The Ivory Coast microtektite strewnfield: new data

Ivory Coast microtektites have recently been found in three piston cores from the Atlantic Ocean. In two of these cores, the microtektites occur in a layer above the base of the Jaramillo geomagnetic event indicating that they fell approximately 0.95 m.y. ago. Major element compositions have been obtained for forty-one of the microtektites by electron microprobe and energy-dispersive X-ray analysis. The geographic location, stratigraphic age and major element compositions indicate that these microtektites are part of the Ivory Coast tektite strewnfield. Present data suggest that the Ivory Coast strewnfield may cover an area of about 4.5 million square kilometers and contain about 20 million metric tons of microtektites.     

Adaptation to climate change in the insurance sector: examples from the UK,Germany and the Netherlands

Adaptation to climate change, particularly flood risks, may come to pose large challenges in the future and will require cooperation among a range of stakeholders. However, there presently exists little research especially on the integration of the private sector in adaptation. In particular, recently developed state programs for adaptation have so far been focused on the public sector. Insurance providers may have much to contribute as they offer other parts of society services to appropriately identify, assess and reduce the financial impacts of climate change-induced risks. This study aims to explore how the institutional distribution of responsibility for flood risk is being renegotiated within the UK, Germany and Netherlands. Examining how the insurance industry and the public sector can coordinate their actions to promote climate change adaptation, the study discusses how layered natural hazard insurance systems may result from attempts to deal with increasing risks due to increasing incidences of extreme events and climate change. It illustrates that concerns over the risks from extreme natural events have prompted re-assessments of the current systems, with insurance requiring long-term legislative frameworks that defines the objectives and responsibilities of insurers and the different political authorities.     

Application of the QUILF thermobarometer to the peralkaline trachytes and pantellerites of the Eburru volcanic complex, East African Rift, Kenya

The Quaternary Eburru volcanic complex in the south-central Kenya Rift consists of pantelleritic trachytes and pantellerites. The phenocryst assemblage in the trachytes is sanidine + fayalite + ferrohedenbergite + aenigmatite ± quartz ± ilmenite ± magnetite ± pyrrhotite ± pyrite. In the pantellerites, the assemblage is sanidine + quartz + ferrohedenbergite + fayalite + aenigmatite + ferrorichterite + pyrrhotite ± apatite, although fayalite, ferrohedenbergite and ilmenite are absent from more evolved rocks (e.g. with SiO₂ > 71%). QUILF temperature calculations for the trachytes range from 709 to 793 °C and for the pantellerites 668–708 °C, the latter temperatures being among the lowest recorded for peralkaline silicic magmas. The QUILF thermobarometer demonstrates that the Eburru magmas crystallized at relatively low oxidation states (ΔFMQ + 0.5 to − 1.6) for both trachytes and pantellerites. The trachytes and pantellerites evolved along separate liquid lines of descent, the trachytes possibly deriving from a more mafic parent by fractional crystallization and the pantellerites from extreme fractionation of comenditic magmas.     

Scanning electron microscopical and cross sectional analysis of extraterrestrial carbonaceous nanoglobules

Abstract— Carbonaceous nanoglobules are ubiquitous in carbonaceous chondrite (CC) meteorites. The Tagish Lake (C2) meteorite is particularly intriguing in containing an abundance of nanoglobules, with a wider range of forms and sizes than encountered in other CC meteorites. Previous studies by transmission electron microscopy (TEM) have provided a wealth of information on chemistry and structure. In this study low voltage scanning electron microscopy (SEM) was used to characterize the globule forms and external structures. The internal structure of the globules was investigated after sectioning by focused ion beam (FIB) milling. The FIB‐SEM analysis shows that the globules range from solid to hollow. Some hollow globules show a central open core, with adjoining smaller cores. The FIB with an SEM is a valuable tool for the analysis of extraterrestrial materials, even of sub‐micron‐sized “soft” carbonaceous particles. The rapid site‐specific cross‐sectioning capabilities of the FIB allow the preservation of the internal morphology of the nanoglobules, with minimal damage or alteration of the unsectioned areas.     

Impact of the North Atlantic Oscillation on Middle Eastern Climate and Streamflow

Interannual to decadal variations in Middle Eastern temperature, precipitationand streamflow reflect the far-field influence of the North Atlantic Oscillation (NAO), a dominant mode of Atlantic sector climate variability. Using a new sea surface temperature (SST) based index of the NAO and availablestreamflow data from five Middle Eastern rivers, we show that the first principal component of December through March streamflow variability reflects changes in the NAO. However, Middle East rivers have two primary flooding periods.The first is rainfall-driven runoff from December through March, regulated on interannual to decadal timescales by the NAO as reflected in local precipitation and temperature.The second period, from April through June, reflects spring snowmelt and contributes in excess of 50% of annual runoff.This period, known locally as the khamsin, displays no significantNAO connections and a less direct relationship with local climatic factors, suggesting that streamflow variability during this period reflects land-cover change, possibly related to agriculture and hydropower generation, and snowmelt.     

Products and Mechanism of the Gas Phase Reaction of Ozone with β-Pinene

Gas phase ozonolysis of -pinene was performedin a 570 l static reactor at 730 Torr and 296 K insynthetic air and the products were analysed by acombination of gas phase FTIR spectroscopy, HPLC andIC analyses of gas phase and aerosol samples,respectively. The reaction mechanism was investigatedby adding HCHO, HCOOH and H₂O as Criegeeintermediate scavenger and cyclohexane as OH radicalscavenger. Main identified products (yields inparentheses) in the presence of cyclohexane as OHradical scavenger were HCHO (0.65 ± 0.04),nopinone (0.16 ± 0.04), 3-hydroxy-nopinone (0.15± 0.05), CO₂ (0.20 ± 0.04), CO (0.030± 0.002), HCOOH (0.020 ± 0.002), the secondaryozonide of -pinene (0.16 ± 0.05), andcis-pinic acid (0.02 ± 0.01). The decompositionof the primary ozonide was found to yieldpredominantly the excited C₉-Criegee intermediateand HCHO (0.84 ± 0.04) and to a minor extent theexcited CH₂OO intermediate and nopinone (0.16± 0.04). Roughly 40% of the excitedC₉-Criegee intermediate becomes stabilised andcould be shown to react with HCHO, HCOOH and H₂O. The atmospherically important reaction of thestabilised C₉-Criegee intermediate with H₂Owas found to result in a nopinone increase of (0.35± 0.05) and in the formation of H₂O₂(0.24 ± 0.03). Based on the observed products,the unimolecular decomposition/isomerisationchannels of the C₉-Criegee intermediate arediscussed in terms of the hydroperoxide and esterchannels. Subsequent reactions of the nopinonylradical, formed in the hydroperoxide channel, lead tomajor products like 3-hydroxy-nopinone but also tominor products like cis-pinic acid. A mechanismfor the formation of this dicarboxylic acid isproposed and its possible role in aerosol formationprocesses discussed.     

Precise orbit determination for the GRACE mission using only GPS data

The GRACE (gravity recovery and climate experiment) satellites, launched in March 2002, are each equipped with a BlackJack GPS onboard receiver for precise orbit determination and gravity field recovery. Since launch, there have been significant improvements in the background force models used for satellite orbit determination, most notably the model for the geopotential. This has resulted in significant improvements to orbit accuracy for very low altitude satellites. The purpose of this paper is to investigate how well the orbits of the GRACE satellites (about 470 km in altitude) can currently be determined using only GPS data and based on the current models and methods. The orbit accuracy is assessed using a number of tests, which include analysis of orbit fits, orbit overlaps, orbit connecting points, satellite Laser ranging residuals and K-band ranging (KBR) residuals. We show that 1-cm radial orbit accuracy for the GRACE satellites has probably been achieved. These precise GRACE orbits can be used for such purposes as improving gravity recovery from the GRACE KBR data and for atmospheric profiling, and they demonstrate the quality of the background force models being used.