close to the gross N₂ production. When the two different techniques were applied on the same sediment, the small difference in rates obtained by the two methods seemed to reflect N-fixation as also supported from measurements of ethylene production in acetylene enriched sediment cores. The N₂:Ar and isotope pairing techniques may be combined to provide simultaneous measurements of denitrification and N-fixation. Both techniques have several assumptions that must be met to achieve accurate rates; a number of tests are outlined that can be applied to demonstrate that these assumptions are being meet.